全文获取类型
收费全文 | 555篇 |
免费 | 31篇 |
国内免费 | 4篇 |
专业分类
化学 | 408篇 |
晶体学 | 23篇 |
力学 | 6篇 |
数学 | 14篇 |
物理学 | 139篇 |
出版年
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 7篇 |
2020年 | 12篇 |
2019年 | 12篇 |
2018年 | 11篇 |
2017年 | 8篇 |
2016年 | 12篇 |
2015年 | 14篇 |
2014年 | 12篇 |
2013年 | 31篇 |
2012年 | 19篇 |
2011年 | 25篇 |
2010年 | 18篇 |
2009年 | 11篇 |
2008年 | 28篇 |
2007年 | 17篇 |
2006年 | 22篇 |
2005年 | 35篇 |
2004年 | 18篇 |
2003年 | 29篇 |
2002年 | 22篇 |
2001年 | 28篇 |
2000年 | 25篇 |
1999年 | 7篇 |
1998年 | 8篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 8篇 |
1992年 | 17篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1985年 | 12篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 7篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1974年 | 3篇 |
1972年 | 2篇 |
1968年 | 2篇 |
1965年 | 3篇 |
排序方式: 共有590条查询结果,搜索用时 15 毫秒
11.
Allylation of carbonucleophiles with allylic carbamates under neutral conditions has been studied. The C-allylation of carbonucleophile is competitive with the N-allylation of amines, and the structure of amines is crucial for the selectivity. Bulky secondary amines gave the best results. Also a new method of protection-deprotection of amines as carbamates has been developed. Smooth deprotection is possible by the palladium-catalyzed reaction of allyl carbamates with formic acid. This method is particulary useful for primary amines, including optically active amino acids. 相似文献
12.
13.
Dehydrroxy-trans-resorcylide () was synthesized by efficient intramolecular alkylation of the protected cyanohydrin. The butadiene telomer obtained by the palladium catalyzed reaction of butadiene with acetic acid was used as a suitable block of the carbocycle. 相似文献
14.
15.
Kiyoharu Tadanaga Kazuki Iwashita Tsutomu Minami Noboru Tohge 《Journal of Sol-Gel Science and Technology》1996,6(1):107-111
Nylon-6 substrates were coated with SiO2 thin films by the sol-gel method and their water permeability coefficient was evaluated. Methyltriethoxysilane (MTES) and tetraethoxysilane (TEOS) were used as starting materials. The addition of MTES to TEOS has enabled the formation of crack-free thin films on the substrates. The thin films strongly adhered to the substrates. The water permeability coefficients of nylon-6 substrates coated with these thin films decreased with the increase in the ratio of TEOS to the total alkoxides. The pretreatment of the nylon-6 substrates with -aminopropyltriethoxysilane was found to be effective to suppress the water permeability. The water permeability was suppressed by about 40% under the optimal condition. 相似文献
16.
Takaharu Otsuka 《Hyperfine Interactions》1993,78(1-4):19-34
Magnetic dipole and electric quadrupole moments are discussed in terms of the interacting boson model (IBM) and the shell model. From the viewpoint of the IBM, systematic variations of magnetic moments will be discussed by analyzing data of Xe and Ba isotopes. Magnetic and quadrupole moments of various states of Sm and Os isotopes are discussed, pointing out an open problem in the magnetic moments of Os isotopes. The importance of measuring the quadrupole moment of O(6) or -unstable nuclei is emphasized by the example of128Xe. The structure of neutron-rich unstable nuclei will be studied in terms of the shell model, by paying attention to the break-down of the closed shell structure, for instance, the collapse ofN=20 closed shell withZN=20. The magnetic moment of the anomalous ground state of11Be is another topic of this discussion, and it is studied in terms of a new theoretical framework called variational shell model. 相似文献
17.
A general method for acylation of indoles at the 3-position with acyl chlorides in the presence of dialkylaluminum chloride 总被引:1,自引:0,他引:1
[reaction--see text] Indoles are selectively acylated at the 3-position in high yields on treatment with a wide variety of acyl chlorides in CH(2)Cl(2) in the presence of diethylaluminum chloride or dimethylaluminum chloride. The reaction proceeds under mild conditions and is applicable to indoles bearing various functional groups without NH protection. 相似文献
18.
Large-scale separation of metallic and semiconducting single-walled carbon nanotubes 总被引:6,自引:0,他引:6
Maeda Y Kimura S Kanda M Hirashima Y Hasegawa T Wakahara T Lian Y Nakahodo T Tsuchiya T Akasaka T Lu J Zhang X Gao Z Yu Y Nagase S Kazaoui S Minami N Shimizu T Tokumoto H Saito R 《Journal of the American Chemical Society》2005,127(29):10287-10290
In the applications of single-walled carbon nanotubes (SWNTs), it is extremely important to separate semiconducting and metallic SWNTs. Although several methods have been reported for the separation, only low yields have been achieved at great expense. We show a separation method involving a dispersion-centrifugation process in a tetrahydrofuran solution of amine, which makes metallic SWNTs highly concentrated to 87% in a simple way. 相似文献
19.
Syuji?Fujii Hideto?Minami Masayoshi?OkuboEmail author 《Colloid and polymer science》2004,282(6):569-574
Poly(methyl methacrylate) (PMMA) particles were produced by dispersion polymerization of methyl methacrylate in the presence of mercaptopropyl terminated poly(dimethylsiloxane) (MP-PDMS) in supercritical carbon dioxide at about 30 MPa for 24 h at 65 °C. The particle diameter could be controlled in a size range of submicron to micron by varying MP-PDMS concentration. The MP-PDMS worked as not only a chain transfer agent but also a colloidal stabilizer, which was named tran
stab.Part CCLI of the series Studies on suspension and emulsion 相似文献
20.
The ionic conductivity was measured in the temperature range 250–300 K as a function of composition of superionic conducting glasses in the pseudobinary system AgIAg2MoO4. The conductivity, ranging from 10?2 to 10?4 Ω?1 cm?1 at room temperature, increases linearly in logarithmic scale with increasing AgI content, while the total silver ion concentration remains nearly constant in the whole glass-forming region of the present system. Such a composition dependence of conductivity is considered to be evidence that only a fraction of the silver ions in glass contributes to the ionic conduction. The conductivity and the activation energy for conduction differ slightly between bulk glasses and pressed pellets of pulverized glasses. The close agreement in bulk glasses and pellets suggests that bulk rather than grain boundary or surface diffusion dominates the conduction process in the present glasses. 相似文献