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151.
Keitaro Tanoi Natsuko I. Kobayashi Takayuki Saito Naoko Iwata Atsushi Hirose Yoshimi Ohmae Ren Iwata Hisashi Suzuki Tomoko M. Nakanishi 《Journal of Radioanalytical and Nuclear Chemistry》2013,296(2):749-751
The time course of Mg uptake and release using intact rice plants and 28Mg as a tracer is presented. Since there is no conventional Mg tracer available, 28Mg was produced via 27Al(α, 3p)28Mg reaction using a cyclotron. Using the purified 28Mg tracer, it was found that the uptake amount of 28Mg by the rice plants increased linearly during 30 min of application. After 28Mg treatment for 90 min, the roots were sequentially washed with iced solution for 120 min. Within about 10 min, almost all of the 28Mg, that was thought to be weakly bound to the apoplast, was washed away. 相似文献
152.
Tomoyuki Miyazawa Haruka Abe Takayuki Suzuki Yosuke Togashi Kazuhiro Koshiji Yuki Nonaka 《Journal of carbohydrate chemistry》2013,32(5):252-266
We evaluated the potential of a linear β-1,3-glucan (curdlan) as a starting material to access C6-modified glucose derivatives and found that 6-bromo-6-deoxyglucose, 6-azide-6-deoxyglucose, and 6-acetamido-6-deoxyglucose could be readily prepared from curdlan through its C6-selective and quantitative modifications and subsequent acid-catalyzed hydrolysis. 相似文献
153.
Isao Kadota Takayuki Kishi Yuka Fujisawa Yuji Yamagami Hiroyoshi Takamura 《Tetrahedron letters》2010,51(30):3960-5853
A convenient method for the stereoselective construction of angular methyl group of fuzed cyclic ethers is described. Reactions of mixed thioacetals with Me2Zn/Zn(OTf)2 afforded the corresponding methylated products in good yields. Various protective groups such as MOM ether, benzylidene acetal, TBS ether, and pivaloyl group were stable under the reaction conditions. 相似文献
154.
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156.
RuS2 nanoparticles, smaller than 3 nm in diameter, were prepared by H2S gas injection into the AOT/isooctane reverse micellar solution containing RuCl3 aqueous solution. The nanoparticle size was found to be independent of the Wo (water content) value of the reverse micellar system, as shown by TEM observation. The recovery and immobilization of the RuS2 nanoparticles from reverse micelles onto thiol-modified polystyrene particles (PSt-SH) were successfully carried out, by the addition of PSt-SH into the reverse micellar solution under conditions of mild stirring. The resulting composites, PSt-RuS2, showed photocatalytic activity for H2 generation form aqueous solution containing 2-propanol and Na2SO3 as sacrificial electron donors. 相似文献
157.
Takayuki Tonoi 《Tetrahedron letters》2005,46(37):6355-6358
Bis-trifluoromethanesulfonylamide (bis-triflylamide) itself works as an efficient chiral Brønsted acid catalyst for the hetero Diels-Alder reactions between Danishefsky’s diene and glyoxylate or phenylglyoxal presumably through double hydrogen bonding. 相似文献
158.
We applied a time-resolved small-angle neutron scattering technique to the vesicle system of dimyristoylphosphatidylcholine for the first time to determine lipid kinetics. The observed kinetics could be explicitly represented by a simple model that includes two independent kinetic parameters, i.e., the rates of transbilayer and interbilayer exchange. This technique is perfectly suited for the determination of lipid exchange kinetics in equilibrium and applicable to evaluation of the activity of the factors relevant to lipid migration, such as translocase and lipid transfer proteins. 相似文献
159.
Yasuhiro Shiraishi Yugo Furubayashi Go Nishimura Takayuki Hirai 《Journal of luminescence》2007,127(2):623-632
Dinuclear lanthanide (Ln=Tb3+ or Eu3+) complexes (Ln2L2) of two octadentate macrocyclic polyaminopolycarboxylic ligands connected through a benzophenone (BP) moiety (L2) have been synthesized. Sensitized luminescence properties of Ln2L2 in water have been studied in comparison to those of BP-conjugated mononuclear Ln complexes (LnL1). The luminescence intensity of Tb2L2 is lower than that of TbL1 because of lower triplet quantum yield of the BP moiety. In contrast, Eu2L2 shows higher intensity than EuL1. For both Eu complexes, energy level of triplet excited-state BP (3BP*) is only 3 kJ mol−1 higher than that of 5D2 excited-state of Eu3+. The 5D2 state formed by a triplet-energy transfer (TET) from 3BP* is therefore deactivated by a back energy transfer (BET) to the ground-state BP, resulting in low luminescence intensity of EuL1. In contrast, within Eu2L2, TET from 3BP* to 5D0 state of two Eu3+ ions is accelerated, thus leading to higher luminescence intensity. Another notable feature of Eu2L2 is the luminescence quantum yield independent of its concentration. In contrast, for EuL1 system, an intermolecular BET occurs from 5D2 state of Eu3+ to the ground-state BP conjugated to another EuL1 complex, resulting in a yield decrease with the concentration increase. 相似文献
160.
Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess
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Dr. Arimasa Matsumoto Takaaki Abe Atsushi Hara Takayuki Tobita Taisuke Sasagawa Prof. Dr. Tsuneomi Kawasaki Prof. Dr. Kenso Soai 《Angewandte Chemie (International ed. in English)》2015,54(50):15218-15221
Asymmetric amplification during self‐replication is a key feature that is used to explain the origin of homochirality. Asymmetric autocatalysis of pyrimidyl alkanol in the asymmetric addition of diisopropylzinc to pyrimidine‐5‐carbaldehyde is a unique example of this phenomenon. Crystallization of zinc alkoxides of this 5‐pyrimidyl alkanol and single‐crystal X‐ray diffraction analysis of the alkoxide crystals reveal the existence of tetramer or higher oligomer structures in this asymmetric autocatalytic system. 相似文献