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101.
102.
[structure: see text] An effective method for the total synthesis of 2-hydroxy-24-oxooctacosanolide, a defensive salivary secretion of the African termite Pseudacanthotermes spiniger, has been developed. The key lactonization to form a 29-membered ring lactone core is performed using 2-methyl-6-nitrobenzoic anhydride with a catalytic amount of 4-(dimethylamino)pyridine N-oxide. 相似文献
103.
Kurata S 《Molecular diversity》2006,10(4):599-605
Summary The elimination of infectious non-self by the host defense systems of multicellular organisms requires a variety of recognition and effector molecules. The diversity is generated in somatic cells or encoded in the germ-line. In adaptive immunity in jawed vertebrates, the diversity of immunoglobulins and antigen receptors is generated by gene rearrangements in somatic cells. In innate immunity, various effector molecules and pattern recognition receptors, such as antimicrobial peptides and peptidoglycan recognition proteins, are encoded in the germ-line of multicellular organisms, including insects and jawed vertebrates. In the present review, we discuss how insect host defense systems recognize and eliminate a multitude of microbes via germ-line-encoded molecules, including recent findings that a Drosophila member of the immunoglobulin superfamily is extensively diversified by alternative splicing in somatic immune cells and participates in the elimination of bacteria. 相似文献
104.
Eduardo Viegas Misako Takayasu Wataru Miura Koutarou Tamura Takaaki Ohnishi Hideki Takayasu Henrik Jeldtoft Jensen 《Complexity》2013,19(1):22-36
The world economy consists of highly interconnected and interdependent commercial and financial networks. Here, we develop temporal and structural network tools to analyze the state of the economy and the financial markets. Our analysis indicates that a strong clustering can be a warning sign. Reduction in diversity, which was an essential aspect of the dynamics surrounding the financial markets crisis of 2008, is seen as a key emergent feature arising naturally from the evolutionary and adaptive dynamics inherent to the financial markets. Similarly, collusion amongst construction firms in a number of regions in Japan in the 2000s can be identified with the formation of clusters of anomalous highly connected companies. © 2013 Wiley Periodicals, Inc. Complexity 19: 22–36, 2013 相似文献
105.
Takaaki Takatsuka Hideki Tomita Tetsu Sonoda Volker Sonnenschein Chika Sakamoto Hiroki Mita Takuma Noto Chikara Ito Shigetaka Maeda Tetsuo Iguchi Michiharu Wada Klaus Wendt Iain Moore 《Hyperfine Interactions》2013,216(1-3):41-46
93Nb(n, n′)93mNb reaction allows retrospective estimation of integrated fast neutron dose in nuclear reactor. We proposed isomer-selective trace analysis of 93mNb by Resonance Ionization Mass Spectrometry (RIMS) combined with a gas-jet atomic source and an injection locked Ti:Sapphire laser system operated at several kHz. Resonant ionization spectroscopy of Nb in gas-jet using Ti:Sapphire laser was demonstrated. 相似文献
106.
Ying Xu Hosho Katsura Takaaki Hirano Vladimir E. Korepin 《Journal of statistical physics》2008,133(2):347-377
We study a 1-dimensional AKLT spin chain, consisting of spins S in the bulk and S/2 at both ends. The unique ground state of this AKLT model is described by the Valence-Bond-Solid (VBS) state. We investigate
the density matrix of a contiguous block of bulk spins in this ground state. It is shown that the density matrix is a projector
onto a subspace of dimension
. This subspace is described by non-zero eigenvalues and corresponding eigenvectors of the density matrix. We prove that for
large block the von Neumann entropy coincides with Renyi entropy and is equal to
.
NSF Grant DMS-0503712. 相似文献
107.
Conventionally, the Fourier transform is applied for sound intensity analysis of stationary signals, but this method can be applied for analyzing non-stationary transient signals. Instead of the Fourier transform analysis, instantaneous spectrum analysis methods such as the Wigner-Ville distribution and the wavelet transform are proposed. By using the mathematical example as a transient signal, advantages and disadvantages of these methods including the short-time Fourier transform are compared. From calculation results, it is considered that the STFT method is the most suitable for the accurate measurement of sound intensity levels, but the WT method is also recommended from its higher resolution of transient signals. 相似文献
108.
