全文获取类型
收费全文 | 93篇 |
免费 | 5篇 |
专业分类
化学 | 81篇 |
晶体学 | 1篇 |
力学 | 1篇 |
物理学 | 15篇 |
出版年
2020年 | 2篇 |
2019年 | 6篇 |
2018年 | 1篇 |
2016年 | 3篇 |
2015年 | 2篇 |
2014年 | 3篇 |
2013年 | 1篇 |
2012年 | 8篇 |
2011年 | 10篇 |
2010年 | 4篇 |
2009年 | 2篇 |
2008年 | 8篇 |
2007年 | 6篇 |
2006年 | 7篇 |
2005年 | 3篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 4篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 4篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有98条查询结果,搜索用时 0 毫秒
21.
Dr. Takenori Dairaku Dr. Kyoko Furuita Dr. Hajime Sato Dr. Jakub Šebera Dr. Katsuyuki Nakashima Dr. Jiro Kondo Daichi Yamanaka Prof. Yoshinori Kondo Dr. Itaru Okamoto Prof. Akira Ono Dr. Vladimír Sychrovský Dr. Chojiro Kojima Prof. Yoshiyuki Tanaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(37):13028-13031
The structure of an AgI‐mediated cytosine–cytosine base pair, C–AgI–C, was determined with NMR spectroscopy in solution. The observation of 1‐bond 15N‐109Ag J‐coupling (1J(15N,109Ag): 83 and 84 Hz) recorded within the C–AgI–C base pair evidenced the N3–AgI–N3 linkage in C–AgI–C. The triplet resonances of the N4 atoms in C–AgI–C demonstrated that each exocyclic N4 atom exists as an amino group (?NH2), and any isomerization and/or N4–AgI bonding can be excluded. The 3D structure of AgI–DNA complex determined with NOEs was classified as a B‐form conformation with a notable propeller twist of C–AgI–C (?18.3±3.0°). The 109Ag NMR chemical shift of C‐AgI‐C was recorded for cytidine/AgI complex (δ(109Ag): 442 ppm) to completed full NMR characterization of the metal linkage. The structural interpretation of NMR data with quantum mechanical calculations corroborated the structure of the C–AgI–C base pair. 相似文献
22.
Yasumoto K Nishigami A Kasai F Kusumi T Ooi T 《Chemical & pharmaceutical bulletin》2006,54(2):271-274
2,6-Dimethylheptyl sulfate (1) and 6-methyloctyl sulfate (3) were isolated from Daphnia pulex as the Daphnia kairomones that induced morphological defense of a freshwater phytoplankton Scenedesmus gutwinskii var. heterospina (NIES-802). The absolute stereochemistry at C2 of 1 was determined by (1)H-NMR analysis of the (R)-MTPA ester of alcohol 2. The absolute configuration at C6 of 3 was determined by Ohrui's method applied to alcohol 4. 相似文献
23.
Tsukasa Ikeda Yuki Inoue Akihito Suehiro Hirofumi Ikeshoji Takenori Ishida Noboru Takiguchi Akio Kuroda Junichi Kato Hisao Ohtake 《Journal of inclusion phenomena and macrocyclic chemistry》2002,44(1-4):381-382
Inclusion complex formation between cyclodextrin and autoinducer of gram negative bacteria in aqueous solution was investigated by 1D 1H-NMR and ROESY spectra. An inhibitioneffect was observed on autoinducer activities of quorum sensing in Pseudomonas aeruginosa by adding cyclodextrins to the bacterial culture medium. 相似文献
24.
Yoshiko Sakaino Hiroshi Kakisawa Takenori Kusumi 《Journal of heterocyclic chemistry》1975,12(5):953-956
Treatment of the dimer of 2-arylphenanthro[9,10-d]imidazoles with nucleophilic compounds such as alcohols, aliphatic amines, and carboxylic acids afforded 2-substituted-2H- and 4-substituted-4H-2-arylphenanthro[9,10-d]isoimidazoles. These products showed a characteristic photochromism by dissociation to a stable imidazolyl radical. 相似文献
25.
The photochemical reactions of 2‐substituted N‐(2‐halogenoalkanoyl) derivatives 1 of anilines and 5 of cyclic amines are described. Under irradiation, 2‐bromo‐2‐methylpropananilides 1a – e undergo exclusively dehydrobromination to give N‐aryl‐2‐methylprop‐2‐enamides (=methacrylanilides) 3a – e (Scheme 1 and Table 1). On irradiation of N‐alkyl‐ and N‐phenyl‐substituted 2‐bromo‐2‐methylpropananilides 1f – m , cyclization products, i.e. 1,3‐dihydro‐2H‐indol‐2‐ones (=oxindoles) 2f – m and 3,4‐dihydroquinolin‐2(1H)‐ones (=dihydrocarbostyrils) 4f – m , are obtained, besides 3f – m . On the other hand, irradiation of N‐methyl‐substituted 2‐chloro‐2‐phenylacetanilides 1o – q and 2‐chloroacetanilide 1r gives oxindoles 2o – r as the sole product, but in low yields (Scheme 3 and Table 2). The photocyclization of the corresponding N‐phenyl derivatives 1s – v to oxindoles 2s – v proceeds smoothly. A plausible mechanism for the formation of the photoproducts is proposed (Scheme 4). Irradiation of N‐(2‐halogenoalkanoyl) derivatives of cyclic amines 5a – c yields the cyclization products, i.e. five‐membered lactams 6a , b , and/or dehydrohalogenation products 7a , c and their cyclization products 8a , c , depending on the ring size of the amines (Scheme 5 and Table 3). 相似文献
26.
