全文获取类型
收费全文 | 1490篇 |
免费 | 45篇 |
国内免费 | 7篇 |
专业分类
化学 | 1037篇 |
晶体学 | 14篇 |
力学 | 17篇 |
数学 | 158篇 |
物理学 | 316篇 |
出版年
2022年 | 9篇 |
2021年 | 7篇 |
2020年 | 12篇 |
2019年 | 13篇 |
2018年 | 5篇 |
2017年 | 20篇 |
2016年 | 30篇 |
2015年 | 24篇 |
2014年 | 27篇 |
2013年 | 77篇 |
2012年 | 52篇 |
2011年 | 88篇 |
2010年 | 40篇 |
2009年 | 60篇 |
2008年 | 81篇 |
2007年 | 101篇 |
2006年 | 88篇 |
2005年 | 107篇 |
2004年 | 90篇 |
2003年 | 69篇 |
2002年 | 71篇 |
2001年 | 24篇 |
2000年 | 24篇 |
1999年 | 24篇 |
1998年 | 14篇 |
1997年 | 18篇 |
1996年 | 17篇 |
1995年 | 8篇 |
1994年 | 16篇 |
1993年 | 14篇 |
1992年 | 28篇 |
1991年 | 11篇 |
1990年 | 13篇 |
1989年 | 12篇 |
1988年 | 10篇 |
1987年 | 11篇 |
1986年 | 5篇 |
1985年 | 22篇 |
1984年 | 19篇 |
1983年 | 14篇 |
1982年 | 23篇 |
1981年 | 13篇 |
1980年 | 23篇 |
1979年 | 20篇 |
1978年 | 10篇 |
1977年 | 12篇 |
1976年 | 9篇 |
1975年 | 15篇 |
1974年 | 12篇 |
1973年 | 9篇 |
排序方式: 共有1542条查询结果,搜索用时 15 毫秒
121.
122.
Kunihiko Takabe Suguru Ohkawa Toshio Sato Gia Hien Tang Takao Katagiri 《Tetrahedron letters》1980,21(40):3883-3884
Dimerization of 3-methyl-3-butenenitrile (1) by lithium dialkylamide gave selectively 3,5,5-trimethyl-1-amino-4-cyanocyclohexa-1,3-diene (2), which was easily hydrolyzed by aqueous acid to afford 4-cyanoisophorone (3,5,5-trimethyl-4-cyano-cyclohex-2-enone) (3) quantitatively. 相似文献
123.
124.
An infrared, pulsed heterodyne laser radar using differential absorption technique with tunable lasers is proposed as a practical means of measuring dispersed air pollutants with range resolution. A system analysis shows that this scheme offers an adequate sensitivity for ranges up to several km. 相似文献
125.
Mizukoshi Y Seino S Okitsu K Kinoshita T Otome Y Nakagawa T Yamamoto TA 《Ultrasonics sonochemistry》2005,12(3):191-195
We prepared Au/gamma-Fe2O3 composite nanoparticles by sonochemically reducing Au(III) ions employing no stabilizer in the aqueous solution to form stable Au nanoparticles and allowing them to attach onto the surface of gamma-Fe2O3 particles with an average size of 21 nm. Size of the formed Au nanoparticle depended on the initial concentration of Au(III) ions. The number of the Au nanoparticles, supported on each gamma-Fe2O3 particle was controlled by changing the relative amounts of Au(III) ions and gamma-Fe2O3 particles. The composite nanoparticles exhibited a high affinity with glutathione, a tripeptide with mercapto group so that separation and manipulation of glutathione in aqueous solutions could be performed by application of external magnetic field. Because the surfaces of the Au nanoparticles were not shielded by any stabilizers, or naked, sonochemically prepared Au/gamma-Fe2O3 composite nanoparticles seemed to show stronger affinity to the glutathione than those by the radiochemical method. 相似文献
126.
