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71.
Homoleptic cyclometalated iridium complexes with highly efficient red phosphorescence and application to organic light-emitting diode 总被引:7,自引:0,他引:7
Tsuboyama A Iwawaki H Furugori M Mukaide T Kamatani J Igawa S Moriyama T Miura S Takiguchi T Okada S Hoshino M Ueno K 《Journal of the American Chemical Society》2003,125(42):12971-12979
Phosphorescence studies of a series of facial homoleptic cyclometalated iridium(III) complexes have been carried out. The complexes studied have the general structure Ir(III)(C-N)(3), where (C-N) is a monoanionic cyclometalating ligand: 2-(5-methylthiophen-2-yl)pyridinato, 2-(thiophen-2-yl)-5-trifluoromethylpyridinato, 2,5-di(thiophen-2-yl)pyridinato, 2,5-di(5-methylthiophen-2-yl)pyridinato, 2-(benzo[b]thiophen-2-yl)pyridinato, 2-(9,9-dimethyl-9H-fluoren-2-yl)pyridinato, 1-phenylisoquinolinato, 1-(thiophen-2-yl)isoquinolinato, or 1-(9,9-dimethyl-9H-fluoren-2-yl)isoquinolinato. Luminescence properties of all the complexes at 298 K in toluene are as follows: quantum yields of phosphorescence Phi(p) = 0.08-0.29, emission peaks lambda(max) = 558-652 nm, and emission lifetimes tau = 0.74-4.7 micros. Bathochromic shifts of the Ir(thpy)(3) family [the complexes with 2-(thiophen-2-yl)pyridine derivatives] are observed by introducing appropriate substituents, e.g., methyl, trifluoromethyl, or thiophen-2-yl. However, Phi(p) of the red emissive complexes (lambda(max) > 600 nm) becomes small, caused by a significant decrease of the radiative rate constant, k(r). In contrast, the complexes with the 1-arylisoquinoline ligands are found to have marked red shifts of lambda(max) and very high Phi(p) (0.19-0.26). These complexes are found to possess dominantly (3)MLCT (metal-to-ligand charge transfer) excited states and have k(r) values approximately 1 order of magnitude larger than those of the Ir(thpy)(3) family. An organic light-emitting diode (OLED) device that uses Ir(1-phenylisoquinolinato)(3) as a phosphorescent dopant produces very high efficiency (external quantum efficiency eta(ex) = 10.3% and power efficiency 8.0 lm/W at 100 cd/m(2)) and pure-red emission with 1931 CIE (Commission Internationale de L'Eclairage) chromaticity coordinates (x = 0.68, y = 0.32). 相似文献
72.
Osako T Terada S Tosha T Nagatomo S Furutachi H Fujinami S Kitagawa T Suzuki M Itoh S 《Dalton transactions (Cambridge, England : 2003)》2005,(21):3514-3521
The structure and dioxygen-reactivity of copper(I) complexes R supported by N,N-bis(6-methylpyridin-2-ylmethyl)amine tridentate ligands L2R[R (N-alkyl substituent)=-CH2Ph (Bn), -CH2CH2Ph (Phe) and -CH2CHPh2(PhePh)] have been examined and compared with those of copper(I) complex (Phe) of N,N-bis[2-(pyridin-2-yl)ethyl]amine tridentate ligand L1(Phe) and copper(I) complex (Phe) of N,N-bis(pyridin-2-ylmethyl)amine tridentate ligand L3(Phe). Copper(I) complexes (Phe) and (PhePh) exhibited a distorted trigonal pyramidal structure involving a d-pi interaction with an eta1-binding mode between the metal ion and one of the ortho-carbon atoms of the phenyl group of the N-alkyl substituent [-CH2CH2Ph (Phe) and -CH2CHPh2(PhePh)]. The strength of the d-pi interaction in (Phe) and (PhePh) was weaker than that of the d-pi interaction with an eta2-binding mode in (Phe) but stronger than that of the eta1 d-pi interaction in (Phe). Existence of a weak d-pi interaction in (Bn) in solution was also explored, but its binding mode was not clear. Redox potentials of the copper(I) complexes (E1/2) were also affected by the supporting ligand; the order of E1/2 was Phe>R>Phe. Thus, the order of electron-donor ability of the ligand is L1Phe相似文献
73.
Motozaki T Sawamura K Suzuki A Yoshida K Ueki T Ohara A Munakata R Takao K Tadano K 《Organic letters》2005,7(11):2265-2267
[reaction: see text]. We have completed the total synthesis of natural (+)-tubelactomicin A (1), a 16-membered macrolide antibiotic. This Letter presents a highly efficient synthesis of the upper-half segment (C14-C24) and the completion of the total synthesis featuring a high-yielding Stille coupling for the connection of the upper-half and lower-half segments and Mukaiyama macrolactonization for the construction of the entire structure of 1. 相似文献
74.
