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171.
Xu Y Jang K Yamashita T Tanaka Y Mawatari K Kitamori T 《Analytical and bioanalytical chemistry》2012,402(1):99-107
By combining cell technology and microchip technology, innovative cellular biochemical tools can be created from the microscale
to the nanoscale for both practical applications and fundamental research. On the microscale level, novel practical applications
taking advantage of the unique capabilities of microfluidics have been accelerated in clinical diagnosis, food safety, environmental
monitoring, and drug discovery. On the other hand, one important trend of this field is further downscaling of feature size
to the 101–103 nm scale, which we call extended-nano space. Extended-nano space technology is leading to the creation of innovative nanofluidic
cellular and biochemical tools for analysis of single cells at the single-molecule level. As a pioneering group in this field,
we focus not only on the development of practical applications of cellular microchip devices but also on fundamental research
to initiate new possibilities in the field. In this paper, we review our recent progress on tissue reconstruction, routine
cell-based assays on microchip systems, and preliminary fundamental method for single-cell analysis at the single-molecule
level with integration of the burgeoning technologies of extended-nano space. 相似文献
172.
Structures of excited states in 11B are investigated with a method of β – γ constraint antisymmetrized molecular dynamics in combination with the generator coordinate method. Various cluster structures are suggested in excited states. For negative-parity states, we suggest a band with a 2α + t cluster structure. This band starts from the ${3/2^{-}_{3}}$ state and can correspond to the experimental band observed recently. We find that the feature of the ${3/2^{-}_{3}}$ is quite similar to the ${0^{+}_{2}}$ state in 12C. 相似文献
173.
We study growth of higher Sobolev norms of solutions of the onedimensional periodic nonlinear Schr?dinger equation (NLS). By a combination of the normal form reduction and the upside-down I-method, we establish $${\left\| {u(t)} \right\|_{{H^s}}} \le {(1 + \left| t \right|)^{a(s - 1) + }}$$ with ?? = 1 for a general power nonlinearity. In the quintic case, we obtain the above estimate with ?? = 1/2 via the space-time estimate due to Bourgain [4, 5]. In the cubic case, we compute concretely the terms arising in the first few steps of the normal form reduction and prove the above estimate with ?? = 4/9. These results improve the previously known results (except for the quintic case). In the Appendix, we also show how Bourgain??s idea in [4] on the normal form reduction for the quintic nonlinearity can be applied to other powers. 相似文献
174.
175.
Michio Sorai Corresponding author Kazuya Saito Corresponding author Tadahiro Nakamoto Mayumi Ikeda Yuri G. Galyametdinov Irina Galyametdinova 《Liquid crystals》2013,40(7):861-869
The heat capacity of the cubic mesogen ACBC(16) was measured between 16 and 500?K by adiabatic calorimetry. As well as the known condensed phases, a new crystalline phase was found to undergo a glass transition at around 165?K. Phase transitions between crystal, SmC, cubic, and isotropic liquid phases took place at 399.16, 431.15, and 474.30?K, respectively. As in the case of ANBC, a broad hump was observed in the heat capacity of the isotropic liquid phase. The first order nature of the SmC–cubic phase transition was confirmed for the first time by the observation of supercooling of the cubic phase. The broad hump in the isotropic liquid phase was shown to extend to a low temperature side if the isotropic liquid was supercooled, suggesting that the event occurring at the hump is not directly related to the cubic–isotropic liquid phase transition. 相似文献
176.
Shigeharu Onogi Tadahiro Asada Yoshiharu Fukui Takeo Fujisawa 《Journal of Polymer Science.Polymer Physics》1967,5(6):1067-1078
The time-dependent birefringence has been measured simultaneously with the stress relaxation on quenched and annealed low-density polyethylene at various temperatures from 10 to 70°C. The strain-optical coefficient increases generally with increasing time, and approaches the equilibrium value, which depends upon the temperature. When the strain-optical coefficient at a fixed time is plotted against temperature, it first increases and then decreases after passing through a maximum at Tmax with increasing temperature. The higher the degree of crystallinity, the higher are the equilibrium values of the strain-optical coefficient and Tmax. The curves for strain-optical coefficient versus time and relaxation modulus versus time below Tmax can be superposed well by a horizontal shift along the abscissa. The optical shift factor obeys the original WLF equation, while the mechanical shift factor is much larger than the optical one. The molecular mechanisms corresponding to this dispersion of the strain-optical coefficient and viscoelastic αc absorption peak near Tmax are discussed. 相似文献
177.
Tadahiro Ishii Takashi Handa Satoru Matsunaga 《Journal of Polymer Science.Polymer Physics》1979,17(5):811-823
Effects of tacticity and steric hindrance on excimer formation were investigated in isotactic and atactic polystyrene, poly(o-methylstyrene), poly(m-methylstyrene), and poly(p-methylstyrene) in the presence and absence of a quencher (CCl4). The calculated rate constants for excimer formation in the isotactic polymers except for poly(o-methylstyrene) were almost the same and larger than those in the corresponding atactic polymers. These results indicate that excimer formation was due to not only rotational sampling but also energy migration to trapping sites. It was found that steric hindrance on excimer formation was intimately related to the excition diffusion length in the polymer chain. 相似文献
178.
Upon irradiation of a benzene-d6 solution of 1,2,2,5-tetrakis[di-tert-butyl(methyl)silyl]-4,7-diaryl- 1,2,5-trisilabicyclo-[3.2.0]hepta-3,6-diene [1a: aryl = phenyl, b: aryl = 3,5-bis-(trimethylsilyl)phenyl], 1,4,7,7-tetrakis[di-tert-butyl-(methyl)silyl]-2,5-diaryl-1,4,7- trisilabicyclo[2.2.1]hepta-2,5-diene (2a,b) was formed via skeletal rearrangement. 相似文献
179.
The synthesis of an asymmetric glycocluster 1 has been achieved using two glycocluster units 12 and 13, prepared by coupling the cluster chain unit 4 with each omega-amino acid (beta-alanine and 6-aminocapronic acid) trichloroethyl ester, and peptidic C-terminal block glycocluster 16, prepared by coupling the bifunctional linker 14 with sugar unit 9. This method facilitated the synthesis of the cluster optionally modulated the distance between the side-chain branched points by using various omega-amino acids. We also synthesized glycodendron 2 using the same intermediate. 相似文献
180.
In our investigation of a cell proliferation-based screening assay using human ligand-dependent cell lines for medicinal herbal extracts, the acetone extract of the whole plants of Euphorbia lunulata (EL) was observed for its proliferation activity for insulin- and interleukin-10 (IL-10)-dependent cell lines. Fractionation of the active extract led to the isolation of one new flavonoid galactoside, quercetin 3-O-(2',3'-digalloyl)-beta-D-galactopyranoside (1), and four known ones, quercetin 3-O-(2'-galloyl)-beta-D-galactopyranoside (2), hyperin (3), quercetin (4), and gallic acid (5). Compounds 1 and 2 showed insulin-like activity. Compounds 4 and 5 showed IL-10-like activity. This is the first report of these activities of EL, and 1 and 2 will become the seed compounds for the development of a nonpeptidyl insulin substitutional medicine. Compounds 4 and 5 support the pharmacological use of EL, which has been employed as an herbal medicine for the treatment of bronchial asthma. 相似文献