N-Phenethylhexadecanamide was isolated from the MeOH extract of the fruiting bodies of the mushroom Laetiporus sulphureus together with eburicoic acid. Their structures were elucidated by spectroscopic methods. 相似文献
The main purpose of this paper is to present a crop planning problem for agricultural management under uncertainty. It is significant that agricultural managers assign their limited farmlands to cultivation of which crops in a season. This planning is called the crop planning problem and influences their incomes for the season. Usually, the crop planning problem is formulated as a linear programming problem. But there are many uncertain factors in agricultural problems, so future profits for crops are not certain values. A linear programming model with constant profit coefficients may not reflect the environment of decision making properly. Therefore, we propose a model of crop planning with fuzzy profit coefficients, and an effective solution procedure for the model. Furthermore, we extend this fuzzy model, setting the profit coefficients as discrete randomized fuzzy numbers. We show concrete optimal solutions for each models. 相似文献
The AcOEt extract of Hypholoma fasciculare yielded four new congeners, fascicularones H ( 4 ), I ( 5 ), J ( 6 ), and K ( 7 ). All structures were unambiguously established by 1D and 2D NMR and MS data. In a lettuce seedling assay, compounds 4 – 7 showed radicle elongation. 相似文献
The X-ray crystal structure of natural commelinin is investigated. The results demonstrate that commelinin is a tetranuclear (4 Mg2+) metal complex, in which two Mg2+ ions chelate to six anthocyanin molecules, while the other two Mg2+ ions bind to six flavone molecules, stabilizing the commelinin complex, a new type of supramolecular complex. 相似文献
Ethylene polymerization was conducted with bis(cyclopentadienyl)zirconium dichloride (1) and rac-dimethylsilylenebis(indenyl)zirconium dichloride (2) combined with trialkylaluminum (AlR3; R=methyl (Me), ethyl (Et), isobutyl (iBu))/triphenylcarbenium tetrakis(pentafluorophenyl)borate (Ph3CB(C6F5)4) or tris(pentafluorophenyl)borane (B(C6F5)3) to study the effect of cocatalysts on polymerization rate (Rp). When AlMe3 was used, no activity or very low activity was observed with both zirconocenes regardless of the borane compounds used. The replacement of AlMe3 to AlEt3 or AliBu3 with 1–AlR3/Ph3CB(C6F5)4 caused polymerization and induction time was observed to reach the maximum Rp. Especially in the case of using AlEt3, it took about 30 min to show the activity. When B(C6F5)3 was used, AlEt3 was not effective but AliBu3 gave the highest activity among all the combinations of AlR3 and the borane compounds. In the case of polymerization with 2 using Ph3CB(C6F5)4, high activity was observed with both AlEt3 and AliBu3 without any induction period. When B(C6F5)3 was used instead of Ph3CB(C6F5)4, very low activity was observed with AlEt3. On the other hand, high activity was observed with AliBu3, and the maximum Rp was found at the beginning of the polymerization. The effect of AlR3 on the formation of active species was discussed based on these results. 相似文献
α‐Diimine nickel complexes bearing bulky ortho‐sec‐phenethyl groups (bis{[N,N′‐(4‐methyl‐2,6‐di‐sec‐phenethylphenyl)imino]‐1,2‐dimethylethane}dibromonickel ( 1 ), bis{[N,N′‐(4,6‐dimethyl‐2‐sec‐phenethylphenyl)imino]‐1,2‐dimethylethane}dibromonickel ( 2 ), bis{[N,N′‐(4‐methyl‐2‐sec‐phenethylphenyl)imino]‐1,2‐dimethylethane}dibromonickel ( 3 )) and {bis[N,N′‐(2,4,6‐trimethylphenyl)imino]‐1,2‐dimethylethane}dibromidonickel ( 4 ) are used as a precatalyst for the polymerization of trans‐4‐octene upon activation with modified methylaluminoxane. These catalysts conduct chain‐walking polymerization of trans‐4‐octene to give polymers possessing propyl and butyl branches with high molecular weight and narrow molecular weight distribution. The branching structure depends on the nickel complex as well as the polymerization temperature, and the ratio of propyl branch was increased with increasing the bulkiness of the ligand and decreasing the polymerization temperature. Consequently, the most bulky 1 among the complexes used is found to polymerize trans‐4‐octene with high 1,5‐regioselectivity at −20 °C to give poly(1‐propylpentan‐1,5‐diyl).
A new sesquiterpenoid, strobiluric acid has isolated from the liquid culture extract of the fungus Strobilurus stephanocystis together with seven known sesquiterpenoids. Their structures were established based on spectroscopic data. 相似文献
For the copolymerization of ethylene with propylene or a higher α‐olefin, using Et[Ind]2ZrCl2 metallocene catalyst, modification of silica with silicon tetrachloride prior to MAO adsorption can increase the activity, which is more pronounced for ethylene/1‐hexene copolymerization at higher pressure and temperature. The molecular weight of the copolymer produced was lower and the polydispersity tends to be decreased. No significant effect of SiCl4 addition on the microstructure and the chemical composition distribution of the copolymer produced was observed. 相似文献