全文获取类型
收费全文 | 8859篇 |
免费 | 379篇 |
国内免费 | 1931篇 |
专业分类
化学 | 5158篇 |
晶体学 | 7篇 |
力学 | 658篇 |
综合类 | 228篇 |
数学 | 1410篇 |
物理学 | 3708篇 |
出版年
2024年 | 3篇 |
2023年 | 9篇 |
2022年 | 8篇 |
2021年 | 9篇 |
2020年 | 14篇 |
2019年 | 10篇 |
2018年 | 11篇 |
2016年 | 21篇 |
2015年 | 51篇 |
2014年 | 23篇 |
2013年 | 104篇 |
2012年 | 114篇 |
2011年 | 1348篇 |
2010年 | 690篇 |
2009年 | 698篇 |
2008年 | 123篇 |
2007年 | 128篇 |
2006年 | 206篇 |
2005年 | 447篇 |
2004年 | 1361篇 |
2003年 | 801篇 |
2002年 | 697篇 |
2001年 | 560篇 |
2000年 | 231篇 |
1999年 | 232篇 |
1998年 | 287篇 |
1997年 | 202篇 |
1996年 | 133篇 |
1995年 | 140篇 |
1994年 | 114篇 |
1993年 | 510篇 |
1992年 | 530篇 |
1991年 | 327篇 |
1990年 | 349篇 |
1989年 | 331篇 |
1988年 | 139篇 |
1987年 | 15篇 |
1986年 | 80篇 |
1985年 | 24篇 |
1984年 | 33篇 |
1983年 | 11篇 |
1982年 | 10篇 |
1977年 | 3篇 |
1976年 | 2篇 |
1962年 | 2篇 |
1938年 | 3篇 |
1937年 | 2篇 |
1936年 | 2篇 |
1931年 | 2篇 |
1893年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
5,6-Dihydro-OSW-1 (1) was synthesized following our previous procedure for the total synthesis of OSW-1. This compound demonstrated slightly stronger potency than that of OSW-1 against the growth of cancer cells. 相似文献
22.
Introduction In the previous studies on the oxidation reaction,peroxydisulfate was widely used as an oxidizingagent.1-5 One of the advantages of this oxidant lies in itsstability in a wide range of pH values. The reaction be-tween Fe(CN)5L3- (L=N-aromatic heterocyclic li-gands) and S2O8 2- has been proved to proceed throughan outer-sphere electron transfer mechanism.5 For a re-action [(Eq. (1)] to be under an outer-sphere mechanismthe steps involved are the formation of a reactant … 相似文献
23.
NianYuanTAN XiaoMingXIAO ZeLinLI TakekoMATSUMURA-INOUE 《中国化学快报》2004,15(6):687-690
A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra. 相似文献
24.
Qing An WU Zhen Yuan XU Mei ZHENG Dan Qian XU Jun XU Yin Chu SHENCollege of Chemical Engineering Materials Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(7)
Six new 13-O-acylavermectin Bl aglycones(3-8) were synthesized from avermectin B1 aglycone and their bioactivities were evaluated against Spodoptera exigua, Spodoptera eridania, Tetranychus urticae and Aphis fabae. 相似文献
25.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献
26.
Gui Hong YAN Da XING* Shi Ci TAN Institute of Laser Life Science South China Normal University Guangzhou 《中国化学快报》2004,15(1):101-104
Electrochemiluminescence (ECL), like other chemiluminescence technique, offers high signal-to-noise ratio. Furthermore, it has the advantage over other chemiluminescence techniques of being initiated by a voltage potential. Thus, it provides a better-controlled luminescence. This technique has been used in measuring many kinds of organic and inorganic matters, and analyzing many kinds of antigen, antibody and hapten, such as carcinoembryonic antigen and alpha-fetoprotein, etc1-6. The ele… 相似文献
27.
XiangGuoSHI DaFangZHONG YuMingSUN YuFengZHANG 《中国化学快报》2004,15(4):431-434
A sensitive analytical method to identify active metabolites of bitespiramycin in rat urine and bile was developed by liquid chromatography-electrospray ionization tandem mass spectrometry(LC/ESI-MS^n).Bitespiramycin and its major active metabolites in rat urine and bile were isolated and identified as M1 serial(spiramycin Ⅰ,Ⅱ,Ⅲ),M2 serial(platenomycin A1,josamycin and leucomycin A1) and M3 serial(deisovalerylplatenomycin A1,deisovaleryljosamycin,deisovalerylleucomycin A1). 相似文献
28.
DongXiangLI WanGuoHOU ShuPingLI MingTuHAO GaoYongZHANG 《中国化学快报》2004,15(2):224-227
The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations. 相似文献
29.
Zhong Hong YAN Chun Hao YANG Xi Han WU Yu Yuan XIEDivision of Chemistry Shanghai Second Medical University Shanghai Sate Key Laboratory of Drug Research Shanghai Institute of Materia Medica Shanghai Institutesfor Biological Sciences Shanghai 《中国化学快报》2004,(4)
The first and facile synthesis of (±)syringaresinol was described. 相似文献
30.
两段级联掺铒光纤放大器的优化研究 总被引:7,自引:4,他引:3
基于Giles模型,研究了980 nm和1480 nm泵浦的两段级联掺铒光纤放大器(EDFA)的设计,得出了掺铒光纤(EDF)的最佳长度和光隔离器的最佳位置随泵浦功率和信号功率的变化关系.比较980 nm和1480 nm泵浦的两段级联EDFA,可以发现,前者的最佳EDF长度短,而光隔离器最佳位置距EDFA输入端远. 相似文献