首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   12601篇
  免费   1034篇
  国内免费   702篇
化学   8444篇
晶体学   121篇
力学   499篇
综合类   51篇
数学   1484篇
物理学   3738篇
  2023年   159篇
  2022年   293篇
  2021年   292篇
  2020年   308篇
  2019年   326篇
  2018年   253篇
  2017年   264篇
  2016年   404篇
  2015年   415篇
  2014年   485篇
  2013年   722篇
  2012年   899篇
  2011年   1025篇
  2010年   651篇
  2009年   676篇
  2008年   769篇
  2007年   734篇
  2006年   647篇
  2005年   561篇
  2004年   532篇
  2003年   455篇
  2002年   404篇
  2001年   330篇
  2000年   270篇
  1999年   206篇
  1998年   162篇
  1997年   139篇
  1996年   175篇
  1995年   131篇
  1994年   150篇
  1993年   124篇
  1992年   117篇
  1991年   96篇
  1990年   106篇
  1989年   82篇
  1988年   90篇
  1987年   61篇
  1986年   69篇
  1985年   95篇
  1984年   69篇
  1983年   68篇
  1982年   49篇
  1981年   46篇
  1980年   47篇
  1979年   34篇
  1977年   37篇
  1976年   37篇
  1975年   34篇
  1974年   48篇
  1973年   44篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
Plant-parasitic nematodes infect a diversity of crops, resulting in severe economic losses in agriculture. Microbial volatile organic compounds (VOCs) are potential agents to control plant-parasitic nematodes and other pests. In this study, VOCs emitted by a dozen bacterial strains were analyzed using solid-phase microextraction followed by gas chromatography–mass spectrometry. Fumigant toxicity of selected VOCs, including dimethyl disulfide (DMDS), 2-butanone, 2-pentanone, 2-nonanone, 2-undecanone, anisole, 2,5-dimethylfuran, glyoxylic acid, and S-methyl thioacetate (MTA) was then tested against Caenorhabditis elegans. DMDS and MTA exhibited much stronger fumigant toxicity than the others. Probit analysis suggested that the values of LC50 were 8.57 and 1.43 μg/cm3 air for DMDS and MTA, respectively. MTA also showed stronger fumigant toxicity than DMDS against the root-knot nematode Meloidogyne incognita, suggesting the application potential of MTA.  相似文献   
122.
在模拟生理条件下,用荧光光谱法研究了诺氟沙星对牛血清白蛋白以及锌(Ⅱ)对诺氟沙星和牛血清白蛋白荧光光谱特性的影响。实验结果表明,诺氟沙星和锌(Ⅱ)都可以使牛血清白蛋白的荧光强度发生猝灭。根据荧光猝灭双倒数图计算诺氟沙星和牛血清白蛋白之间的结合常数为6.80×105,结合位点数为1.21。由此可见,诺氟沙星和牛血清白蛋白之间有很强的结合作用,这为诺氟沙星在体内被蛋白质储存和转运提供了条件。并且在锌(Ⅱ)存在下,诺氟沙星与牛血清白蛋白的结合作用有所增强。荧光猝灭双倒数图计算的结果表明,诺氟沙星和牛血清白蛋白之间的结合常数和结合位点数均随锌(Ⅱ)浓度的增大而增大。通过对锌(Ⅱ)、诺氟沙星和牛血清白蛋白的结合反应的研究,进一步探讨了诺氟沙星、锌(Ⅱ)在生物体内与蛋白质相互作用的机理。  相似文献   
123.
同轴引出相对论返波管   总被引:6,自引:12,他引:6  
 提出一种新型相对论返波管 同轴引出相对论返波管结构。首先,利用KARAT软件对这种结构进行了2.5维全电磁粒子数值模拟,经过参数调整,输出的微波脉冲功率为2.0GW,微波频率为9.28 GHz,转换效率达45%。并在模拟中对电子束与电磁波的作用过程进行了跟踪和分析;然后利用SUPERFISH软件对此结构中的场分布进行了计算,结合PIC模拟结果,初步证明了由于内导体的引入改变了返波管末端的反射,有利于电子束与电磁波的能量交换。  相似文献   
124.
ICP-AES法测定滑石中主次量成分   总被引:3,自引:0,他引:3  
本文报道了采用ICP-AES法测定滑石中的成分。将滑石试样经碳酸钠、硼砂混合熔剂熔融、酸浸取,用电感耦合等离子体原子发射光谱法(ICP-AES)同时测定SiO2,MgO,CaO,Al2O3,Fe2O3,方法回收率在98.8%-104.0%,测定的RSD(n=6)在0.12%-0.24%之间,测试结果与部颁标准的化学分析法基本相符。  相似文献   
125.
