全文获取类型
收费全文 | 866篇 |
免费 | 29篇 |
国内免费 | 1篇 |
专业分类
化学 | 707篇 |
晶体学 | 5篇 |
力学 | 16篇 |
数学 | 30篇 |
物理学 | 138篇 |
出版年
2023年 | 5篇 |
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 16篇 |
2019年 | 20篇 |
2018年 | 9篇 |
2016年 | 23篇 |
2015年 | 17篇 |
2014年 | 30篇 |
2013年 | 68篇 |
2012年 | 44篇 |
2011年 | 38篇 |
2010年 | 32篇 |
2009年 | 35篇 |
2008年 | 42篇 |
2007年 | 46篇 |
2006年 | 45篇 |
2005年 | 40篇 |
2004年 | 34篇 |
2003年 | 32篇 |
2002年 | 21篇 |
2001年 | 14篇 |
2000年 | 12篇 |
1999年 | 12篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1996年 | 11篇 |
1995年 | 11篇 |
1994年 | 20篇 |
1993年 | 6篇 |
1992年 | 17篇 |
1991年 | 10篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1987年 | 7篇 |
1985年 | 8篇 |
1984年 | 7篇 |
1983年 | 7篇 |
1982年 | 8篇 |
1981年 | 12篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1978年 | 11篇 |
1977年 | 10篇 |
1976年 | 12篇 |
1975年 | 8篇 |
1974年 | 6篇 |
1973年 | 5篇 |
1972年 | 7篇 |
1966年 | 3篇 |
排序方式: 共有896条查询结果,搜索用时 15 毫秒
131.
132.
133.
134.
135.
[structure: see text] An effective method for the total synthesis of 2-hydroxy-24-oxooctacosanolide, a defensive salivary secretion of the African termite Pseudacanthotermes spiniger, has been developed. The key lactonization to form a 29-membered ring lactone core is performed using 2-methyl-6-nitrobenzoic anhydride with a catalytic amount of 4-(dimethylamino)pyridine N-oxide. 相似文献
136.
Eduardo Viegas Misako Takayasu Wataru Miura Koutarou Tamura Takaaki Ohnishi Hideki Takayasu Henrik Jeldtoft Jensen 《Complexity》2013,19(1):22-36
The world economy consists of highly interconnected and interdependent commercial and financial networks. Here, we develop temporal and structural network tools to analyze the state of the economy and the financial markets. Our analysis indicates that a strong clustering can be a warning sign. Reduction in diversity, which was an essential aspect of the dynamics surrounding the financial markets crisis of 2008, is seen as a key emergent feature arising naturally from the evolutionary and adaptive dynamics inherent to the financial markets. Similarly, collusion amongst construction firms in a number of regions in Japan in the 2000s can be identified with the formation of clusters of anomalous highly connected companies. © 2013 Wiley Periodicals, Inc. Complexity 19: 22–36, 2013 相似文献
137.
Takaaki Takatsuka Hideki Tomita Tetsu Sonoda Volker Sonnenschein Chika Sakamoto Hiroki Mita Takuma Noto Chikara Ito Shigetaka Maeda Tetsuo Iguchi Michiharu Wada Klaus Wendt Iain Moore 《Hyperfine Interactions》2013,216(1-3):41-46
93Nb(n, n′)93mNb reaction allows retrospective estimation of integrated fast neutron dose in nuclear reactor. We proposed isomer-selective trace analysis of 93mNb by Resonance Ionization Mass Spectrometry (RIMS) combined with a gas-jet atomic source and an injection locked Ti:Sapphire laser system operated at several kHz. Resonant ionization spectroscopy of Nb in gas-jet using Ti:Sapphire laser was demonstrated. 相似文献
138.
Ying Xu Hosho Katsura Takaaki Hirano Vladimir E. Korepin 《Journal of statistical physics》2008,133(2):347-377
We study a 1-dimensional AKLT spin chain, consisting of spins S in the bulk and S/2 at both ends. The unique ground state of this AKLT model is described by the Valence-Bond-Solid (VBS) state. We investigate
the density matrix of a contiguous block of bulk spins in this ground state. It is shown that the density matrix is a projector
onto a subspace of dimension
. This subspace is described by non-zero eigenvalues and corresponding eigenvectors of the density matrix. We prove that for
large block the von Neumann entropy coincides with Renyi entropy and is equal to
.
NSF Grant DMS-0503712. 相似文献
139.
Conventionally, the Fourier transform is applied for sound intensity analysis of stationary signals, but this method can be applied for analyzing non-stationary transient signals. Instead of the Fourier transform analysis, instantaneous spectrum analysis methods such as the Wigner-Ville distribution and the wavelet transform are proposed. By using the mathematical example as a transient signal, advantages and disadvantages of these methods including the short-time Fourier transform are compared. From calculation results, it is considered that the STFT method is the most suitable for the accurate measurement of sound intensity levels, but the WT method is also recommended from its higher resolution of transient signals. 相似文献
140.
Haruka Takeuchi Prof. Dr. Shinsuke Inuki Kohei Nakagawa Takaaki Kawabe Dr. Atsuhiko Ichimura Prof. Dr. Shinya Oishi Prof. Dr. Hiroaki Ohno 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(47):21396-21401
We report herein a nonbiomimetic strategy for the total synthesis of the plicamine-type alkaloids zephycarinatines C and D. The key feature of the synthesis is a stereoselective reductive radical ipso-cyclization using visible-light-mediated photoredox catalysis. This cyclization enabled the construction of a 6,6-spirocyclic core structure through the addition of a carbon-centered radical onto the aromatic ring. Biological evaluation of zephycarinatines and their derivatives revealed that the synthetic derivative with a keto group displays moderate inhibitory activity against LPS-induced NO production. This approach could offer future opportunities to expand the chemical diversity of plicamine-type alkaloids as well as providing useful intermediates for their syntheses. 相似文献