全文获取类型
收费全文 | 2425篇 |
免费 | 60篇 |
国内免费 | 16篇 |
专业分类
化学 | 1767篇 |
晶体学 | 51篇 |
力学 | 18篇 |
综合类 | 1篇 |
数学 | 164篇 |
物理学 | 500篇 |
出版年
2022年 | 12篇 |
2021年 | 18篇 |
2020年 | 18篇 |
2019年 | 29篇 |
2018年 | 11篇 |
2016年 | 42篇 |
2015年 | 35篇 |
2014年 | 50篇 |
2013年 | 156篇 |
2012年 | 90篇 |
2011年 | 102篇 |
2010年 | 60篇 |
2009年 | 66篇 |
2008年 | 99篇 |
2007年 | 127篇 |
2006年 | 125篇 |
2005年 | 117篇 |
2004年 | 92篇 |
2003年 | 101篇 |
2002年 | 98篇 |
2001年 | 62篇 |
2000年 | 74篇 |
1999年 | 37篇 |
1998年 | 32篇 |
1997年 | 29篇 |
1996年 | 53篇 |
1995年 | 38篇 |
1994年 | 34篇 |
1993年 | 26篇 |
1992年 | 46篇 |
1991年 | 29篇 |
1990年 | 35篇 |
1989年 | 29篇 |
1988年 | 49篇 |
1987年 | 20篇 |
1986年 | 25篇 |
1985年 | 37篇 |
1984年 | 27篇 |
1983年 | 32篇 |
1982年 | 36篇 |
1981年 | 42篇 |
1980年 | 19篇 |
1979年 | 47篇 |
1978年 | 24篇 |
1977年 | 20篇 |
1976年 | 17篇 |
1975年 | 25篇 |
1974年 | 21篇 |
1973年 | 27篇 |
1972年 | 14篇 |
排序方式: 共有2501条查询结果,搜索用时 15 毫秒
61.
Yasuo Saegusa Sakayu Iida Shigeo Nakamura Nguyen Chau Yoshio Iwakura 《Journal of polymer science. Part A, Polymer chemistry》1984,22(5):1017-1023
Aromatic polythioamide-oxothioxoquinazolines were synthesized by the polycondensation of 2,2′-(m-phenylene)bis-1,3,4-thiadiazoline-5-thione with aromatic bis-o-amino esters. The polymerizations were carried out at 160°C in acidic media such as m-cresol, sulfolane, and polyphosphoric acid to produce polymers with reduced viscosities up to 0.5 dL/g. These polymers were soluble in polar aprotic solvents like N-methyl-2-pyrrolidone and some acidic media including m-cresol. The polythioamide-oxothioxoquinazolines showed relatively good thermal stability with 10% weight loss at 344–394°C in air. 相似文献
62.
Y Takeuchi H Yasukawa Y Yamaoka Y Morimoto S Nakao Y Fukumori T Fukuda 《Chemical & pharmaceutical bulletin》1992,40(2):484-487
Whole skin lipid bio-liposomes (skin bio-liposomes), in size ranging from 2 to 8 microns, were prepared by a reverse phase evaporation technique using rat full thickness skin. Leakage of an encapsulated fluorescence probe, ANTS (delta-amino-1,3,6-naphthalene-trisulfonate), was measured by adding transdermal penetration enhancers (penetrants) into the medium where the skin bio-liposomes were present. Oleylamine induced a fast release of ANTS from the liposomes compared to lauryl-amine which showed a weak action. With these penetrants, the degree of ANTS release from the prepared bio-liposomes was found to correlate well with the results of frequency changes in the CH-asymmetric stretching band near 2920 cm-1 in the rat stratum corneum. The penetrant which caused relatively strong leakage of ANTS induced the significantly large shift of the peak toward the higher wave-numbers due to the perturbation in the structure of lipids of the stratum corneum. The skin bio-liposomes prepared from the rat full thickness skin could be useful in evaluating the penetrants. 相似文献
63.
