Methods and correlations for the prediction of quenching rates on hot surfaces

A substantial quantity of experimental data on rewetting, much of which has not been previously reported, is analysed using the results of calculations of the two-dimensional conduction processes taking place in the walls of tubes, which have been used to simulate the cladding of nuclear fuel elements. Correlations giving the quenching heat-transfer coefficient and sputtering temperature are proposed as a result of the analysis. These correlations may be combined with the previously reported conduction analysis to predict rewetting rates under a wide range of conditions. The new data include falling film rewetting rates measured for a range of system pressures (1–15 bars), initial wall temperatures (200–650°C), coolant mass flowrates (3–50 g sec^?1) and subcoolings (0–90°C). Measurements have also been made of rewetting rates by bottom flooding of both saturated and subcooled water at atmospheric pressure.     

Anionic forensic signatures for sample matching of potassium cyanide using high performance ion chromatography and chemometrics

Potassium cyanide was used as a model toxicant to determine the feasibility of using anionic impurities as a forensic signature for matching cyanide salts back to their source. In this study, portions of eight KCN stocks originating from four countries were separately dissolved in water and analyzed by high performance ion chromatography (HPIC) using an anion exchange column and conductivity detection. Sixty KCN aqueous samples were produced from the eight stocks and analyzed for 11 anionic impurities. Hierarchal cluster analysis and principal component analysis were used to demonstrate that KCN samples cluster according to source based on the concentrations of their anionic impurities. The Fisher-ratio method and degree-of-class separation (DCS) were used for feature selection on a training set of KCN samples in order to optimize sample clustering. The optimal subset of anions needed for sample classification was determined to be sulfate, oxalate, phosphate, and an unknown anion named unk5. Using K-nearest neighbors (KNN) and the optimal subset of anions, KCN test samples from different KCN stocks were correctly determined to be manufactured in the United States. In addition, KCN samples from stocks manufactured in Belgium, Germany, and the Czech Republic were all correctly matched back to their original stocks because each stock had a unique anionic impurity profile. The application of the Fisher-ratio method and DCS for feature selection improved the accuracy and confidence of sample classification by KNN.     

A new construction of polarizations of solvable lie algebras

Let G be a real solvable Lie algebra and G*, the vector space dual. For φεG*, a construction of a polarization at φ is described. The construction is based on the use of maximal elements of G with respect to a partial order that depends on φ. It is proved that the construction breaks down only when G fails to satisfy the criterion of Brezin and Dixmier.     

Invariant states of a thermally conducting barrier

For an infinite one-dimensional system representing a thermally conducting barrier and two semi-infinite reservoirs which it separates, we prove the existence of a unique stationary probability distribution, to which essentially any initial distribution converges for large times.Research partially supported by NSF grant No. PHY-8003298.Research partially supported by NSF grant No. PHY-8201708.     

Isotaktisches Poly(p-fluorstyrol): Analyse der Konformation und der molekularen Packung

Ohne Zusammenfassung     

A note on a paper by G.Pólya

This note is concerned with the computer implementation of Pólya's paper [8] for determining the zeros of a special class of entire functions. Grau's modification to the Graeffe process [6] is utilised to bound the iterated coefficients.