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51.
Site-dependent NMR relaxation time T1(r) is calculated in the vortex state using the Bogoliubov-de Gennes theory, taking account of possible "field-induced stripe" states in which the magnetism arises locally around a vortex core in d-wave superconductivity. The recently observed huge enhancement T-11(r) below T(c) at a core site in Tl2Ba2CuO6 is explained. The field-induced stripe picture explains consistently other relevant STM and neutron experiments.  相似文献   
52.
Excess enthalpies, excess heat capacities, excess volumes and sound velocities of the mixture of dioxane isomers, 1,3-dioxane and 1,4-dioxane, were measured. One of the isomers, 1,4-dioxane is considered as non-polar liquid and the other as polar liquid. Excess enthalpies are positive and small, less than 55 J mol-1. Excess heat capacities are also very small and the curve is W-shaped, and the values are from 0.03 to -0.08 J mol-1 K-1. Excess volumes and excess isentropic compressibilities are small and positive, and less than 0.03 cm3 mol-1 and 0.8 TPa-1. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
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Analogs of methyl jasmonate (=methyl (1R*,2R*)‐3‐oxo‐2‐[(Z)‐pent‐2‐enyl]cyclopentaneacetate; MJA) bearing a cyclopropane ring, double bond, or a F‐substituent were synthesized, and their odor characteristics were examined. Most of the analogs with the same stereochemical properties as methyl epijasmonate showed odor properties superior to MJA. Interestingly, the enol acetate of MJA had a diffusive orchid‐like note.  相似文献   
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We report nuclear quadrupole resonance (NQR) studies on the chain Cu sites of PrBa2Cu4O8, a quasi-one-dimensional conductor with a nearly quarter-filled band. The nuclear spin-lattice relaxation rate 1/T1 shows a pronounced peak near 100 K caused by fluctuations of electric field gradient. Similar peak was observed for the spin-echo decay rate 1/T2, however, at a different temperature near 50 K. These results and broadening of the NQR spectrum at low temperatures indicate that slow charge fluctuations of either electronic or ionic origin freeze gradually at low temperatures.  相似文献   
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We have constructed and analyzed an updated dataset consisting of 4759 experimental datapoints for the oxidative coupling of methane (OCM) reaction based on literature data reported before 2020 (∼2019) using machine learning (ML) methods. Several ML methods, including random forest regression (RFR), extra trees regression (ETR), and gradient boosting regression with XGBoost (XGB), were used in conjunction with our proposed approach, in which elemental features are used as input representations rather than inputting the catalyst compositions directly. A recent research trend, namely, the extensive exploration of Mn/Na2WO4/SiO2 catalyst systems in recent years due to their high activity and durability, was clearly reflected in the dataset analysis. An ML model for the prediction of the reaction outcome (C2 yield) was successfully developed, and feature importance scores and SHapley Additive exPlanations (SHAP) values were calculated based on ETR and XGB, respectively, to identify the input variables with the greatest influence on the catalyst performance and observe how these important variables affect the C2 yield in the OCM. The discovery and optimization of catalytic processes using ML as a “surrogate” model were explored, and promising catalytic system candidates for the OCM reaction were identified. Notably, the developed ML model predicted catalysts containing elements that do not appear in the OCM dataset. This clearly demonstrates desirably high potential of our ML model to enable extrapolative predictions for ML-aided future catalysis research.  相似文献   
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We report nuclear magnetic resonance studies on the beta-pyrochlore oxide superconductor KOs2O6. The nuclear relaxation at the K sites is entirely caused by fluctuations of the electric field gradient, which we ascribe to highly anharmonic low frequency oscillation (rattling) of K ions. A phenomenological analysis shows a crossover from overdamped to underdamped behavior of the rattling phonons with decreasing temperature and its sudden sharpening below the superconducting transition temperature T(c). Suppression of the Hebel-Slichter peak in the relaxation rate at the O sites below T(c) also indicates strong electron-phonon coupling.  相似文献   
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Grain boundary relaxation at elevated temperatures in fine-grained pure magnesium and Mg–Al solid solutions was investigated by measuring damping capacity at low frequencies. A sharp increase in damping capacity caused by grain boundary relaxation was observed at above a certain temperature. The onset temperature depended on aluminum content; the onset temperature increased with aluminum content. It was demonstrated that aluminum was effective in suppressing grain boundary relaxation in magnesium alloys. However, additional measurement of the damping capacity of a dilute Mg–Y alloy revealed that yttrium was more effective in suppressing grain boundary relaxation.  相似文献   
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