全文获取类型
收费全文 | 1036篇 |
免费 | 14篇 |
国内免费 | 6篇 |
专业分类
化学 | 695篇 |
晶体学 | 36篇 |
力学 | 23篇 |
数学 | 196篇 |
物理学 | 106篇 |
出版年
2023年 | 4篇 |
2022年 | 17篇 |
2021年 | 19篇 |
2020年 | 12篇 |
2019年 | 17篇 |
2018年 | 12篇 |
2017年 | 22篇 |
2016年 | 23篇 |
2015年 | 15篇 |
2014年 | 20篇 |
2013年 | 60篇 |
2012年 | 44篇 |
2011年 | 63篇 |
2010年 | 40篇 |
2009年 | 41篇 |
2008年 | 53篇 |
2007年 | 54篇 |
2006年 | 57篇 |
2005年 | 53篇 |
2004年 | 56篇 |
2003年 | 44篇 |
2002年 | 40篇 |
2001年 | 16篇 |
2000年 | 21篇 |
1999年 | 15篇 |
1998年 | 16篇 |
1997年 | 11篇 |
1996年 | 19篇 |
1995年 | 13篇 |
1994年 | 11篇 |
1993年 | 10篇 |
1992年 | 10篇 |
1991年 | 7篇 |
1990年 | 8篇 |
1989年 | 12篇 |
1988年 | 10篇 |
1987年 | 7篇 |
1986年 | 10篇 |
1985年 | 14篇 |
1984年 | 8篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 10篇 |
1980年 | 6篇 |
1977年 | 6篇 |
1976年 | 8篇 |
1918年 | 2篇 |
1914年 | 2篇 |
1913年 | 2篇 |
1907年 | 2篇 |
排序方式: 共有1056条查询结果,搜索用时 15 毫秒
61.
Efficient Solvent‐Free Synthesis of Benzothiazine‐Fused Pyrrolo[3,4‐c]coumarins: Cycloaddition Reactions between Coumarin‐Based Dihydrobenzothiazoles and Isocyanides 下载免费PDF全文
Mehdi Khoobi Ali Ramazani Mohammad Mahdavi Alireza Foroumadi Saeed Emami Sang Woo Joo Katarzyna Ślepokura Tadeusz Lis Abbas Shafiee 《Helvetica chimica acta》2014,97(6):847-853
A new and unusual synthesis of benzothiazine‐fused pyrrolo[3,4‐c]coumarins, involving the ring‐opening of coumarin‐based dihydrobenzothiazoles and subsequent [4+1] cycloaddition reaction with isocyanides, was described. Thus, simple heating of various 3‐(2,3‐dihydro‐2‐methylbenzo[d]thiazol‐2‐yl)coumarins with isocyanides produced the title compounds in good yields under solvent‐free conditions. 相似文献
62.
Synthesis of Novel α‐(Acyloxy)‐α‐(quinolin‐4‐yl)acetamides by a Three‐Component Reaction between an Isocyanide,Quinoline‐4‐carbaldehyde,and Arenecarboxylic Acids 下载免费PDF全文
Jafar Taran Ali Ramazani Sang Woo Joo Katarzyna Ślepokura Tadeusz Lis 《Helvetica chimica acta》2014,97(8):1088-1096
Novel α‐(acyloxy)‐α‐(quinolin‐4‐yl)acetamides were synthesized by the Passerini three‐component reaction between an isocyanide, quinoline‐4‐carbaldehyde, and arenecarboxylic acids in H2O. The reactions were carried out in one pot at room temperature with quantitative yields. 相似文献
63.
64.
Tadeusz Iwaniec 《Transactions of the American Mathematical Society》2002,354(5):1961-1995
This paper has arisen from an effort to provide a comprehensive and unifying development of the -theory of quasiconformal mappings in . The governing equations for these mappings form nonlinear differential systems of the first order, analogous in many respects to the Cauchy-Riemann equations in the complex plane. This approach demands that one must work out certain variational integrals involving the Jacobian determinant. Guided by such integrals, we introduce two nonlinear differential operators, denoted by and , which act on weakly differentiable deformations of a domain .
Solutions to the so-called Cauchy-Riemann equations and are simply conformal deformations preserving and reversing orientation, respectively. These operators, though genuinely nonlinear, possess the important feature of being rank-one convex. Among the many desirable properties, we give the fundamental -estimate
In quest of the best constant , we are faced with fascinating problems regarding quasiconvexity of some related variational functionals. Applications to quasiconformal mappings are indicated.
65.
Tadeusz Jankowski 《Czechoslovak Mathematical Journal》2002,52(3):553-563
The method of quasilinearization is a well-known technique for obtaining approximate solutions of nonlinear differential equations. In this paper we apply this technique to functional differential problems. It is shown that linear iterations converge to the unique solution and this convergence is superlinear. 相似文献
66.
67.
A new pentadentate Schiff base 2,6,10-triaza-1,11-bis(2′-aminophenyl)-undeca-1,10-diene, abaDPT, and its complexes of general formula M(abaDPT)X2 where M = Cu(II), Ni(II), X = Cl, Br, I, NO3 and ClO4, have been prepared. The complexes have been characterized by electronic and IR spectra, EPR, magnetic moments, molar conductances, and elemental analysis. IR data show an interaction between halide anion of the outer coordination sphere and the complexed amino group. EPR and spectrophotometric data of most of the copper compounds are consistent with a distorted square pyramidal geometry. Single crystal EPR studies of Cu(abaDPT)(NO3)2 and Cu(abaDPT)Br2 revealed that copper atoms in the former compound occupy two magnetically inequivalent places in the lattice while copper atoms in the latter compound take identical sites. Principal g tensor axes of the two compounds have been determined. 相似文献
68.
Complexes of phosphated cornstarch and waxy cornstarch with casein were prepared and characterised. They were prepared from casein in defatted milk and corn and waxy corn starches phosphated to degree of substitution values (DS) of 0.0637 and 0.0968, respectively. The components were blended in starch to casein ratios of 2:1, 1:1, and 1:2, then precipitated with hydrochloric acid. Aqueous solubility, water binding capacity, IR spectra, and thermal analysis (thermogravimetry, TG, and differential thermogravimetry, DTG) of the precipitates revealed that they were not simple physical mixtures of the components. The components interact with one another electrostatically with involvement of the starch phosphate groups and the peptide bonds of casein as documented by the IR spectra. Because of their insolubility in 7 M aqueous urea solution they might also be considered as complexes in which the components were chemically bound. Enzymatic studies showed that they are biodegradable materials. 相似文献
69.
Pisula W Kastler M Wasserfallen D Pakula T Müllen K 《Journal of the American Chemical Society》2004,126(26):8074-8075
The substitution of a hexa-peri-hexabenzocoronene by bulky, space-demanding, 2-decyltetradecyl side chains proved to be an effective procedure to influence the thermal and self-aggregation behavior. The extremely large steric requirement of the introduced side chains modulated the aggregation and resulted in a dramatic lowering of the isotropization temperature and a higher solubility. As an additional consequence of the exceptional, long-range self-aggregation of the discotic molecule, spherulite formation was observed during crystallization by polarized light microscopy. Macroscopic self-assembly was induced by zone crystallization of the material, leading to aligned columnar superstructures as revealed by 2D-WAXS experiments. These extraordinary properties have not yet been reported for a discotic columnar material, making this compound very promising for application in electronic devices. 相似文献
70.