A Non-Heme Iron(III) Complex with Porphyrin-like Properties That Catalyzes Asymmetric Epoxidation

In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.     

Two-particle rapidity correlations in αα, αp,andp p interactions at the CERN intersecting storage rings

Two-particle rapidity correlations have been studied for αα, αp, andp p interactions at the CERN ISR using the Split-Field Magnet (SFM) detector. In order to isolate the true two-particle correlations, the analysis was performed at fixed charged multiplicity. In the framework of a simple cluster model, it is found that cluster widths as well as cluster multiplicities are the same for αα, αp, andp p interactions, and both decrease with increasing charged multiplicity.     

Status of the LHCb experiment

The European Physical Journal C - LHCb is a dedicated experiment to study CP violation and other rare processes in the B meson system at LHC. It is designed to exploit the large sample of Bd and Bs...     

Effective dephosphorylation catalyzed by fluoride ion: A novel synthesis of terminal f-alkylacetylenes from f-alkanoyl chlorides

1H-F-Alkene-1-phosphonates, easily accessible from F-alkanoyl chlorides, underwent dephosphorylation on treatment with a catalytic amount of fluoride ion at O°C to room temperature to give terminal F-alkylacetylenes in good yields.     

Synhtesis of 2-ethoxy-6,11-dimethyl-7,9-bisdehydroaza[16]annulene and 2-ethoxy-8,13-dimethyl-9,11-bisdehydroaza[18]annulene

Title azaannulenes, the paratropic and diatropic vinylogues of pyridine, were synthesized starting from the annulenones.     

Inclusive Pomeron-Pomeron interactions at the CERN ISR

Data are presented for the first time on inclusive Pomeron-Pomeron interactions which produce a central systemX (composed mainly of multimeson states) in proton-proton collisions at \(\sqrt s \) at the CERN ISR. The systemX has a Feynman-x distribution which is sharply peaked atx _f=0, is inconsistent with any significant contributions from Reggeon exchange processes, and has an invariant mass dependence in good agreement with the predicted formM _x ^?2 . Kaon production is about 15% of pion production, nearly independent ofM _x, while proton-antiproton production averages about 5% of pion production and increases withM _x. The structure of the central systemX develops into a jetlike shape, asM _x increases, as would be expected from a model of Pomeron fragmentation. The shape of thex _f(π) distribution in the center of mass of theX system (although not proving existence) is consistent with asoft partonic substructure of the Pomeron.     

Tagging diquarks by protons of high transverse momentum inpp collisions at the ISR

Events are analyzed in which a high transverse momentum proton was produced at polar angles of 10°, 20° and 45°. The experiment was performed with the Split Field Magnet detector at the CERN ISR at \(\sqrt s \) =62 GeV. A 4-jet structure of these events is found [1]. The measured charge structure of spectator jets is compatible with proton production from hard diquark scattering. This is supported by a study of baryon number compensation in the towards jets. The observed charge compensation in the towards jets suggests dominance of hard (ud) scattering. Evidence forΔ ⁺⁺ production at high transverse momentum indicates the presence of an additional (uu) scattering component. The properties of the recoiling away jets are compatible with the fragmentation of a valence quark and/or of a gluon as in the case of meson triggers.     

Syntheses of 6N(N′-formyl-D-phenylalanyl)-deoxyamino-β-cyclodextrin and 6N(N′-formyl-L-phenylalanyl)deoxyamino-β-cyclodextrin and their inclusion behavior

6N(N-formyl-D-phenylalanyl)-deoxyamino--cyclodextrin and 6N(N-formyl-L-phenylal-anyl)-deoxyamino--cyclodextrin (I andII) were prepared. These new hosts formed intramolecular host-guest complexes and included naphthyl derivatives preferentially with a stoichiometry of 1:1. The inclusion behavior was different between I and II because the cavity shape formed with the CD cavity and the phenylalanine moiety of I was different from that of II.     

Asymmetric catalysis of Nozaki-Hiyama allylation and methallylation with a new tridentate bis(oxazolinyl)carbazole ligand

This work describes the development of a new tridentate ligand effective for the asymmetric catalysis of Nozaki-Hiyama allylation and methallylation. Various aldehydes were allylated or methallylated with good enantioselectivity (86-96%), and a key intermediate of calcitriol lactone synthesis was also obtained with excellent diastereoselectivity (97% de, 91%). The enantioselective reaction catalyzed by this Cr-ligand complex is applicable to a broad range of aldehydes and has great potential for natural product synthesis. Another remarkable feature of this ligand is the stability of the Cr-ligand complex which was recovered after the enantioselective reaction and recycled twice without diminishing the enantioselectivity and yield.