Haruka Takeuchi Prof. Dr. Shinsuke Inuki Kohei Nakagawa Takaaki Kawabe Dr. Atsuhiko Ichimura Prof. Dr. Shinya Oishi Prof. Dr. Hiroaki Ohno 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(47):21396-21401
We report herein a nonbiomimetic strategy for the total synthesis of the plicamine-type alkaloids zephycarinatines C and D. The key feature of the synthesis is a stereoselective reductive radical ipso-cyclization using visible-light-mediated photoredox catalysis. This cyclization enabled the construction of a 6,6-spirocyclic core structure through the addition of a carbon-centered radical onto the aromatic ring. Biological evaluation of zephycarinatines and their derivatives revealed that the synthetic derivative with a keto group displays moderate inhibitory activity against LPS-induced NO production. This approach could offer future opportunities to expand the chemical diversity of plicamine-type alkaloids as well as providing useful intermediates for their syntheses. 相似文献
109.
Bo Huang Hirokazu Kobayashi Tomokazu Yamamoto Takaaki Toriyama Syo Matsumura Yoshihide Nishida Katsutoshi Sato Katsutoshi Nagaoka Masaaki Haneda Wei Xie Yusuke Nanba Michihisa Koyama Fenglong Wang Shogo Kawaguchi Yoshiki Kubota Hiroshi Kitagawa 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(8):2252-2257
Ru is an important catalyst in many types of reactions. Specifically, Ru is well known as the best monometallic catalyst for oxidation of carbon monoxide (CO) and has been practically used in residential fuel cell systems. However, Ru is a minor metal, and the supply risk often causes violent fluctuations in the price of Ru. Performance‐improved and cost‐reduced solid‐solution alloy nanoparticles of the Cu‐Ru system for CO oxidation are now presented. Over the whole composition range, all of the CuxRu1?x nanoparticles exhibit significantly enhanced CO oxidation activities, even at 70 at % of inexpensive Cu, compared to Ru nanoparticles. Only 5 at % replacement of Ru with Cu provided much better CO oxidation activity, and the maximum activity was achieved by 20 at % replacement of Ru by Cu. The origin of the high catalytic performance was found as CO site change by Cu substitution, which was investigated using in situ Fourier transform infrared spectra and theoretical calculations. 相似文献
110.
Dongshuang Wu Kohei Kusada Tomokazu Yamamoto Takaaki Toriyama Syo Matsumura Ibrahima Gueye Okkyun Seo Jaemyung Kim Satoshi Hiroi Osami Sakata Shogo Kawaguchi Yoshiki Kubota Hiroshi Kitagawa 《Chemical science》2020,11(47):12731
We report the synthesis of high-entropy-alloy (HEA) nanoparticles (NPs) consisting of five platinum group metals (Ru, Rh, Pd, Ir and Pt) through a facile one-pot polyol process. We investigated the electronic structure of HEA NPs using hard X-ray photoelectron spectroscopy, which is the first direct observation of the electronic structure of HEA NPs. Significantly, the HEA NPs possessed a broad valence band spectrum without any obvious peaks. This implies that the HEA NPs have random atomic configurations leading to a variety of local electronic structures. We examined the hydrogen evolution reaction (HER) and observed a remarkably high HER activity on HEA NPs. At an overpotential of 25 mV, the turnover frequencies of HEA NPs were 9.5 and 7.8 times higher than those of a commercial Pt catalyst in 0.05 M H2SO4 and 1.0 M KOH electrolytes, respectively. Moreover, the HEA NPs showed almost no loss during a cycling test and were much more stable than the commercial Pt catalyst. Our findings on HEA NPs may provide a new paradigm for the design of catalysts.RuRhPdIrPt high-entropy-alloy nanoparticles with a broad and featureless valence band spectrum show high hydrogen evolution reaction activity. 相似文献