Ando K Tsuji E Ando Y Kunitomo J Kobayashi R Yokomizo T Shimizu T Yamashita M Ohta S Nabe T Kohno S Ohishi Y 《Organic & biomolecular chemistry》2005,3(11):2129-2139
Variable benzo[b]furan derivatives having (E)- and (Z)-2-alkylcarbamoyl-1-methylvinyl groups at the 2-, 4- and 5-positions and a carboxylpropoxy or (1-phenyl)ethoxy group at the 7-position were prepared to find novel and selective leukotriene B4(LTB4) receptor antagonists. (E)-2-(2-diethylcarbamoyl-1-methylvinyl)-7-(1-phenylethoxy)benzo[b]furan (4v) showed selective inhibition to the human BLT2 receptor (hBLT2). On the other hand, (E)-2-acetyl-4-(2-diethylcarbamoyl-1-methylvinyl)-7-(1-phenylethoxy)benzo[b]furan (7v) inhibited both human BLT(1) receptor (hBLT1) and hBLT2. The (E)-2-(2-diethylcarbamoyl-1-methylvinyl) group lay on approximately the same plane as the benzo[b]furan ring, whereas the (E)-4-(2-diethylcarbamoyl-1-methylvinyl) group had the torsion angle (45.7 degree) from the benzo[b]furan ring plane. However, the (Z)-(2-alkylcarbamoyl-1-methylvinyl)benzo[b]furans were inactive. The inhibitory activity depended on the conformation of the 2-diethylcarbamoyl-1-methylvinyl group. 相似文献
75.
G. Padrón V. Besada A. Agraz Y. Quiñones L. Herrera Y. Shimonishi T. Takao 《Analytica chimica acta》1989
Mass spectrometry (MS) was used for the characterization of recombinant human α-2 interferon (α-2 IFN) produced in E. coli. After purification by monoclonal antibody affinity chromatography, α-2 IFN showed two major peaks in reversed-phase liquid chromatography (RP- LC). Each component was digested with trypsin and Staphylococcus aureus protease V8, separately or in tandem, and the peptide mixture was analysed by MS without further purification. The first peak corresponded to the 165 amino acid sequence of human α-2 IFN and the main component of the second peak was the acetylated Cys1 α-2 IFN. It was also possible to verify by MS the location of the SS bonds in α-2 IFN and the occurrence of incorrect SS bridges in the products of some renaturation processes. The best renaturation process for obtaining a product without adducts or scrambling of disulphide bonds could be found by using RP-LC and fast atom bombardment MS. 相似文献
76.
Unsymmetrical Pincer‐Type Ruthenium Complex Containing β‐Protic Pyrazole and N‐Heterocyclic Carbene Arms: Comparison of Brønsted Acidity of NH Groups in Second Coordination Sphere 下载免费PDF全文
Tatsuro Toda Prof. Dr. Shigeki Kuwata Prof. Dr. Takao Ikariya 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(31):9539-9542
A reaction of a 2‐(imidazol‐1‐yl)methyl‐6‐(pyrazol‐3‐yl)pyridine with [RuCl2(PPh3)3] resulted in tautomerization of the imidazole unit to afford the unsymmetrical pincer‐type ruthenium complex 2 containing a protic pyrazole and N‐heterocyclic carbene (NHC) arms. Deprotonation of 2 with one equivalent of a base led to the formation of the NHC–pyrazolato complex 3 , indicating that the protic NHC arm is less acidic. When 2 was treated with two equivalents of a base under H2 or in 2‐propanol, the hydrido complex 4 containing protic NHC and pyrazolato groups was obtained through metal–ligand cooperation. 相似文献
77.
Harada T Ikeda S Hashimoto F Sakata T Ikeue K Torimoto T Matsumura M 《Langmuir : the ACS journal of surfaces and colloids》2010,26(22):17720-17725
A core-shell composite consisting of a palladium (Pd) nanoparticle and a hollow carbon shell (Pd@hmC) was employed as a catalyst for aerobic oxidation of various alcohols. The core-shell structure was synthesized by consecutive coatings of Pd nanoparticles with siliceous and carbon layers followed by removal of the intermediate siliceous layer. Structural characterizations using TEM and N(2) adsorption-desorption measurements revealed that Pd@hmC thus-obtained was composed of a Pd nanoparticle core of 3-6 nm in diameter and a hollow carbon shell with well-developed mesopore (ca. 2.5 nm in diameter) and micropore (ca. 0.4-0.8 nm in diameter) systems. When compared to some Pd-supported carbons, Pd@hmC showed a high level of catalytic activity for oxidation of benzyl alcohol into benzaldehyde using atmospheric pressure of O(2) as an oxidant. The Pd@hmC composite also exhibited a high level of catalytic activity for aerobic oxidations of other primary benzylic and allylic alcohols into corresponding aldehydes. The presence of a well-developed pore system in the lateral carbon shell enabled efficient diffusion of both substrates and products to reach the central Pd nanoparticles, leading to such high catalytic activities. This core-shell structure also provided high thermal stability of Pd nanoparticles toward coalescence and/or aggregation due to the physical isolation of each Pd nanoparticle from neighboring particles by the carbon shell: this specific property of Pd@hmC resulted in possible regeneration of catalytic activity for these aerobic oxidations by a high-temperature heat treatment of the sample recovered after catalytic reactions. 相似文献
78.
79.