Takenori Izumizawa Manabu Uchida Kenji Furukawa Shigeki Naka Hiroyuki Okada Hiroyuki Onnagawa 《先进技术聚合物》1997,8(7):449-453
The electroluminescent properties of a bichromophoric molecule in which a benzoxyazolylcoumarin and carbazole moiety is combined with 1,2-ethylene linkage, i.e. 3-(2-benzoxyazolyl)-7-[2-(9-carbazolyl)ethoxy]-coumarin (CmCz), were investigated. CmCz exhibits fluorescence of different colors in a solid state and solution. Two types of device were made. One consisted of a vacuum vapor-deposited film of CmCz as an emission layer to utilize fluorescence in the solid state; the second consisted of a spin-cast film doped with CmCz as an emission material to utilize fluorescence in the solution. The device with a vapor-deposited CmCz film between electrodes shows a green emission with a luminance of less than 10−2 cd/m2. The multiple layer device in which the CmCz film was sandwiched between a hole transport layer and electron transport layer showed a green emission whose spectrum is identical to the photoluminescent spectrum in the vapor-deposited CmCz film. A maximum luminance of the multiple layer device is about 5000 cd/m2. On the other hand, the devices consisting of a spin-cast film containing a hole transport material, an electron transport material and CmCz showed a blue emission whose spectra are identical to the photoluminescent spectrum of CmCz in chloroform. Luminance of these devices is over 100 cd/m2. © 1997 John Wiley & Sons, Ltd. 相似文献
27.
28.
Adare A Afanasiev S Aidala C Ajitanand NN Akiba Y Al-Bataineh H Alexander J Aoki K Aramaki Y Atomssa ET Averbeck R Awes TC Azmoun B Babintsev V Bai M Baksay G Baksay L Barish KN Bassalleck B Basye AT Bathe S Baublis V Baumann C Bazilevsky A Belikov S Belmont R Bennett R Berdnikov A Berdnikov Y Bickley AA Bok JS Boyle K Brooks ML Buesching H Bumazhnov V Bunce G Butsyk S Camacho CM Campbell S Chen CH Chi CY Chiu M Choi IJ Choudhury RK Christiansen P Chujo T Chung P Chvala O Cianciolo V Citron Z 《Physical review letters》2011,107(25):252301
Flow coefficients ν(n) for n=2, 3, 4, characterizing the anisotropic collective flow in Au+Au collisions at √s(NN)=200 GeV, are measured relative to event planes Ψ(n), determined at large rapidity. We report ν(n) as a function of transverse momentum and collision centrality, and study the correlations among the event planes of different order n. The ν(n) are well described by hydrodynamic models which employ a Glauber Monte Carlo initial state geometry with fluctuations, providing additional constraining power on the interplay between initial conditions and the effects of viscosity as the system evolves. This new constraint can serve to improve the precision of the extracted shear viscosity to entropy density ratio η/s. 相似文献
29.
Cho S Furumoto T Hyodo T Jido D Ko CM Lee SH Nielsen M Ohnishi A Sekihara T Yasui S Yazaki K;ExHIC Collaboration 《Physical review letters》2011,106(21):212001
Identifying hadronic molecular states and/or hadrons with multiquark components either with or without exotic quantum numbers is a long-standing challenge in hadronic physics. We suggest that studying the production of these hadrons in relativistic heavy ion collisions offers a promising resolution to this problem as yields of exotic hadrons are expected to be strongly affected by their structures. Using the coalescence model for hadron production, we find that, compared to the case of a nonexotic hadron with normal quark numbers, the yield of an exotic hadron is typically an order of magnitude smaller when it is a compact multiquark state and a factor of 2 or more larger when it is a loosely bound hadronic molecule. We further find that some of the newly proposed heavy exotic states could be produced and realistically measured in these experiments. 相似文献
30.
Yusuke Hotta Tsukasa Kaneko Ryuji Hayashi Akito Yamamoto Shota Morimoto Junya Chiba Takenori Tomohiro 《化学:亚洲杂志》2019,14(3):398-402
We developed a novel diazirine‐based photolabeling agent having a (coumarin‐4‐yl)methyl ester scaffold, which exhibited multiple photochemical properties of crosslinking, fluorogenicity and cleavage. These properties can be kinetically regulated via photoinduced electron transfer between diazirine and coumarin moieties. The C?O bond of (coumarin‐4‐yl)methyl ester can be cleaved via photochemical excitation of coumarin moiety, that function has been initially quenched by the diazirine moiety. Upon diazirine photolysis with 365‐nm light, interacting protein was stably captured with photoactivatable ligand probe. Then, the unlocked cleavage function was activated with 313 nm light, and the reaction was accelerated in a weakly‐basic solution. The crosslinked protein could be selectively isolated with attachment of a small coumarin tag on the surface. This multi‐functional labeling agent has a great potential to facilitate LC‐MS/MS‐based protein identification. 相似文献