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141.
Rotor-assisted population transfer (RAPT) was developed as a method for enhancing MAS NMR sensitivity of quadrupolar nuclei by transferring polarization associated with satellite transitions to the central m=12-->-12 transition. After a single RAPT transfer, there still remains polarization in the satellite transitions that can be transferred to the central transition. This polarization is available without having to wait for the spin system to return to thermal equilibrium. We describe a new RAPT scheme that uses the remaining polarization of the satellites to obtain a further enhancement of the central transition by performing RAPT-enhanced experiments multiple times before waiting for re-equilibration of the spin system. For 27Al (I=5/2) in albite we obtain a multiple RAPT enhancement of 3.02, a 48% increase over single RAPT. For 93Nb (I=9/2) in NaNbO(3) we obtain a multiple RAPT enhancement of 5.76, an 89% increase over single RAPT. We also describe a data processing procedure for obtaining the maximum possible signal-to-noise ratio. 相似文献
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143.
Sim TB Kang SH Lee KS Lee WK Yun H Dong Y Ha HJ 《The Journal of organic chemistry》2003,68(1):104-108
5-Funtionalized enantiomerically pure oxazolidin-2-ones were prepared in one pot from commercially available chiral aziridines bearing an electron-withdrawing group at C-2 with retention of the configuration in high yields by regioselective aziridine ring-opening followed by intramolecular cyclization. 相似文献
144.
Double-quantum and double-quantum-filtered satellite-transition magic-angle spinning (STMAS) experiments are proposed. The experiments efficiently convert satellite-transition coherence from single- to double-quantum with a central-transition selective pi-pulse. The conversion allows the selection of double-quantum coherence transfer pathways with phase cycling that completely filters out unwanted diagonal and outer satellite-transition peaks. Both experiments are demonstrated with RbNO3 and AlPO4-berlinite as model compounds for obtaining clean STMAS spectra of spins 3/2 and 5/2, respectively. 相似文献
145.
Ammar R Bean A Besson D Davis R Kwak N Zhao X Anderson S Frolov VV Kubota Y Lee SJ Mahapatra R O'Neill JJ Poling R Riehle T Smith A Stepaniak CJ Urheim J Ahmed S Alam MS Athar SB Jian L Ling L Saleem M Timm S Wappler F Anastassov A Duboscq JE Eckhart E Gan KK Gwon C Hart T Honscheid K Hufnagel D Kagan H Kass R Pedlar TK Schwarthoff H Thayer JB von Toerne E Zoeller MM Richichi SJ Severini H Skubic P Undrus A Chen S Fast J Hinson JW Lee J Miller DH Shibata EI Shipsey IP Pavlunin V 《Physical review letters》2001,86(7):1167-1170
Using data recorded with the CLEO II and CLEO II.V detector configurations at the Cornell Electron Storage Rings, we report the first observation and mass measurement of the Sigma(*+)(c) charmed baryon, and an updated measurement of the mass of the Sigma(+)(c) baryon. We find M(Sigma(*+)(c))-M(Lambda(+)(c)) = (231.0+/-1.1+/-2.0) MeV, and M(Sigma(+)(c))-M(Lambda(+)(c)) = (166.4+/-0.2+/-0.3) MeV, where the errors are statistical and systematic, respectively. 相似文献
146.
The identification of tyre induced vehicle interior noise 总被引:2,自引:0,他引:2
Sound transmission into a vehicle is classified as either airborne or structure borne sound. From the point view of noise control, the reduction of noise transferred by different paths requires different solutions. Coherence function analysis is often used to identify transmission paths. However it can be difficult to separate the airborne from structure borne components. The principle of acoustic reciprocity offers a convenient method for overcoming this difficulty. The principal states that the transfer function between an acoustic volume velocity source and an acoustic receiver is independent of a reversal of the position of source and receiver. The work done on this study involves exciting a stationary tyre and measuring the surface velocity of the tyre at a number of discrete points. The acoustic transfer functions between each point on the tyre and a receiver point are measured reciprocally. Two sets of measurements are then combined to yield a measure of the sound pressure due to a point force on the tyre via the acoustic transmission path only. This technique also provides information on the relative contributions of various regions of the tyre wall to the resultant noise. Also the sound radiation characteristics, the horn effect, and resonance at the wheel housing are identified through the reciprocal measurement. 相似文献
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148.
[structure: see text] A yttrium(III) complex derived from proligand 7c has been shown to be a superior catalyst for enantioselective intramolecular alkene hydroaminations that provide cyclic amines with ee's ranging from 69% to 89%. 相似文献
149.
Cinabro D Henderson S Liu T Saulnier M Wilson R Yamamoto H Bergfeld T Eisenstein BI Gollin G Ong B Palmer M Selen M Thaler JJ Sadoff AJ Ammar R Ball S Baringer P Bean A Besson D Coppage D Copty N Davis R Hancock N Kelly M Kwak N Lam H Kubota Y Lattery M Nelson JK Patton S Perticone D Poling R Savinov V Schrenk S Wang R Alam MS Kim IJ Nemati B O'Neill JJ Severini H Sun CR Zoeller MM Crawford G Daubenmier CM Fulton R Fujino D Gan KK Honscheid K Kagan H Kass R Lee J Malchow R Morrow F Skovpen Y 《Physical review letters》1994,72(10):1406-1410