首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2795篇
  免费   94篇
  国内免费   8篇
化学   2112篇
晶体学   38篇
力学   22篇
数学   58篇
物理学   667篇
  2022年   23篇
  2021年   19篇
  2020年   41篇
  2019年   47篇
  2018年   34篇
  2017年   19篇
  2016年   56篇
  2015年   55篇
  2014年   65篇
  2013年   116篇
  2012年   113篇
  2011年   122篇
  2010年   69篇
  2009年   70篇
  2008年   177篇
  2007年   141篇
  2006年   174篇
  2005年   170篇
  2004年   183篇
  2003年   125篇
  2002年   101篇
  2001年   64篇
  2000年   48篇
  1999年   56篇
  1998年   27篇
  1997年   31篇
  1996年   45篇
  1995年   45篇
  1994年   31篇
  1993年   23篇
  1992年   56篇
  1991年   44篇
  1990年   31篇
  1989年   35篇
  1988年   24篇
  1987年   33篇
  1986年   33篇
  1985年   31篇
  1984年   20篇
  1983年   18篇
  1982年   27篇
  1981年   22篇
  1980年   31篇
  1979年   21篇
  1978年   17篇
  1977年   17篇
  1976年   13篇
  1975年   20篇
  1974年   21篇
  1973年   25篇
排序方式: 共有2897条查询结果,搜索用时 31 毫秒
21.
A Q-algebra can be represented as an operator algebra on an infinite dimensional Hilbert space. However we don’t know whether a finite n-dimensional Q-algebra can be represented on a Hilbert space of dimension n except n = 1, 2. It is known that a two dimensional Q-algebra is just a two dimensional commutative operator algebra on a two dimensional Hilbert space. In this paper we study a finite n-dimensional semisimple Q-algebra on a finite n-dimensional Hilbert space. In particular we describe a three dimensional Q-algebra of the disc algebra on a three dimensional Hilbert space. Our studies are related to the Pick interpolation problem for a uniform algebra.  相似文献   
22.
Let a physical body Ω in ?2 or ?3 be given. Assume that the electric conductivity distribution inside Ω consists of conductive inclusions in a known smooth background. Further, assume that a subset Γ ? ?Ω is available for boundary measurements. It is proved using hyperbolic geometry that certain information about the location of the inclusions can be exactly recovered from static electric measurements on Γ. More precisely: given a ball B with center outside the convex hull of Ω and satisfying (B? ∩ ?Ω) ? Γ, boundary measurements on Γ with explicitly given Dirichlet data are enough to determine whether B intersects the inclusion. An approximate detection algorithm is introduced based on the theory. Numerical experiments in dimension two with simulated noisy data suggest that the algorithm finds the inclusion‐free domain near Γ and is robust against measurement noise. © 2007 Wiley Periodicals, Inc.  相似文献   
23.
24.
We have investigated the magnetic and magneto-transport properties of a systematic sequence of five InAs/Mn digital alloys grown by a combination of molecular beam epitaxy and atomic layer epitaxy. The samples consist of 30 periods of Mn fractional monolayers (ML) (0.17–0.5 ML) separated by 14 ML thick InAs spacer layers in a superlattice configuration. Four samples show n-type electrical conduction while the fifth (0.25 ML Mn) is p-type. Squid magnetization measurements performed on these samples show remnant magnetization above room temperature, which is apparently related to a second phase.  相似文献   
25.
P-Chirogenic trialkylphosphonium salts were prepared from the corresponding free phosphines by treatment with a strong acid (HBF4 or HOTf). No racemization of the phosphonium salts occurred in methanol or water even at considerably high temperature. The salts were conveniently used in rhodium-catalyzed asymmetric hydrogenation of enamides.  相似文献   
26.
Copper(II) is determined by non-extractive spectrophotometry as a complex of butylene dithiocarbamate formed in situ by reaction between carbon disulfide and pyrrolidine in aqueous Triton X-100 medium. This method is similar to that with butylene dithiocarbamate as starting material in the sense of simplicity, sensitivity, precision and accuracy. Pyrrolidine is the best of seven secondary amines tested in this way for copper determinations.  相似文献   
27.
Current on-line solid-phase extraction methods combined with HPLC for shortening the clean-up operation are not suitable for simultaneously detecting compounds that have a wide variety of hydrophobicities. To solve these problems, we designed a new on-line sample preparation system. The system consists of an eluting pump, a mixing TEE connector, a 10-port 2-position valve and a solid-phase extraction precolumn. The eluate from the precolumn is diluted with a weak solvent from the HPLC at the TEE connection to load low hydrophobic compounds onto the analytical column. The proposed on-line sample preparation system was successfully applied to the simultaneous analysis of 21 pesticides in river water using LC/TOF-MS. In this method, the recoveries from river water samples were 67 to 126% (mean 83%), the reproducibility (CV%) was in the range from 1.1 to 11% (mean 5.6%), the calibration curve was linear in the range from 1 ppb to 500 ppb (r > 0.999) and the detection limits (S/N = 3) were in the range from 0.0034 ppb (daimuron) to 3.3 ppb (oxine-copper).  相似文献   
28.
In this study, we attempted to control the timing of light-emission from bioluminescent bacteria, by changed cell numbers inoculated into medium. Luminous bacteria express bioluminescence when the number of cells reached a threshold. Inoculated cell density had an effect on the time of bioluminescence starting. Samples were prepared by varying cell density of inoculation. In the results, all the vials showed different luminescence profiles in the order of inoculated cell population.  相似文献   
29.
30.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号