Fatigue effect in luminescence of glow discharge amorphous silicon at low temperatures

Fatigue in the luminescence was observed in glow discharge amorphous silicon at 4.2 K and 77 K. This fatigue was not recovered by infra-red illumination, but by heating the sample at higher temperatures. These results are interpreted in terms of enhancement of non-radiative recombination associated with dangling bonds created by high optical excitation.     

Radical and palladium-catalyzed cyclizations to cyclobutenes: an entry to the BCD ring system of penitrem D

A novel approach toward the synthesis of the BCD ring system of penitrem D is described. The strategy capitalizes on the fast cyclization rates of aryl radicals into cyclobutenes and allows access to a variety of fused tricyclic structures. Radical/polar crossover reactions of precursors 24-29 promoted by samarium diiodide in the presence of HMPA and acetone allow access to the fully functionalized BCD ring system of penitrem D. The stereochemical implications of these processes are evaluated, and a Pd-mediated cyclization approach toward the penitrems is also introduced.     

Alpha scattering from nonclosed shell nucleus 12C and alpha-nucleus interaction

In order to understand the α-nucleus interactions for the α+¹²C～α+¹⁶O systems systematically, α scattering from ¹²C is studied in a microscopic coupled-channel model using a folding potential and realistic microscopic wave functions of ¹²C. The experimental angular distributions of elastic and inelastic scattering to the 2⁺(4.43 MeV), 3^? (9.64 MeV), and 0 ₂ ⁺ (7.66 MeV) states in the range of E _α = 41–172.5 MeV are analyzed.     

Catalytic asymmetric cyclopropanation using bridged dirhodium tetraprolinates on solid support

Dirhodium tetraprolinates in highly cross-linked macroporous polystyrene resins are very effective catalysts for asymmetric cyclopropanation using methyl aryldiazoaceates.     

Profiling the Cell Surface Glycome of Five Fungi Using Lectin Microarray

Fungal surface glycans play roles in cell protection and interaction. Our knowledge of fungal glycans, however, is limited to model yeasts and a few medically/industrially important fungi. We evaluated the usefulness of a lectin microarray in analysis of live cell surface glycans and then applied the technique to glycome of varieties of yeast-form fungi from various phyla and subphyla. We found glycan profiles are different among and within taxonomic groups. For example, Saccharomycotina were classified into two groups, one bound to mannose-specific lectins and the other bound to galactose/N-acetylgalactosamine-specific lectins. In Basidiomycota, Pucciniomycotina yeasts were distinguished from other subphylum members in binding to fucose-specific lectins. Supplemental materials are available for this article. Go to the publisher's online edition of Journal of Carbohydrate Chemistry to view the free supplemental file.