全文获取类型
收费全文 | 32185篇 |
免费 | 761篇 |
国内免费 | 599篇 |
专业分类
化学 | 12654篇 |
晶体学 | 313篇 |
力学 | 1657篇 |
综合类 | 29篇 |
数学 | 9300篇 |
物理学 | 9592篇 |
出版年
2023年 | 110篇 |
2022年 | 122篇 |
2021年 | 178篇 |
2020年 | 174篇 |
2019年 | 164篇 |
2018年 | 1324篇 |
2017年 | 1556篇 |
2016年 | 897篇 |
2015年 | 724篇 |
2014年 | 668篇 |
2013年 | 910篇 |
2012年 | 3452篇 |
2011年 | 2629篇 |
2010年 | 2021篇 |
2009年 | 1728篇 |
2008年 | 757篇 |
2007年 | 793篇 |
2006年 | 779篇 |
2005年 | 4577篇 |
2004年 | 4012篇 |
2003年 | 2378篇 |
2002年 | 546篇 |
2001年 | 350篇 |
2000年 | 167篇 |
1999年 | 236篇 |
1998年 | 170篇 |
1997年 | 117篇 |
1996年 | 96篇 |
1995年 | 91篇 |
1994年 | 69篇 |
1993年 | 60篇 |
1992年 | 207篇 |
1991年 | 175篇 |
1990年 | 155篇 |
1989年 | 121篇 |
1988年 | 109篇 |
1987年 | 63篇 |
1986年 | 47篇 |
1985年 | 46篇 |
1983年 | 32篇 |
1976年 | 79篇 |
1975年 | 37篇 |
1974年 | 40篇 |
1973年 | 48篇 |
1972年 | 39篇 |
1970年 | 34篇 |
1969年 | 37篇 |
1968年 | 35篇 |
1967年 | 30篇 |
1966年 | 37篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
71.
Cr-doped mullites were prepared from single-phase precursors containing up to 9.60 wt% Cr2O3 using a sol-gel technique followed by thermal treatment. Particle induced X-ray emission spectroscopy and X-ray powder diffraction were used to characterize the samples. Mullites were orthorhombic, space group Pbam. Cr doping caused the increase of unit-cell parameters. Strongest expansion was noticed along c-axis followed by a and b (Δc/c=0.089, Δa/a=0.061, Δb/b=0.045% per mole Cr2O3). A second phase, namely θ-(Al,Cr)2O3, was revealed by XRD in the sample containing 9.60 wt% Cr2O3. The structure of mullites was refined by the Rietveld method, location of Cr3+ was performed by the EPR spectroscopy. At low chromium doping level (Cr2O3 content less than ∼5 wt%) Cr3+ ions were substituted for Al3+ in the AlO6 octahedra of the mullite structure (M1 site). For higher doping level, Cr3+ ions were additionally substituted for Al3+ in the AlO6 octahedra of the second phase [θ-(Al,Cr)2O3 at 1400 °C, or α-(Al,Cr)2O3 at 1600 °C] which segregated in the system. Substitution of Cr3+ for Al3+ on M1 site in the mullite structure resulted in increase of average distances in (M1)O6 octahedron and decrease of average distances in T*O4 tetrahedron, while average distances in TO4 tetrahedron stayed almost constant. 相似文献
72.
Xie Ruixiang Wang Min Duan Changchun Yan Yihua R. A. Sych A. T. Altyntsev 《中国科学A辑(英文版)》2002,45(1):97-105
A complex solar radio moving type IV burst was observed on 23 September 1998 with the broadband (1.0–2.0 GHz and 2.6–3.8 GHz) spectrometers with high temporal and spectral resolutions at National Astronomical Observatories of China (NAOC). Comparing to the high spatial resolution data of Siberian Solar Radio Telescope (SSRT), we find that this burst is a rare type of moving type IV burst which is caused by the expanding arches, and the spatial structure oscillations of the radio sources are related with the time structure pulsations of the radio emission. Furthermore, the burst is associated with the multiple quasi-periodic long-term pulsations, and this suggests the existence of multi-scale magnetic structures in a large expanding coronal arch. We think the moving type IV burst is due to the synchrotron emission of the energetic electrons trapped in the expanding arch, and the multiple quasi-periodic pulsations are due to the second harmonic plasma emission. 相似文献
73.
本文研究并揭示了L_(2~a)(2~(2~a-1))型正交表行(列)间的递推规律,提出了一种泛函梯度数值计算的新方法——正交试验法,该方法在计算速度和精度上优于直接梯度法;在通用性及节省内存方面优于伴随算子法。 相似文献
74.
I Cserpan M Kalman M L Tj?rnhammar A Simoncsits 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(3):265-272
A general method to convert single-stranded, chemically synthesized oligonucleotides into cloned duplexes is described. Oligonucleotides supplied with 3'-terminal extensions that are complementary to 3'-protruding ends obtained by certain restriction enzymes can be cloned either directly or with the help of an adapter molecule into double-stranded vectors. Two methods have also been developed for consecutive cloning applications. According to these methods, the synthetic oligonucleotides (and their enzymatically prepared complementary strands) are joined, one after the other, inside a cloning vector, each joining requiring one cloning step. Synthetic genes are thus built up from oligonucleotides corresponding to only one strand of the DNA. The sequential assembly of the cloned duplex takes place in the 5' to 3' direction. Each oligonucleotide is supplied with a four-nucleotide-long 3'-terminal extension, but this sequence is eliminated when the joining takes place, leaving no limiting sequence between the oligonucleotides. The two consecutive cloning methods, the adapter and the polycloning site methods, are illustrated by the assembly of short artificial genes. 相似文献
75.
Andrzej Wi?nicki 《Journal of Mathematical Analysis and Applications》2002,267(1):158-172
We use a newly introduced concept of neocompactness to study problems from metric fixed point theory. In particular, we give a sufficient condition for a superreflexive Banach space X to have the fixed point property and obtain shorter proofs of some well-known results in that theory. 相似文献
76.
77.
78.
The theoretical proton-40Ca optical potential is constructed based on theα-particle model of the nucleus. With this potential, the differential cross section, analysing power and the spin rotation function for 200 MeV proton-40Ca elastic scattering are calculated. The results are in good agreement with the experimental data. 相似文献
79.
In vitro and in vivo proton T1 data are reported that demonstrate that the paramagnetic copper-D-penicillamine complex can be applied as a potential contrast agent to magnetic resonance imaging. 相似文献
80.
T Christensen E B Jensen F Junker H Dalb?ge F Abildgaard J J Led 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1992,46(1):97-99
Biosynthetic human growth hormone specifically 13C-labelled in the carbonyl positions of all 26 leucine residues has been obtained by recombinant DNA techniques using 13C-labelled leucine and an E. coli strain that requires leucine. It is shown that, on the whole, the labelling is specific with no significant mislabelling as would have been the case had the 13C-labelled leucine been metabolized. 相似文献