Inorganic nitrogen species (nitrate, nitrite and ammonium ions) were simultaneously determined by microcolumn ion chromatography. Nitrate and nitrite were determined by UV detection at 206 nm, whereas ammonium ion was determined by fluorescence detection at excitation 410 nm and emission 470 nm. The latter fluorescence detection is based on the postcolumn reaction of ammonium ion with o-phthalaldehyde in the presence of 2-mercaptoethanol. Effects of the reagent concentration, pH, and other reaction conditions on the signal intensity were examined, and the optimum condition was explored. The present method allowed simultaneous determination of nitrate, nitrite and ammonium ions in river water. 相似文献
64.
Shigeyama M Ohgaya O Takeuchi H Hino T Kawashima Y 《Chemical & pharmaceutical bulletin》2001,49(2):129-133
We intended to develop a desired ointment base suitable for treatment of bedsores including the proliferation of granulation and epidermis. The main bedsore bacteria detected in our hospital were S. aureus in gram-positive coccus and P. aeruginosa in gram-negative bacillus. As the macrogol ointment (MO) was found to have bactericidal effects on these bacteria, MO was adopted as the base for the objective ointment. To improve the properties of the ointment base such as regulating the humidity of the exudation and controlling the release of antibiotics formulated in the ointment, co-formulating effects of various additives to MO were evaluated. The sustained release function of the ointment base was obtained by adding hydrophilic petrolatum (HP) to MO. However, the resultant ointment was found to have a poor humidity regulating property. On the other hand, MO containing 5% of hydroxypropyl cellulose (HPC) showed both the humidity regulating and the controlled drug releasing properties. It was considered that HPC particles dispersed in the ointment could be swelled by absorbing water to form a gel network. The curd tension meter tests for the ointments prepared with the various polymers showed that the MO-HPC base, which showed the highest sustained drug releasing property, was found to have the highest hardness. This result means that HPC formulated into the base forms the most rigid gel structure to resist the erosion of the ointment and to control the drug release. 相似文献
65.
Ishii K Takeuchi S Shimizu S Kobayashi N 《Journal of the American Chemical Society》2004,126(7):2082-2088
In this study, we have investigated the singlet oxygen ((1)Delta(g)) generation mechanism using phthalocyaninatosilicon (SiPc) covalently linked to nitroxide radicals (NRs), and we succeeded in increasing the singlet oxygen quantum yield (Phi(Delta)) by linking the NRs. This originates from both an increase in the triplet quantum yield and excited-state lifetimes long enough to utilize photochemical reactions. Because the electron exchange interactions with paramagnetic species were known to result only in very fast excited-state relaxation, leading to a decrease in photochemical reaction yields, this increase in Phi(Delta) is an unusual and precious example for increasing photochemical reaction yields by electron exchange interactions with paramagnetic species. In addition, our experiments and theoretical analyses show that the spin-selective energy transfer rate constant is not influenced by linking the NRs and can be evaluated by the product of spin-statistical factors and matrix elements between the initial and final states. 相似文献
66.
67.
Seventeen derivatives of 2(1H)quinoxalinone and 2H-l,4-benzoxazin-2-one have been synthesized for structural study. All of the compounds having a substituted phenacyl, isonicotinoylmethyl, or 2-furoylmethyl side chain are shown to exist in the enamine form with an internal chelation both in the crystalline and solution states as evidenced by the ir and pmr spectra, respectively. In the gas phase, however, o-hydroxyphenacyl derivatives can exist in another type of intramolecularly hydrogen-bonded form which is supported by their mass spectra. 相似文献
68.
Balakin V Alexandrov VA Mikhailichenko A Flöttmann K Peters F Voss G Bharadwaj V Halling M Holt JA Buon J Jeanjean J LeDiberder F Lepeltier V Puzo P Heimlinger G Settles R Stierlin U Hayano H Ishihara N Nakayama H Oide K Shintake T Takeuchi Y Yamamoto N Bulos F Burke D Field R Hartman S Helm R Irwin J Iverson R Rokni S Roy G Spence W Tenenbaum P Wagner SR Walz D Williams S 《Physical review letters》1995,74(13):2479-2482
69.
70.
Takeuchi S 《Physical review letters》1994,73(16):2173-2175