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131.
Sufficient conditions are given that certain statistics have a common distribution under a wide class of underlying distributions. Invariance methods are the primary technical tool in establishing the theoretical results. These results are applied to MANOVA problems, problems involving canonical correlations, and certain statistics associated with the complex normal distribution. 相似文献
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133.
Takuto Ohsato Dr. Yuri Okuno Prof. Dr. Shintaro Ishida Prof. Dr. Takeaki Iwamoto Dr. Ka‐Ho Lee Prof. Dr. Zhenyang Lin Prof. Dr. Makoto Yamashita Prof. Dr. Kyoko Nozaki 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2016,128(38):11598-11602
A potassium diboryllithate (B2LiK) was synthesized and structurally characterized. DFT calculations, including NPA and AIM analyses of B2LiK, revealed ionic interactions between the two bridging boryl anions and Li+ and K+. Upon standing in benzene, B2LiK deprotonated the solvent to form a hydroborane and a phenylborane. On the basis of DFT calculations, a detailed reaction mechanism, involving deprotonation and hydride/phenyl exchange processes, is proposed. An NBO analysis of the transition state for the deprotonation of benzene suggests that the deprotonation should be induced by the coordination of benzene to the K+. 相似文献
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135.
Dr. Kazuki Fujii Dr. Koichi Mitsudo Dr. Hiroki Mandai Dr. Toshinobu Korenaga Prof. Dr. Seiji Suga 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(9):2208-2212
An efficient enantioselective acyl migration reaction of furanyl carbonates was developed to construct all-carbon quaternary stereogenic centers. In some cases, the reactions required only 0.05 mol % (minimum 500 ppm) of catalyst and showed a high turnover frequency value (TOF; 3640 h−1). Multigram-scale reactions (10 grams) also proceeded with high enantioselectivity (>99:1 e.r.) in quantitative yield. The catalyst was robust and easily recovered in 98 % yield. A wide range of functional groups were tolerated (15 examples, >98 % yield, up to >99:1 e.r.), and a variety of optically active 3,3′-disubstituted benzofuranone derivatives, which are useful intermediates for the synthesis of natural products and pharmaceuticals, were efficiently obtained. Control experiments on the catalyst structure (e.g., catalyst 1 a vs. 1 a ′ and 1 a ′′) and computational calculations revealed that both the catalytic activity and enantioselectivity should be enhanced by hydrogen bonding between catalyst and substrate. Moreover, this system was applied to the challenging γ-selective acyl migration reaction of furanyl carbonates with high γ-selectivity and high enantioselectivity (α:γ=10:90, 95:5 e.r.). 相似文献
136.
Mitsudo K Shiraga T Mizukawa J Suga S Tanaka H 《Chemical communications (Cambridge, England)》2010,46(48):9256-9258
An electro-oxidative method for generating silver acetylides from acetylenes with a Ag anode was developed. The reaction could be integrated into a Pd-catalysed electrochemical Sonogashira-type reaction. In the presence of the catalytic amount of Pd(OAc)(2) and 4-BzO-TEMPO, electro-generated silver acetylides reacted immediately with arylboronic acids to afford the corresponding coupling adducts in high yields. 相似文献
137.
138.
Koichi Mitsudo 《Tetrahedron letters》2006,47(29):5147-5150
N-Glycosylation of 2,3-dideoxy-1-[(2-pyridylmethyl)thio]glycosides (1a) using several activators is described. NBS-promoted glycosylation reaction utilizing either the α- or β-thiodideoxyglycoside proceeded smoothly at −78 °C to give the corresponding dideoxynucleoside in a β-selective manner, presumably through a common glycosyl donor. 相似文献
139.
Kondo T Nomura M Ura Y Wada K Mitsudo TA 《Journal of the American Chemical Society》2006,128(46):14816-14817
Intermolecular [2 + 2 + 1] cocyclization of isocyanates, alkynes, and CO (1 atm) proceeded smoothly in the presence of a catalytic amount of Ru3(CO)12 (3.3 mol %) in mesitylene at 130 degrees C for 3 approximately 42 h to give a variety of polysubstituted maleimides in excellent yields with high selectivity. The reaction may involve an azaruthenacyclopentenone intermediate derived from oxidative cyclization of an isocyanate and an alkyne on an active ruthenium species. 相似文献
140.
Computer Simulation of Axis-Encircling Beams Generated by an Electron Gun with a Permanent Magnet System 总被引:1,自引:0,他引:1
S. Sabchevski T. Idehara I. Ogawa M. Glyavin S. Mitsudo K. Ohashi H. Kobayashi 《International Journal of Infrared and Millimeter Waves》2000,21(8):1191-1209
Results from computer aided design of a novel electron gun generating axis-encircling beams are presented and discussed. Numerical experiments were performed by the new version of the software package GUN-MIG named GUN-MIG/CUSP. It is based on a self-consistent relativistic model and is developed as a problem oriented tool for analysis of electron-optical systems with magnetron injection guns (MIG) and electron guns with field reversal (cusp guns), forming axis-encircling beams. As a result of the simulations an electron-optical design of a novel electron gun with permanent magnet system was accomplished. The gun is expected to form high quality beams with small velocity spread and beam ripple. Parameters of the generated beams are appropriate for a prospective weakly relativistic high harmonic large orbit gyrotron (LOG). The development of such device is in progress now at the Research Center for Development of Far-Infrared Region (FIR Center) at Fukui University. 相似文献