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1.
Optical waveguide fabrication and integration with a micro-mirror inside photosensitive glass by femtosecond laser direct writing 总被引:1,自引:0,他引:1
Z. Wang K. Sugioka Y. Hanada K. Midorikawa 《Applied Physics A: Materials Science & Processing》2007,88(4):699-704
Photosensitive glass is a potentially important material for micro-fluidic devices that can be integrated with micro-optical
components for biochemical analysis. Here, we demonstrate the fabrication of optical waveguides inside glass by femtosecond
laser direct writing. The influence of the laser parameters on the waveguide properties is investigated, and it is revealed
that the waveguide mode can be well controlled. The single mode is achieved at a low writing energy, while the multimode is
achieved with increasing energy. In spite of a longitudinally elongated elliptical shape of the cross-sectional profile, the
far-field pattern of the single-mode waveguide shows an almost symmetric profile. The measured propagation loss and the coupling
loss are evaluated to be ∼0.6 dB/cm and ∼1.6 dB at a wavelength of 632.8 nm, respectively, under the conditions of 1.0–2.0 μJ
pulse energy and 200–500 μm/s scan speed. The increased optical loss is associated with a higher waveguide mode at higher
writing energy. Furthermore, the integration of waveguides and a micromirror made of a hollow microplate inside the glass
is demonstrated to bend the laser beam at an angle of 90° in a small chip. The bending loss is estimated to be smaller than
0.3 dB.
PACS 42.62.-b; 42.82.Cr; 82.50.Pt; 42.79.Gn; 42.81.Qb 相似文献
2.
The electronic effect on the regioselectivity in the alkynylation of phenyloxiranes was investigated using three kinds of metal acetylides. BF3 mediated lithium acetylide provided either the α- or β-alkynylated products by controlling the effect of the para-substituents of the phenyloxiranes. LiClO4 mediated lithium acetylide and titanium acetylide, on the other hand, afforded predominantly the β- and α-products, respectively. 相似文献
3.
Preparation of peptide thioester is essential for native chemical ligation and block condensation. Our novel methodology involves conversion of the carboxylic acid of a peptide into a thioester using p-toluenesulfonyl isocyanate, followed by alkylation, then thiol substitution. Our methodology can also be used for the preparation of glycopeptide thioesters. Furthermore, it is possible to carry out the reaction as a sequential peptide chemical ligation. 相似文献
4.
Otohiko Tsuge Taizo Hatta Hisashi Kojima Nobutaka Miyahara Masafumi Sugaya 《Journal of heterocyclic chemistry》1994,31(5):1283-1287
2-Benzoyl- 5 and 2-acetylacenaphthenone 6 , prepared from the corresponding 1-acyl-2-(1-pyrrolidinyl)-acenaphthylenes 2 and 3 , reacted with arylhydrazines 8 under acidic conditions to give the corresponding 1-arylacenaphtho[1,2-d]pyrazoles 9 and 10 . Novel heteropentalene mesomeric betaines, 5,7-dehydro-5H,7H-benzo[b]acenaphtho[1,2-e]-1,3a,6a-triazapentalenes 13 and 14 were prepared by reductive cyclization of 1-(o-nitrophenyl)acenaphtho[1,2-d]pyrazoles 9d and 10d , respectively. 相似文献
5.
Junya Adachi Taizo Mori Ryo Inoue Masaya Naito Ngoc Ha‐Thu Le Soichiro Kawamorita Jonathan P. Hill Takeshi Naota Katsuhiko Ariga 《化学:亚洲杂志》2020,15(3):406-414
Molecular functions depend on conformations and motions of the corresponding molecular species. An air–water interface is a suitable asymmetric field for the control of molecular conformations and motions under a small applied force. In this work, double‐paddled binuclear PtII complexes containing pyrazole rings linked by alkyl spacers were synthesized and their orientations and emission properties dynamically manipulated at the air–water interface. The complexes emerge from water with concurrent variation of interface orientation of the planes of the PtII complexes from perpendicular to parallel during mechanical compression suggesting a unique ‘submarine emission‘. Phosphorescence of the complexes is quenched at the air–water interface prior to monolayer formation with intensities subsequently rapidly increasing during monolayer compression. These results indicate that asymmetric reactions and motions might be controlled by applying mechanical force at the air–water interface. 相似文献
6.