We report the first observations of the spin-singlet bottomonium states h(b)(1P) and h(b)(2P). The states are produced in the reaction e(+)e(-)→h(b)(nP)π(+)π(-) using a 121.4 fb(-1) data sample collected at energies near the Υ(5S) resonance with the Belle detector at the KEKB asymmetric-energy e(+)e(-) collider. We determine M[h(b)(1P)]=(9898.2(-1.0-1.1)(+1.1+1.0)) MeV/c(2) and M[h(b)(2P)]=(10,259.8±0.6(-1.0)(+1.4)) MeV/c(2), which correspond to P-wave hyperfine splittings ΔM(HF)=(+1.7±1.5) and (+0.5(-1.2)(+1.6)) MeV/c(2), respectively. The significances of the h(b)(1P) and h(b)(2P) are 5.5σ and 11.2σ, respectively. We find that the production of the h(b)(1P) and h(b)(2P) is not suppressed relative to the production of the Υ(1S), Υ(2S), and Υ(3S).  相似文献   
126.
The structural, vibrational and thermodynamic properties of β-octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (β–HMX) crystal have been studied using the isothermal-isobaric molecular dynamics (NPT-MD) simulations. The variations of cell volume, lattice constants and molecular geometry of solid β–HMX are presented and discussed at different pressure and temperature. It was found that the N–N bond is significantly lengthened with increasing temperature, which suggests that it is relevant to the initial decomposition. An abrupt change at 27 Gpa for the volume and internal geometrical parameters was observed. This is in good accord with the experimental observation that there is a phase transition at 27 GPa, which is clearly due to conformational change, not chemical reaction. The vibrational frequencies at ambient conditions agree well with experimental results, and the pressure/temperature-induced frequency shifts of these modes are discussed. Frequency discontinuity was also observed at pressure when the phase transition occurred. The Grüneisen parameter was obtained using the vibrational frequency.  相似文献   
127.
When arsenides are grown by molecular beam epitaxy at low substrate temperatures, as much as 2% excess arsenic can be incorporated into the epilayer. This excess arsenic is in the form of antisites, but there is also a substantial concentration of gallium vacancies. With anneal, there is a significant decrease in the arsenic antisite and gallium vancancy concentrations as the excess arsenic precipitates. With further anneal, the arsenic precipitates coarsen. This combination of low substrate temperature molecular beam epitaxy and a subsequent anneal results in a broad spectrum of materials, from highly defected epilayers to a two-phase system of semimetallic arsenic precipitates in an arsenide semiconductor matrix. These materials exhibit some very interesting and useful electrical and optical properties.  相似文献   
128.
设计了一套光学对准测量装置,该装置主要由面阵CCD相机、光学镜头、图像处理模块、LED红光光源、球面反光镜组成。介绍了测量原理,测量目标采用等腰三角形排列,通过面阵CCD对目标所反射的图像进行采集,由图像处理模块对该图像进行实时处理,能够同时得到X、Y、Z以及旋转角度等四维坐标数据。推导了光斑图像坐标和被测平面距离等计算公式,并进行了对准精度分析。结果表明,该装置位置误差〈1mm,角度误差为0.24°,实现了高精度、自动、快速对准测量。  相似文献   
129.
Using quantum mechanics GASTEP software package based on the first principle density function theory, the electronic structure and optical properties of Ga1−xAlxAs at different Al constituent are calculated. Result shows that with the increase of Al constituent, the band gap of Ga1−xAlxAs increases and varies from direct band gap to indirect band gap; the absorption band edge and the absorption peak move to high-energy side; the static reflectivity decreases. With the increasing of the incident photon energy, Ga1−xAlxAs shows metal reflective properties in certain energy range. With the increasing of Al constituent, static dielectric constant decreases and the intersection of dielectric function and the x-axis move towards high-energy side; the peak of energy loss function move to low-energy side and the peak value reduces.  相似文献   
130.
The stability of a reflection-mode GaAs photocathode has been investigated by monitoring the photocurrent and the spectral response at room temperature.We observe the photocurrent of the cathode decaying with time in the vacuum system under the action of Cs current,and find that the Cs atoms residing in the vacuum system are helpful in prolonging the life of the cathode.We examine the evolution and analyse the influence of the barrier on the spectral response of the cathode.Our results support the double dipolar model for the explanation of the negative electron affinity effect.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号