Cyclization‐Induced Turn‐On Fluorescence System Applicable to Dicarboxylate Sensing

A novel tetraphenylethene‐based fluorescence (FL) chemosensor exhibits nonlinear turn‐on FL switching though cooperative binding of L ‐tartarate, where its convergent binding to form cyclic substructures is responsible for the FL increase. This binding scheme achieves selective detection of dicarboxylates over monocarboxylates, thus is potentially applicable to the preliminary screening for metabolic disorders.     

Chaotic phenomena on a coupled nonlinear oscillator based on the rollins-hunt's model

Based on the Rollins-Hunt's model, chaotic phenomena in a driven coupled R-L-diode oscillator are examined numerically. It is found that a straightforward extension of this model to a system with two degrees of freedom is valid as far as the quasiperiodic route to chaos is concerned. However, this model is not sufficient to explain the intermittency and the quasiperiodic routes including the discontinuous (jump) bifurcations with hysteresis. Then it is shown that the additional nonlinearity due to variable capacitance of the diode is effective to explain the above phenomena. It is also shown that a two-dimensional discrete return map in which nonlinear terms are introduced in a characteristic form simulates systematically the numerical results. In particular, this map model can explain effectively the mechanisms which cause the intermittency and the cliscontinuous bifurcation.     

The Hamiltonian dynamics over real hypersurfaces in Kaehler manifolds

Let X be a Kaehler manifold with complex dimension n. Let ωX be its Kaehler form. Let M be a strongly pseudo convex real hypersurface in X. For this hypersurface, the deformation theory of CR structures is successfully developed. And we find that H¹(M,T^′) (the T^′-valued Kohn-Rossi cohomology) is the Zariski tangent space of the versal family. In this paper, the geometrical meaning of H¹(M,O) is studied, and we propose to study displacements of the real hypersurface, which preserves the type of the differential form, ωX, over CR structures, on M, infinitesimally.     

Interaction of Near-Field Light with Ordered Polystyrene Spheres: Experimental Studies

We have experimentally observed the interaction of near-field light excited in a total internal reflection geometry with a periodic two-dimensional array of polystyrene spheres. The angular- and frequencyscanned attenuated-total-reflection (ATR) method was employed to observe the interaction. ATR spectra indicate that there is an easy axis and a difficult axis for the light propagation. When light is incident toward the easy axis, resonant dips appear in the ATR spectra. The experimental results were compared with those obtained by finite-difference time-domain analysis. The numerical results obtained by this method are able to explain a part of the experimental ones. Parts of the dips in the ATR spectra were considered to stem from propagating and whispering-gallery (WG) modes. That is, the propagation of the WG-modes over several spheres may enhance the coupling between the spheres and the incident light, and consequently may induce resonant structures in the ATR spectra.This paper was originally presented at the 5th International Conference on NEAR FIELD OPTICS and RELATED TECHNOLOGIES (NFO-5), which was held on December 6–10, 1998 at Coganoi Bay Hotel, Shirahama, Japan, in cooperation with the Japan Society of Applied Physics and Mombusho Grant-in Aid for Scientific Research on Priority Areas “Nearfield Nano-optics” Project, sponsored by Japan Society for the Promotion of Science.     

Instrumentation of high temperature and pressure reaction system with continuous flow and its hyphenation to a liquid chromatograph.

A continuous flow-type hydrothermal reaction system, in which both temperature and pressure were rapidly and dynamically controlled, was constructed. It is called a real time high temperature and pressure reaction system (RT-HighTP). The RT-HighTP was hyphenated with liquid chromatograph (RT-HighTP-LC) to achieve prompt analysis of the reaction products. The RT-HighTP system produced stable pressure under the supercritical and subcritical phases (%RSD < 3%). The RT-HighTP-LC was able to change the hydrothermal condition rapidly. The hydrothermal products under four conditions were analyzed within 70 min. Further, the hydrothermal products of lignin was easily taken out using the sample collecting loop and analyzed by an external instrument of GC/MS.     

Structural and photo-luminescence properties of nanocrystalline silicon films deposited at low temperature by plasma-enhanced chemical vapor deposition

Nanocrystalline silicon (nc-Si) films were prepared by a plasma-enhanced chemical vapor deposition method at a deposition temperature below 220 °C with different dynamic pressures (P_g), hydrogen flow rates ([H₂]), and RF powers, using SiH₄/H₂/SiF₄ mixtures. We examined the photo-luminescence (PL) spectra and the structural properties. We observed two stronger and weaker PL spectra with a peak energies around E_PL = 1.8 and 2.2-2.3 eV, respectively, suggesting that the first band was related to nanostructure in the films, and another band was associated with SiO-related bonds. The nc-Si films with rather large PL intensity was obtained for high [H₂] and/or low pressure values, However, effects of [H₂] are likely to be different from those of P_g. The average grain size (δ) and the crystalline volume fraction (ρ) at first rapidly increase, and then slowly increase, with increasing P_g. Other parameters exhibited opposite behaviors from those of δ or ρ. These results were discussed in connection with the changes in the PL properties with varying the deposition conditions.     

Codes from curves with total inflection points

The concept of pure gaps of a Weierstrass semigroup at several points of an algebraic curve has been used lately to obtain codes that have a lower bound for the minimum distance which is greater than the Goppa bound. In this work, we show that the existence of total inflection points on a smooth plane curve determines the existence of pure gaps in certain Weierstrass semigroups. We then apply our results to the Hermitian curve and construct codes supported on several points that compare better to one-point codes from that same curve.      

Magnetic properties and structure of FePt/FeMn multilayers

A systematic study of the magnetic properties by ion beam sputter-deposition system, was conducted in conjunction with the structure of FePt/FeMn multilayers fabricated onto MgO(0 0 1) substrates. Both parallel and perpendicular exchange biases were observed in the multilayers and were found to decrease drastically, as the deposition temperature is higher than 350 °C, which is evidently due to the interdiffusion at the interface. The thickness dependence study shows that the perpendicular magnetic anisotropy observed in the multilayers originates from surface anisotropy, being consistent with the decrease of perpendicular magnetic anisotropy as the deposition temperature is increased. The difference between parallel and perpendicular blocking temperatures that was clearly observed, is possibly due to the spin canting out of plane at the interface.