Okada S Okinaka K Iwawaki H Furugori M Hashimoto M Mukaide T Kamatani J Igawa S Tsuboyama A Takiguchi T Ueno K 《Dalton transactions (Cambridge, England : 2003)》2005,(9):1583-1590
This study reports substituent effects of iridium complexes with 1-phenylisoquinoline ligands. The emission spectra and phosphorescence quantum yields of the complexes differ from that of tris(1-phenylisoquinolinato-C2,N)iridium(iii)(Irpiq) depending on the substituents. The maximum emission peak, quantum yield and lifetime of those complexes ranged from 598-635 nm, 0.17-0.32 and 1.07-2.34 micros, respectively. This indicates the nature of the substituents has a significant influence on the kinetics of the excited-state decay. The substituents attached to phenyl ring have an influence on a stability of the HOMO. Furthermore, those substituents have effect on the contribution to a mixing between 3pi-pi* and (3)MLCT for the lowest excited states. Some of the complexes display the larger quantum yield than Irpiq, which has the quantum yield of 0.22. The organic light emitting diode (OLED) device based on tris [1-(4-fluoro-5-methylphenyl)isoquinolinato-C2,N]iridium(iii)(Ir4F5Mpiq) yielded high external quantum efficiency of 15.5% and a power efficiency of 12.4 lm W(-1) at a luminance of 218 cd m(-2). An emission color of the device was close to an NTSC specification with CIE chromaticity characteristics of (0.66, 0.34). 相似文献
127.
We experimentally demonstrate continuous-variable quantum teleportation beyond the no-cloning limit. We teleport a coherent state and achieve the fidelity of 0.70 +/- 0.02 that surpasses the no-cloning limit of 2/3. Surpassing the limit is necessary to transfer the nonclassicality of an input quantum state. By using our high-fidelity teleporter, we demonstrate entanglement swapping, namely, teleportation of quantum entanglement, as an example of transfer of nonclassicality. 相似文献
128.
Fuji T Rauschenberger J Apolonski A Yakovlev VS Tempea G Udem T Gohle C Hänsch TW Lehnert W Scherer M Krausz F 《Optics letters》2005,30(3):332-334
A new scheme for stabilizing the carrier-envelope (CE) phase of a few-cycle laser pulse train is demonstrated. Self-phase modulation and difference-frequency generation in a single periodically poled lithium niobate crystal that transmits the main laser beam allows CE phase locking directly in the usable output. The monolithic scheme obviates the need for splitting off a fraction of the laser output for CE phase control, coupling into microstructured fiber, and separation and recombination of spectral components. As a consequence, the output yields 6-fs, 800-nm pulses with an unprecedented degree of short- and long-term reproducibility of the electric field waveform. 相似文献
129.
Rösch O Gunnarsson O Zhou XJ Yoshida T Sasagawa T Fujimori A Hussain Z Shen ZX Uchida S 《Physical review letters》2005,95(22):227002
We present angle-resolved photoemission spectroscopy (ARPES) data on undoped La2CuO4, indicating polaronic coupling between bosons and charge carriers. Using a shell model, we calculate the electron-phonon coupling and find that it is strong enough to give self-trapped polarons. We develop an efficient method for calculating ARPES spectra in undoped systems. Using the calculated couplings, we find the width of the phonon sideband in good agreement with experiment. We analyze reasons for the observed dependence of the width on the binding energy. 相似文献
130.
Huang DJ Chang CF Jeng HT Guo GY Lin HJ Wu WB Ku HC Fujimori A Takahashi Y Chen CT 《Physical review letters》2004,93(7):077204
We present measurements of the spin and orbital magnetic moments of Fe3O4 by using SQUID and magnetic circular dichroism in soft x-ray absorption. The measurements show that Fe3O4 has a noninteger spin moment, in contrast to its predicted half-metallic feature. Fe3O4 also exhibits a large unquenched orbital moment. Calculations using the local density approximation including the Hubbard U method and the configuration interaction cluster-model suggest that strong correlations and spin-orbit interaction of the 3d electrons result in the noninteger spin and large orbital moments of Fe3O4. 相似文献