全文获取类型
收费全文 | 346篇 |
免费 | 12篇 |
国内免费 | 3篇 |
专业分类
化学 | 287篇 |
晶体学 | 11篇 |
力学 | 4篇 |
数学 | 16篇 |
物理学 | 43篇 |
出版年
2023年 | 6篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 3篇 |
2015年 | 5篇 |
2014年 | 10篇 |
2013年 | 17篇 |
2012年 | 27篇 |
2011年 | 25篇 |
2010年 | 13篇 |
2009年 | 11篇 |
2008年 | 23篇 |
2007年 | 20篇 |
2006年 | 11篇 |
2005年 | 19篇 |
2004年 | 12篇 |
2003年 | 17篇 |
2002年 | 13篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 6篇 |
1995年 | 7篇 |
1994年 | 2篇 |
1993年 | 5篇 |
1992年 | 7篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 5篇 |
1982年 | 2篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 4篇 |
1975年 | 3篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1970年 | 2篇 |
1968年 | 5篇 |
排序方式: 共有361条查询结果,搜索用时 15 毫秒
101.
102.
A two-channel separable potential model is given such that the T-matrix is given in the form of a N/D matrix. This model is used to examine the relationships between the three different definitions for a resonance in the two-channel problem, particularly for a 3S1 Λp resonance. In order to obtain a phenomenological hyperon-nucleon (YN) scattering T-matrix in the present model, a least-squares fit is performed to the existing available data for the scattering cross sections and angular distributions at low energies using the s- and p-wave N/D solutions which carry sixteen independent parameters. Several solution sets of potential parameters are found, for which we can obtain good fits to the Λp → Λp, Σ?p → Λn and ΣN → ΣN data, particularly to the cross-section data for these processes. The p-wave contributions are estimated, and particularly the possibility of p-wave YN resonances is pointed out for the solutions for which we do not assume a 31 Λp resonance. 相似文献
103.
104.
We detected impurity 55Mn NMR in Cu-45 ppm and -110 ppm Mn dilute alloys at temperatures of 150–330 K. The hyperfine field we obtained was 65±5 kOe/μB. From a temperature variation of linewidths we could estimate Jsd as 1.2±0.1 eV, using the reported theories of relaxation times T1 and T2. 相似文献
105.
The sodium and potassium ion pump is an intrinsic enzyme of plasma membranes. In these experiments it was driven backward in a transient two-step operation involving, first, phosphorylation of the enzyme from inorganic phosphate, and second, transfer of the phosphate group from the enzyme to ADP upon addition of a high concentration of Na+. There was no evidence of a significant concentration gradient across the membranes. Na+ presumably reached the solutions on both faces of the membrane simultaneously and provided the energy for synthesis simply as a consequence of ligand binding. An interaction free energy between the free energy of the binding of Na+ and the free energy of hydrolysis of the phosphate group on the enzyme was estimated. The experiments also suggested a feature of the transport mechanism. This is control by phosphorylation of access pathways from the solutions in contact with the faces of the membrane to an active center for cation binding. In the dephosphoenzyme access would be to the intracellular solution and in the phosphoenzyme access would be to the extracellular solution. 相似文献
106.
Underwater acoustics and cavitating flow of water entry 总被引:3,自引:0,他引:3
The fluid mechanics of water entry is studied through investigating the underwater acoustics and the supercavitation. Underwater
acoustic signals in water entry are extensively measured at about 30 different positions by using a PVDF needle hydrophone.
From the measurements we obtain (1) the primary shock wave caused by the impact of the blunt body on free surface; (2) the
vapor pressure inside the cavity; (3) the secondary shock wave caused by pulling away of the cavity from free surface; and
so on. The supercavitation induced by the blunt body is observed by using a digital high-speed video camera as well as the
single shot photography. The periodic and 3 dimensional motion of the supercavitation is revealed. The experiment is carried
out at room temperature.
The project supported by the “BaiRen Plan” of Chinese Academy of Sciences 相似文献
107.