Fabrication of microfluidic optical waveguides on glass chips with femtosecond laser pulses 总被引:1,自引:0,他引:1
We describe the fabrication of microfluidic channel structures on the surface of a borosilicate glass slide by femtosecond laser direct writing for optical waveguide application. Liquid with a variable refractive index is fed into the microchannel, serving as the core of the waveguide. We demonstrate that either a multimode or a single-mode waveguide can be achieved by controlling the refractive index of the liquid. 相似文献
7.
K. Obata K. Sugioka T. Akane N. Aoki K. Toyoda K. Midorikawa 《Applied Physics A: Materials Science & Processing》2001,73(6):755-759
A collinear irradiation system of F2 and KrF excimer lasers for high-quality and high-efficiency ablation of hard materials by the F2 and KrF excimer lasers’ multi-wavelength excitation process has been developed. This system achieves well-defined micropatterning
of fused silica with little thermal influence and little debris deposition. In addition, the dependence of ablation rate on
various conditions such as laser fluence, irradiation timing of each laser beam, and pulse number is examined to investigate
the role of the F2 laser in this process. The multi-wavelength excitation effect is strongly affected by the irradiation timing, and an extremely
high ablation rate of over 30 nm/pulse is obtained between -10 ns and 10 ns of the delay time of F2 laser irradiation. The KrF excimer laser ablation threshold decreases and its effective absorption coefficient increases
with increasing F2 laser fluence. Moreover, the ablation rate shows a linear increase with the logarithm of KrF excimer laser fluence when the
F2 laser is simultaneously irradiated, while single KrF excimer laser ablation shows a nonlinear increase. The ablation mechanism
is discussed based on these results.
Received: 16 July 2001 / Accepted: 27 July 2001 / Published online: 2 October 2001 相似文献
8.
9.
The negative chemical ionization mass spectra of representative perfluorinated alkanes, cycloalkanes, ethers and tertiary amines have been examined, using Ar at about 0.5 torr as the reagent gas. The compounds chosen are typical of those under study as components of fluorochemical emulsion blood substitutes. Many such PFC's, particularly those with cyclic or branched structures, give intense molecular ions; most give simple spectra with a few major fragment ions at high mass, in marked contrast to the EI spectra which are dominated by m/e 69 (CF3+) and 131 (C3F5+) of no value for structure elucidation. NCI-GC/MS is more sensitive than conventional EI-GC/MS and promises to be more generally useful for structure determination. Specific examples from the various classes will be presented, and their NCI and EI mass spectra compared. 相似文献
10.
Hirota K Hasegawa T Nakajima T Makino K Terada H 《Colloids and surfaces. B, Biointerfaces》2011,87(2):293-298
In this work we obtain the thermodynamic properties of mixed (1-stearoyl-2-oleoyl-sn-glycero-3-phosphocholine) PC and (1-stearoyl-2-oleoyl-sn-glycero-3-phospho-l-serine (sodium salt)) PS monolayers. Measurements of compressibility (isotherms, bulk modulus, and excess area per molecule) and surface potential show that the properties of monolayers at the air–water interface depend on the concentration of ions (Na+ and K+) and the proportion of PS in the mixture. The dependence on PS arises because the molecule is originally bound to a Na+ counterion; by increasing the concentration of ions the entropy changes, creating a favorable system for the bound counterions of PS to join the bulk, leaving a negatively charged molecule. This change leads to an increase in electrostatic repulsions which is reflected by the increase in area per molecule versus surface pressure and a higher surface potential. The results lead to the conclusion that this mixture of phospholipids follows a non ideal behavior and can help to understand the thermodynamic behavior of membranes made of binary mixtures of a zwitterionic and an anionic phospholipid with a bound counterion. 相似文献