14-electron disilene palladium complex having strong pi-complex character

The first 14-electron disilene palladium complex eta2-[tetrakis(tert-butyldimethylsilyl)disilene](tricyclohexylphosphine)palladium (4) was synthesized. In the solid state, complex 4 has one tricyclohexylphosphine ligand bound unsymmetrically to the palladium center in regard to the eta2-disilene moiety. The elongation of the Si-Si bond length from that of the corresponding free disilene (3.2%) and the bent back angles of the disilene moiety (4.41 degrees and 9.65 degrees ) for 4 were much smaller than those for the corresponding 16-electron eta2-disilene complex (Me3P)2Pd[tetrakis(tert-butyldimethylsilyl)disilene] (4.6% and 27.2 degrees , respectively). Complex 4 is regarded as the complex having the strongest pi-complex character among the known disilene complexes. Highly symmetric NMR spectra were observed for 4; central Si1 and Si2 nuclei were equivalent and appeared as a doublet with 2J(29Si-31P) of 19 Hz, indicating facile flipping of the phosphine ligand in the Pd-Si-Si plane.     

Optical Coherence Tomography System based on Synthesis of Optica Coherence Function with a Wavelength-Scanning Laser Source

A new optical coherence tomography system using a wavelength-scanning laser source is presented. The system has the advantage that the depth resolution can be controlled by the scanning range. In general, rapid scanning of the wavelength varies the output power of the laser source, and it is difficult to detect a weak signal of reflected light from the scattering object. By synchronizing the intensity-integrated detector with the variation, the dynamic range of the detection has been improved. To confirm the performance, tomographic imaging of biological tissues is demonstrated.     

Input Power Conditions for Distributed Fiber Optic Temperature Sensors in Raman Optical Time-Domain Reflectometry

The critical power of the input pulse in which spontaneous Raman scattering is not seriously disturbed by stimulated Raman scattering in a fiber optic temperature sensor has been investigated experimentally and theoretically. The critical power determines the critical distance, which is nearly equal to the distance where optical time-domain reflectometry (OTDR) signal of the stimulated Raman scattering becomes maximum. From this fact, a new method to determine the critical input power with the OTDR system has been proposed, which may be applicable to most distributed fiber optic temperature sensors. It has been determined that the critical power of the input pulse is 4 watts for an infinitely long silica fiber.Presented at the International Commission of Optics Topical Meeting, Kyoto, 1994.     

On the Polar Decomposition of the Product of Two Operators and Its Applications

Let T = U|T| and S = V|S| be the polar decompositions. In this paper, we shall obtain the polar decomposition of TS as TS = UWV|TS|, where |T||S^*| = W||T||S^*|| is the polar decomposition. Next, we shall show that TS = UV|TS| is the polar decomposition if and only if |T| commutes with |S^*|. Lastly, we shall apply this result to binormal and centered operators. We shall obtain characterizations of these operator classes from the viewpoint of the polar decomposition.     

CONTROLLED SYNTHESIS OF AMPHIPHILIC BLOCK POLYMERS HAVING GLUCOSE RESIDUES AND THEIR STRUCTURE FORMATION

Vinyl ether (VE)-based amphiphilic block copolymers with D-glucose residues as hydrophilicpendants were synthesized by CH_3 CH(OiBu)Cl/ZnI_2-initiated sequential living cationic copolymerization of3-O-(vinyloxy)ethyl-1, 2:5, 6-di-O-isopropylidene-D-glucofuranose (IGVE) and isobutyl VE (IBVE ) andsubsequent deprotection. The precursor block copolymers had a narrow molecular weight distribution(M_w/M_n～1.1) and a controlled segmental composition. The solubility characteristics of the amphiphiliccopolymer depended strongly on composition. Their solvent-cast thin films were examined, under atransmission electron microscope, and could be seen to exhibit various microphase-separated surfacemorphologies such as spheres, cylinders, and lamellae, depending on composition. The amphiphiliccopolymers with the appropriate segmental composition were found to form a stable monolayer at the air-water interface, which was successfully transferred onto a substrate by the Langmuir-Blodgett (LB)technique. The layered strucfure of the built-up LB films was controlled by blending the homopolymer.     

Reaction characteristics of cellulose in the LiCl/1,3‐dimethyl‐2‐imidazolidinone solvent system

In order to elucidate the nature of the LiCl/1,3dimethy2imidazolidinone (DMI) solvent system as one of the homogeneous reaction media of cellulose, cellulose acetate (CA) and Omethylcellulose (MC) were prepared using this solvent system, and the distribution of substituents within anhydroglucose units was examined by ¹³CNMR. It was found that (i) homogeneous cellulose solutions can be easily prepared by heating 2, 5–12 and 100 parts of weight of cellulose, LiCl, and DMI, respectively, and (ii) the relative reactivity of hydroxyl groups is in the order C6 > C2 > C3 for both CA and MC. A remarkable feature of this solvent system is that the reaction efficiency in etherification is very high compared with other homogeneous solvent systems.     

Optogenetic Control of Phosphatidylinositol (3,4,5)-Triphosphate Production by Light-Sensitive Cryptochrome Proteins on the Plasma Membrane

Main observation and conclusion Phosphatidylinositol (3,4,5)-triphosphate (PIP3),acting as a fundamental second messenger,is emerging as a promising biomarker f...     

Matroid representation of clique complexes

In this paper, we approach the quality of a greedy algorithm for the maximum weighted clique problem from the viewpoint of matroid theory. More precisely, we consider the clique complex of a graph (the collection of all cliques of the graph) which is also called a flag complex, and investigate the minimum number k such that the clique complex of a given graph can be represented as the intersection of k matroids. This number k can be regarded as a measure of “how complex a graph is with respect to the maximum weighted clique problem” since a greedy algorithm is a k-approximation algorithm for this problem. For any k>0, we characterize graphs whose clique complexes can be represented as the intersection of k matroids. As a consequence, we can see that the class of clique complexes is the same as the class of the intersections of partition matroids. Moreover, we determine how many matroids are necessary and sufficient for the representation of all graphs with n vertices. This number turns out to be n-1. Other related investigations are also given.