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81.
The redox properties of the system Fe(tmphen)3(II/III) (tmphen=3,4,7,8-tetramethyl-1,10-phenanthroline) have been studied in the solvents nitromethane, acetonitrile, propanediol-1,2-carbonate, dimethylformamide, dimethylacetamide, dimethylsulfoxide and of the systems Fe(phen)3(II/III) (phen=1,10-phenanthroline) and Fe(niphen)3(II/III) (niphen=5-nitro-1,10-phenanthroline) in the solvents nitromethane, acetonitrile, propanediol-1,2-carbonate and acetone. The redox potentials of Fe(tmphen)3(II/III) are nearly independent of the solvent suggesting that the system might be used as a reference redox couple similar to the systems ferrocene/ferricinium or bisbiphenylchromium(0/I). In contrast the redox potentials of Fe(niphen)3(II/III) show a significant decrease with increasing donor number of the solvent which can be explained by nucleophilic attack of solvent molecules at the iron. It is shown that such a mechanism is consistent with the known solvent and salt effects on the kinetics of dissociation of ferroin and ferriin type complexes. 相似文献
82.
Ohne Zusammenfassung 相似文献
83.
84.
Kučinskaitė Agnė Pobłocka-Olech Loretta Krauze-Baranowska Mirosława Briedis Vitalis Savickas Aruñas Sznitowska Małgorzata 《平面色谱法杂志一现代薄层色谱法》2007,20(2):121-125
SPE and TLC have been used for qualitative and quantitative analysis of salidroside, rosavin, rosarin, and rosin in commercially available dry extracts from Rhodiola rosea roots. The best separation of all the compounds was achieved on silica gel TLC plates with ethyl acetate—methanol—water, 77 + 13 + 10 (v/v), as mobile phase. UV detection was performed at λ = 215 nm for salidroside and at λ= 245 nm for the rosavins (rosavin, rosarin, and rosin). Detection limits for salidroside and the rosavins were 90 ng and 60 ng per spot, respectively. Results from quantitative analysis confirmed the manufacturer’s declaration of the amounts of salidroside and the rosavins in the extracts.
相似文献85.
Ohne Zusammenfassung 相似文献
86.
The phase analysis of cryolite (Na3AlF6) and sodium metasilicate (Na2SiO3) was performed by thermal analysis. The eutectic system with a region of two immiscible substances at a concentration of Na2SiO3 between 42.8 and 46.3 mol‐% was identified and the eutectic temperature determined to (886±2) °C. Based on the results of mass‐loss measurements, it was assumed that the introduced Na2SiO3 reacts with Na3AlF6 due to the formation of some nonvolatile stable compounds. The stable reaction products were identified by X‐ray diffraction analysis and IR spectroscopy of the spontaneously cooled samples, which established the formation of NaF and stable amorphous aluminosilicate compounds. 相似文献
87.
D. Reichardt V. Bonačić-Koutecký P. Fantucci J. Jellinek 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1997,40(1):486-489
An ab-initio molecular dynamics procedure without precalculation of the Born-Oppenheimer energy surface based on an iterative non-local density functional method employing Gaussian atomic basis has been developed. Analytical gradients are calculated and used for the propagation of nuclei. Sufficiently long trajectories can be calculated at an acceptable computational cost, allowing for analysis of dynamical behaviour of small metallic clusters. This is illustrated on an example of the Li8 cluster. Temperature behaviour of different type of isomers has been investigated. Calculated power spectra allow to identify the presence of more than one isomeric forms along the given trajectories. 相似文献
88.
Laila Čakare Marija Kosec Barbara Malič 《Journal of Sol-Gel Science and Technology》2000,19(1-3):603-606
PbZrO3 (PZ) thin films have been prepared by 2-methoxyethanol route from lead oxide or lead acetate and zirconium n-butoxide. The use of lead oxide as lead source and the seeding layer of TiO2 on Pt/TiO2/SiO2/Si substrate facilitate the formation of the perovskite phase. 相似文献
89.
The paper deals with the problem of the outpatient administration of186Re-HEDP and153Sm-EDTMP for palliative therapy of bone metastases. The subsequent 6 hours stay of the treated patients in a department of nuclear medicine appears to be in compliance with regulations proposed in the Czech Republic as well as with ICRP recommendations. 相似文献
90.
The phase diagrams of the binary system KF-AlF3 as well as the ternary system NaF-KF-AlF3 in the range up to 50 mol% AlF3, were measured using the thermal analysis method. In the system KF-AlF3 the coordinates of the eutectic points are: E
1: 8.0 mol% AlF3, 821.2°C, and E
2: 45.5 mol% AlF3, 565.0°C. In the investigated concentration range of the ternary system 2 eutectic points have been found with the calculated
coordinates: E
1: 36.3 mol% NaF, 62.7 mol% KF, 1.0 mol% AlF3; t=711.2°C; and E
2: 51.9 mol% NaF, 27.4 mol% KF, 20.7 mol% AlF3; t=734.5°C. Other eutectic points lie most probably beyond the investigated part of the system.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献