Studies of ionic conductivity and structural phase transitions of Na3H(SO4)2 crystal

The complex electrical impedance of Na₃H(SO₄)₂ along the b_m-axis has been measured from 25°C to 316°C in the frequency range 4 kHz–40 MHz. The temperature dependence of the electrical conductivity shows remarkable changes in the temperature range 160°C–260°C. The sample crystal becomes a fast ionic conductor above 260°C. The conduction mechanisms of proton and sodium ions in the different phases are analyzed in detail with respect to the structural features of the sample crystal.     

Laser diode beam shaping by optical interference

We recently proposed a novel beam shaping technique that employs Lloyd’s mirror interference. In this study, we apply this technique to three commercial laser diodes: laser diodes used for optical pumping of solid-state lasers, for laser beam printers, and for laser displays. The elliptical output beams from these laser diodes could be transformed into nearly circular beams by inserting a mirror-polished GaAs substrate below the active layer of each laser diode and adjusting its height. The experimentally observed far-field patterns were predicted fairly well by numerical calculations based on Huygens’ integral. We confirmed that our beam shaping technique is applicable to laser diodes with various wavelengths and vertical beam divergence angles. We also describe the monolithic configuration of the beam shaping system, which can be fabricated by dry etching.     

A new binary relation to compare viability of winning coalitions and its interrelationships to desirability relation and blockability relation

This paper aims to propose a new type of binary relations, called the viability relation, defined on the set of all coalitions in a simple game for a comparison of coalition influence, and to investigate its properties, especially its interrelationships to the desirability relation and the blockability relation. The viability relation is defined to compare coalitions based on their robustness over deviation of their members for complementing the inability of the desirability relation and the blockability relation to make a distinguishable comparison among winning coalitions. It is verified in this paper that the viability relation on a simple game is always transitive and is complete if and only if the simple game is S-unanimous for a coalition S. Examples show that there are no general inclusion relations among the desirability relation, the blockability relation and the viability relation. It is also verified that the viability relation and the blockability relation are complementary to each other. Specifically, the blockability relation between two coalitions is equivalent to the inversed viability relation between the complements of the two coalitions.     

On disconnected cuts and separators

For a connected graph G=(V,E), a subset U⊆V is called a disconnected cut if U disconnects the graph, and the subgraph induced by U is disconnected as well. A natural condition is to impose that for any u∈U, the subgraph induced by (V?U)∪{u} is connected. In that case, U is called a minimal disconnected cut. We show that the problem of testing whether a graph has a minimal disconnected cut is NP-complete. We also show that the problem of testing whether a graph has a disconnected cut separating two specified vertices, s and t, is NP-complete.     

Treatment of radioactive liquid organic waste using bacteria community

Waste management plays an important role in radioactive waste volume reduction as well as lowering disposal costs and minimizing the environment-detrimental impact. The employment of biomass in the removal of heavy metals and radioisotopes has a significant potential in liquid waste treatment. The aim of this study is to evaluate the radioactive waste treatment by using three different bacterial communities (BL, BS, and SS) isolated from impacted areas, removing radioisotopes and organic compounds. The best results were obtained in the BS and BL community, isolated from the soil and a lake of a uranium mine, respectively. BS community was able to remove 92% of the uranium and degraded 80% of tributyl phosphate and 70% of the ethyl acetate in 20 days of experiments. BL community removed 81% of the uranium and degraded nearly 60% of the TBP and 70% of the ethyl acetate. SS community collected from the sediment of São Sebastião channel removed 76% of the uranium and 80% of the TBP and 70% of the ethyl acetate. Both americium and cesium were removed by all communities. In addition, the BS community showed to be more resistant to radioactive liquid waste than the other communities. These results indicated that the BS community is the most viable for the treatment of large volumes of radioactive liquid organic waste.     

Crystal structure and phase transition of single crystalline CsNH2SO3

Differential scanning calorimetry (DSC) and X‐ray diffraction measurements have been performed on cesium sulfamate CsNH₂SO₃ single crystal. Two distinct endothermic peaks in the DSC curves are observed at 330 and 436 K. It is pointed out that the peak at 330 K is attributed to the structural phase transition, and the other peak at 436 K is associated with the thermal decomposition of the crystal. The structures in room‐ and high‐temperasture phases are determined, and the space group of the sample crystal is found to change from monoclinic P 2₁/c to orthorhombic Pnma. The structure of the room‐temperature phase consists of two different types of N‐H···O hydrogen bond, but in the high‐temperature phase there is no specific hydrogen bond between the NSO₃ pseudo‐tetrahera. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Crystal structures of Candida albicans N-myristoyltransferase with two distinct inhibitors

Myristoyl-CoA:protein N-myristoyltransferase (Nmt) is a monomeric enzyme that catalyzes the transfer of the fatty acid myristate from myristoyl-CoA to the N-terminal glycine residue of a variety of eukaryotic and viral proteins. Genetic and biochemical studies have established that Nmt is an attractive target for antifungal drugs. We present here crystal structures of C. albicans Nmt complexed with two classes of inhibitor competitive for peptide substrates. One is a peptidic inhibitor designed from the peptide substrate; the other is a nonpeptidic inhibitor having a benzofuran core. Both inhibitors are bound into the same binding groove, generated by some structural rearrangements of the enzyme, with the peptidic inhibitor showing a substrate-like binding mode and the nonpeptidic inhibitor binding differently. Further, site-directed mutagenesis for C. albicans Nmt has been utilized in order to define explicitly which amino acids are critical for inhibitor binding. The results suggest that the enzyme has some degree of flexibility for substrate binding and provide valuable information for inhibitor design.     

Anticorrelated bidirectional output of quasistadium-shaped semiconductor microlasers

Time-domain properties of the output from quasistadium-shaped microcavity semiconductor lasers are studied. Ring modes generating a bidirectional output are selectively excited by partial pumping. We observe a high anticorrelation between the two beams output from the ring modes. This can be considered as the generalization of alternate oscillations reported previously. We find that the outputs exhibit a robust slow modulation of 4–10 MHz, and explain it by the quasi-degeneracy of the resonator modes.     

Spectral profile of atomic emission lines and effects of pulse duration on laser ablation in liquid

The emission spectra of laser-ablated Cu atoms in water were examined, focusing on the irradiation-pulse duration effects. Spectral line profile was observed for the pulse duration of 19, 90, and 150 ns at various delay times. The line width as narrow as instrumental width was obtained by 150-ns pulse at the delay time of 800 ns. Also, long pulses result in high intensity of the emission. The spectral feature obtained by long pulses looks similar to that obtained in a gas phase. The absorption of the later part of the long pulse directly by the plume having been formed by the earlier part of the pulse may be the cause of this gas-phase-like emission. Whether the pulse heats directly the surface or the plume was investigated by the measurements of the removal volume of the ablation pit obtained by laser confocal scanning microscopy and the maximum bubble expansion size observed by shadowgraphy.