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21.
Abstract
Large eddy simulation was performed to visualize the three-dimensional vortical structures interacting with a turbulent premixed in a lean premixed swirl combustor with varied equivalence ratio. It was found that the fluctuation of unsteady heat release due to the deformation of flame surface was significantly decreased as the equivalence ratio increased because of the change in interaction between inner vortical structures and flames. This phenomenon was another evidence of the amplification mechanism in the combustion instabilities due to the strong flame–vortex interactions under lean premixed conditions. 相似文献22.
Sub Hur Hodeok Jang Yonghoon Kim Hanlim Lee Seongtaek Hwang Yunje Oh Y. J. Sung Y. S. Kim Jichai Jeong 《Optical and Quantum Electronics》2007,39(7):561-569
We investigate the performance limits of a pico-cell system using the radio- over-fiber technique with an electroabsorption
modulator (EAM) in a 2.4 GHz wireless local area network (WLAN) environment. To understand the performance limits of the system
using an EAM as the optical transceiver, we vary the optical modulation index (OMI) of the transmitter for different bias
voltages to the EAM. Power margins in the links are found to estimate a possible service range, and packet loss rates (PLRs)
in the pico-cell system are measured to evaluate the transmission performance. The total service range can be extended up
to 3 m by adjusting the OMI of the transmitter for different applied bias voltages to the EAM. 相似文献
23.
Moiz Ahmad Yinan Liu Zachary W. Slavens Russell Low Elmar Merkle Ken-Pin Hwang Anthony Vu Jingfei Ma 《Magnetic resonance imaging》2010
Sampling water and fat signals symmetrically (i.e., at 0° and 180° relative phase angles) in a dual-echo Dixon technique offers high intrinsic tolerance to phase fluctuations in postprocessing and maximum signal-to-noise performance for the separated water and fat images. However, identification of which image is water and which image is fat after their separation is not possible based on the phase information alone. In this work, we proposed a semiempirical automatic image identification method that is based on the intrinsic asymmetry between the water and fat chemical shift spectra. Specifically, the approximately bimodal feature of the fat spectra and the observation that most in vivo tissues are either predominantly water or predominantly fat are used to construct a spectrum-based algorithm. Additional refinement is accomplished by considering the spatial distribution of the tissues that may have a coexistence of water and fat. The final improved algorithm was tested on a total of 131 three-dimensional patient datasets collected from different scanners and found to yield correct water and fat identification in all datasets. 相似文献
24.
Sarira Sahu W.-Y. P. Hwang 《The European Physical Journal C - Particles and Fields》2008,58(4):609-615
We have calculated the effective potential experienced by highly relativistic neutrinos in a weakly magnetized electron–positron
plasma, where a momentum-dependent finite-width correction to the propagator of W is considered to account for the threshold effect. Magnetars are believed to be sources of TeV–PeV neutrinos which are produced
due to photomeson and proton–proton interactions in their atmosphere. We have studied the resonant-oscillation process ν
e
↔
ν
μ,τ
of the highly relativistic neutrinos in the atmosphere of SGR 1806-20, which is a magnetar. It is shown that, for high-energy
neutrinos propagating within the magnetar atmosphere, the resonance condition can never be satisfied. On the other hand, if
GeV neutrinos are produced deep inside the magnetar atmosphere, where the temperature is about 50 keV or more, then these
neutrinos can undergo resonant oscillation. 相似文献
25.
Nuclear pure quadrupole resonance has been observed in single crystal gallium as a function of hydrostatic pressure up to 7 kbar at temperatures of 77, 198 and 273 K. The resonance frequency vQ increases linearly with pressure and the slope ()T is 13.7, 15.5 and 16.3 Hz/bar at 77, 198 and 273 K respectively. The asymmetry parameter decreases nonlinearly with pressure. Using compressibility and thermal expansion data, the volume dependence of the major principle component of the electric field gradient was deduced. The principal components Kx, Ky and Kz of the Knight shift tensor have been measured as a function of pressure to 6 kbar at 77 K. The isotropic and anisotropic components of the Knight shift were deduced as a function of pressure, and Kiso is found to vary with volume as V4.95 ± 0.80. 相似文献
26.
The action of a series of lanthanide chelate complexes LnL3, where Lu=La, Pr, Nd, Sm, Eu, Dy, Ho, Er and Yb; L= dbm (dibenzoylmethanato), dpm (dipivaloylmethanato), and acac acetylactonato), on nmr spectra of 2-butanol has been studied. The origin of shifting abilities and shifting sign of various lanthanide ions are explained by means of Bleaney's theory. 相似文献
27.
Hee-Jeong Cha Se-Yeun Hwang Da-Som Lee Dr. Akula Ravi Kumar Prof. Dr. Yong-Uk Kwon Moritz Voß Eva Schuiten Prof. Dr. Uwe T. Bornscheuer Prof. Dr. Frank Hollmann Prof. Dr. Deok-Kun Oh Prof. Dr. Jin-Byung Park 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(18):7090-7094
Long-chain aliphatic amines such as (S,Z)-heptadec-9-en-7-amine and 9-aminoheptadecane were synthesized from ricinoleic acid and oleic acid, respectively, by whole-cell cascade reactions using the combination of an alcohol dehydrogenase (ADH) from Micrococcus luteus, an engineered amine transaminase from Vibrio fluvialis (Vf-ATA), and a photoactivated decarboxylase from Chlorella variabilis NC64A (Cv-FAP) in a one-pot process. In addition, long chain aliphatic esters such as 10-(heptanoyloxy)dec-8-ene and octylnonanoate were prepared from ricinoleic acid and oleic acid, respectively, by using the combination of the ADH, a Baeyer–Villiger monooxygenase variant from Pseudomonas putida KT2440, and the Cv-FAP. The target compounds were produced at rates of up to 37 U g−1 dry cells with conversions up to 90 %. Therefore, this study contributes to the preparation of industrially relevant long-chain aliphatic chiral amines and esters from renewable fatty acid resources. 相似文献
28.
Jaechang Lim Sang-Yeon Hwang Seokhyun Moon Seungsu Kim Woo Youn Kim 《Chemical science》2020,11(4):1153
Searching for new molecules in areas like drug discovery often starts from the core structures of known molecules. Such a method has called for a strategy of designing derivative compounds retaining a particular scaffold as a substructure. On this account, our present work proposes a graph generative model that targets its use in scaffold-based molecular design. Our model accepts a molecular scaffold as input and extends it by sequentially adding atoms and bonds. The generated molecules are then guaranteed to contain the scaffold with certainty, and their properties can be controlled by conditioning the generation process on desired properties. The learned rule of extending molecules can well generalize to arbitrary kinds of scaffolds, including those unseen during learning. In the conditional generation of molecules, our model can simultaneously control multiple chemical properties despite the search space constrained by fixing the substructure. As a demonstration, we applied our model to designing inhibitors of the epidermal growth factor receptor and show that our model can employ a simple semi-supervised extension to broaden its applicability to situations where only a small amount of data is available.We propose a scaffold-based graph generative model for designing novel drug candidates that include the desired scaffold as a substructure. 相似文献
29.
The direct reaction of iron pentacarbonyl with diethylamidocyclohexadiene gave three isomeric tricarbonyliron complexes, 1, 2 and 3. Only 1 isomerized to give 2 under acidic conditions, whereas 3 remained unchanged. The chemical properties of the tricarbonyl(amidocyclohexadiene)iron complexes differed from those of the tricarbonyl(carboxycyclohexadiene)iron complexes. Complex 3 which underwent no hydride abstraction with triphenylmethyl hexafluorophosphate, has an exo stereochemistry. 相似文献