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271.
AlCl(3) solution was analyzed at concentrations from 0.02 to 100 mM using an electrospray ionization quadrupole mass spectrometer (ESI-Q-MS), and the dissolution state of aluminum ions is discussed. Results obtained using ESI-Q-MS were consistent with those obtained using (27)Al nuclear magnetic resonance ((27)Al NMR). Aluminum species existed mainly as positively charged monomeric aluminum hydroxide coordinated with several water molecules in solution. The complexation of chloride ions by aluminum ions differed between the positive and negative ion modes. Chemical reactions that partially modified chemical forms of species through ESI-Q-MS measurement were also observed. In the same aluminum chloride solution, using ESI-TOF-MS and ESI-Q-MS/MS studies, the disagreement of the reports is discussed. It is concluded that ESI-TOF-MS might show also the gas-phase reaction in the mass spectrometer but the dissolution state of aluminum species can be shown by ESI-Q-MS. 相似文献
272.
Miniaturization of chemical or biochemical systems creates extremely efficient devices exploiting the advantages of microspaces. Although they are often targeted for implanted tissue engineered organs or drug-delivery devices because of their highly integrated systems, microfluidic devices are usually powered by external energy sources and therefore difficult to be used in vivo. A microfluidic device powered without the need for external energy sources or stimuli is needed. Previously, we demonstrated the concept of a cardiomyocyte pump using only chemical energy input to cells as a driver (Yo Tanaka, Keisuke Morishima, Tatsuya Shimizu, Akihiko Kikuchi, Masayuki Yamato, Teruo Okano and Takehiko Kitamori, Lab Chip, 6(3), pp. 362-368). However, the structure of this prototype pump described there included complicated mechanical components and fabricated compartments. Here, we have created a micro-spherical heart-like pump powered by spontaneously contracting cardiomyocyte sheets driven without a need for external energy sources or coupled stimuli. This device was fabricated by wrapping a beating cardiomyocyte sheet exhibiting large contractile forces around a fabricated hollow elastomeric sphere (5 mm diameter, 250 microm polymer thickness) fixed with inlet and outlet ports. Fluid oscillations in a capillary connected to the hollow sphere induced by the synchronously pulsating cardiomyocyte sheet were confirmed, and the device continually worked for at least 5 days in this system. This bio/artificial hybrid fluidic pump device is innovative not only because it is driven by cells using only chemical energy input, but also because the design is an optimum structure (sphere). We anticipate that this device might be applied for various purposes including a bio-actuator for medical implant devices that relies on biochemical energy, not electrical interfacing. 相似文献
273.
Sawada H Takahashi K Mugisawa M Oya T Ogino S 《Langmuir : the ACS journal of surfaces and colloids》2007,23(24):11947-11950
Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide--acryloylmorpholine co-oligomers were prepared by the co-oligomerizations of fluoroalkanoyl peroxides with the corresponding monomers. These fluorinated co-oligomers exhibited a lower critical solution temperature (LCST) characteristic in aqueous solutions. Of particular interest, a steep time dependence of contact angle values for dodecane was observed from 40 to 60 degrees C to decrease their values, effectively, on the modified PMMA [poly(methyl methacrylate)] film surface treated with fluorinated co-oligomer possessing the LCST: 36 degrees C (in water), although such a steep time dependence was not observed from 20 to 30 degrees C. 相似文献
274.
Kenta Sugawara Yamato Hayashi Jun Fukushima Hirotsugu Takizawa 《Crystal Research and Technology》2015,50(4):319-330
A new facile process has been developed to synthesize silver nanowire transparent conductive films by reducing high‐aspect‐ratio, needle‐shaped silver carboxylates, prepared as the precursor, while retaining their morphology. Nanowire precursors are simply obtained by ultrasound irradiation when silver (I) oxide and carboxylic acids are used as starting materials. The aspect ratio of the precursors is increased when the ultrasound irradiation is followed by microwave irradiation. Silver nanowires can be easily obtained by reducing these precursors with hydrazine gas or irradiating them with Ar plasma for a short time. The morphology of the resulting nanowires is different from that of typical nanowires that have been reported. The nanowires have porous morphology, where small nanoparticles are connected to form nanobeadwire. The nanobeadwire is considered to increase the transparency of the film because of its rough morphology. This new method can synthesize silver nanobeadwires and fabricate the transparent conductive film simultaneously, in one‐step, so that it can significantly simplify manufacturing processes. 相似文献
275.
Mark A. Kline Xiaoxi Wei Ian J. Horner Rui Liu Shuang Chen Si Chen Ka Yi Yung Kazuhiro Yamato Zhonghou Cai Frank V. Bright Xiao Cheng Zeng Bing Gong 《Chemical science》2015,6(1):152-157
As the third-generation rigid macrocycles evolved from progenitor 1, cyclic aromatic oligoamides 3, with a backbone of reduced constraint, exhibit extremely strong stacking with an astoundingly high affinity (estimated lower limit of K
dimer > 1013 M–1 in CHCl3), which leads to dispersed tubular stacks that undergo further assembly in solution. Computational study reveals a very large binding energy (–49.77 kcal mol–1) and indicates highly cooperative local dipole interactions that account for the observed strength and directionality for the stacking of 3. In the solid-state, X-ray diffraction (XRD) confirms that the aggregation of 3 results in well-aligned tubular stacks. The persistent tubular assemblies of 3, with their non-deformable sub-nm pore, are expected to possess many interesting functions. One such function, transmembrane ion transport, is observed for 3. 相似文献
276.
277.
278.
Alaa A. Hassan Yusria R. Ibrahim Ashraf A. Aly Essmat M. El‐Sheref Takehiko Yamato 《Journal of heterocyclic chemistry》2013,50(3):473-477
The reaction of (substituted ethylidene)hydrazinecarbothioamides 4a , 4b , 4c , 4d , 4e , 4f , 4g with dimethyl ethynedicarboxylate ( DMAD , 2 ) gave [(substituted ethylidene)hydrazono)‐4‐oxothiazolidine‐5‐ylidene]acetates 7a , 7b , 7c , 7d , 7e , 7f , 7g (71–88 %). The structure of the new compounds was established by infrared spectroscopy, mass spectrometry, and NMR spectroscopy. 相似文献
279.
A new concept for improving the laser intensity distribution on an inertial confinement fusion target using a phase-controlled multi lens array has been proposed. Circular and hexagonal element lens apertures have been examined, and the circular aperture which eliminated azimuthally asymmetric intensity distribution was chosen. The diffraction fringe of the elementary lens was mitigated in a one-dimensional lens array using edge-shaped plates of a super-Gaussian phase profile. Uniform beam profiles were obtained using a one-dimensional array with 7 spherical lenses and a two-dimensional array with 37 lenses. An approximately flat-top intensity distribution was realized with the lens array with 37 lenses. 相似文献
280.