Tamaki M Takanashi K Harada T Fujinuma K Shindo M Kimura M Uchida Y 《Chemical & pharmaceutical bulletin》2011,59(12):1481-1484
To find candidates with high antimicrobial and low hemolytic activities, many gramicidin S (GS) analogs of various ring sizes have been designed and synthesized. However, syntheses of antimicrobially active analogues of GS having a disordered symmetry structure from C(2) have almost never been reported, because the stable, amphiphilic β-sheet structure of GS with C(2) symmetry is considered essential for its strong antibacterial activity. In the present studies, novel thirteen cycloundecapeptides 1-13 related to GS were synthesized and examined. Among them, cyclo(-Va1(1)-Orn(2)-Leu(3)-D-Phe(4)-X(5)-Pro(6)-Val(7)-Orn(8)-Leu(9)-D-Phe(10)-Pro(11)-) (X=Lys (10), Orn (11), Arg (12) and Lys(Lys) (13)) resulted in high antibiotic activity against both Gram-positive and Gram-negative microorganisms tested. In addition, 11 showed low toxicity against sheep blood cells compared with that of GS. Further, circular dichroism (CD) spectra of 10-13 had a curve similar to each other, suggesting that the conformations of these analogues in methanol are similar to each other. However, CD spectra of 10-13 were different from that of GS in the 190-210 nm region. These results suggest that the presences of one added amino acid residue at position 5 of 10-13 might be partially effective through a structural change in the biological activity of 10-13. In addition, the structural modifications at position 5 lower the undesirable hemolytic activity and enhance the desirable antibiotic activity. 相似文献
108.
A new series of ferroelectric liquid crystals (FLCs) has been designed for active matrix displays based upon the chiral smectic C phase. The FLCs have been derived from optically active fluorinated alkanols and a laterally fluoro substituted biphenylyl-1,3-dioxan core. Their physical properties such as spontaneous polarization, current response time, and tilt angle have been determined. The FLC derived from 2-fluoro-octanol showed a very short current response time of 10μs at T Sm*-N* - T= 10°C, while another FLC with the same core derived from 5-fluoro-octanol gave a value of 150μs. 相似文献
109.
Hatakeyama T Hashimoto S Seki S Nakamura M 《Journal of the American Chemical Society》2011,133(46):18614-18617
A tandem intramolecular electrophilic arene borylation reaction has been developed for the synthesis of BN-fused polycyclic aromatic compounds such as 4b-aza-12b-boradibenzo[g,p]chrysene (A) and 8b,11b-diaza-19b,22b-diborahexabenzo[a,c,fg,j,l,op]tetracene. These compounds adopt a twisted conformation, which results in a tight and offset face-to-face stacking array in the solid state. Time-resolved microwave conductivity measurements prove that the intrinsic hole mobility of A is comparable to that of rubrene, one of the most commonly used organic semiconductors, indicating that BN-substituted PAHs are potential candidates for organic electronic materials. 相似文献
110.
Amphiphilic Organic–Inorganic Hybrid Zeotype Aluminosilicate like a Nanoporous Crystallized Langmuir–Blodgett Film 下载免费PDF全文
Dr. Takuji Ikeda Dr. Norihito Hiyoshi Dr. Shun‐ichi Matsuura Dr. Tetsuya Kodaira Takuma Nakaoka Ami Irisa Miki Kawano Dr. Katsutoshi Yamamoto 《Angewandte Chemie (International ed. in English)》2015,54(27):7994-7998
A new organic–inorganic hybrid zeotype compound with amphiphilic one‐dimensional nanopore and aluminosilicate composition was developed. The framework structure is composed of double aluminosilicate layers and 12‐ring nanopores; a hydrophilic layer pillared by Q2 silicon atom species and a lipophilic layer pillared by phenylene groups are alternately stacked, and 12‐ring nanopores perpendicularly penetrate the layers. The framework topology looks similar to that of an AFI‐type zeolite but possesses a quasi‐multidimensional pore structure consisting of a 12‐ring channel and intersecting small pores equivalent to 8‐rings. The hybrid material with alternately laminated lipophilic and hydrophilic nanospaces can be assumed as a crystallized Langmuir–Blodgett film. It demonstrates microporous adsorption for both hydrophilic and lipophilic adsorptives, and its outer surface tightly adsorbs lysozyme whose molecular size is much larger than its micropore opening. Our results suggest the possibility of designing porous adsorbent with high amphipathicity. 相似文献