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排序方式: 共有279条查询结果,搜索用时 281 毫秒
101.
Masato Matsuda Ken-ichiro Yamamoto Taiji Yakushiji Makoto Fukuda Takehiro Miyasaka Kiyotaka Sakai 《Journal of membrane science》2008,310(1-2):219-228
Hydrophilizing synthetic polymer dialysis membranes with polyvinylpyrrolidone (PVP) play an important role for inhibition of protein adsorption on membrane surface. In the present study, the effect of PVP on protein adsorption was evaluated from a nano-scale perspective. Swelling behavior of PVP present on wet polysulfone (PS)/PVP film surfaces was observed by atomic force microscopy (AFM). Fibrinogen and human serum albumin (HSA) were immobilized on the tip of AFM probes, with which a force-curve between protein and wet PS/PVP film surface was measured by AFM while scanning in order to visualize two-dimensional protein adsorbability on film surfaces. Furthermore, HSA adsorbability on non-PVP containing PEPA dialysis membrane (FLX-15GW) and PVP containing PEPA dialysis membrane (FDX-150GW) was evaluated by the AFM force-curve method. As a result, PS/PVP film surface was completely covered with hydrated and swollen PVP at 5 wt% or more PVP content. Protein adsorbability on PS/PVP film surfaces decreased greatly with increasing content of PVP. The adsorption of HSA was inhibited by the presence of PVP on film surfaces more significantly than that of more hydrophobic fibrinogen. HSA adsorbability on wet FLX-15GW dialysis membrane surface was 428 ± 174 pN whereas that on wet FDX-150GW dialysis membrane surface was 42 ± 29 pN. 相似文献
102.
S. Yamashita K. Hino Y. Inoue Y. Okada R. Hirahara Y. Nakazawa H. Miyasaka M. Yamashita 《Journal of Thermal Analysis and Calorimetry》2008,92(2):439-442
A magnetic-fields dependence of heat capacity of [Mn5(hmp)4(OH)2{N(CN)2}6]2MeCN·2THF (hmp=hydroxymethylpyridinate) is investigated by the thermal relaxation calorimetry technique. This compound is
a three-dimensional system consisting of Mn4 single-molecule magnet (SMM) units and Mn2+ ions, which are linked by the dicyanamide ligands to form a coordination network structure. A sharp peak of C
p being associated with the formation of three-dimensional long-range order is observed around 1.96 K. The thermodynamic discussion
based on the magnetic entropy suggests that both SMMs and Mn2+ ions are involved in the formation of the anitiferromagnetic spin ordering. However, this long-range ordering is very sensitive
to the external magnetic fields which work to change the magnitude of the Zeeman splitting of the SMM levels. The behavior
under magnetic fields is similar to that of the two-dimensional Mn4-network system studied previously. 相似文献
103.
Dr. Shinobu Arikawa Dr. Akihiro Shimizu Dr. Daisuke Shiomi Prof. Dr. Kazunobu Sato Prof. Dr. Takeji Takui Dr. Hikaru Sotome Prof. Dr. Hiroshi Miyasaka Dr. Masahito Murai Prof. Dr. Shigehiro Yamaguchi Prof. Dr. Ryo Shintani 《Angewandte Chemie (International ed. in English)》2023,62(29):e202302714
A kinetically-stabilized nitrogen-doped triangulene cation derivative has been synthesized and isolated as the stable diradical with a triplet ground state that exhibits near-infrared emission. As was the case for a triangulene derivative we previously synthesized, the triplet ground state with a large singlet-triplet energy gap was experimentally confirmed by magnetic measurements. In contrast to the triangulene derivative, the nitrogen-doped triangulene cation derivative is highly stable even in solution under air and exhibits near-infrared absorption and emission because the alternancy symmetry of triangulene is broken by the nitrogen cation. Breaking the alternancy symmetry of triplet alternant hydrocarbon diradicals by a nitrogen cation would therefore be an effective strategy to create stable diradicals possessing magnetic properties similar to the parent hydrocarbons but with different electrochemical and photophysical properties. 相似文献
104.
Construction of an Artificial Ferrimagnetic Lattice by Lithium Ion Insertion into a Neutral Donor/Acceptor Metal–Organic Framework 下载免费PDF全文
Dr. Kouji Taniguchi Keisuke Narushima Julien Mahin Dr. Wataru Kosaka Prof. Dr. Hitoshi Miyasaka 《Angewandte Chemie (International ed. in English)》2016,55(17):5238-5242
Construction of a molecular system in which the magnetic lattice exhibits long‐range order is one of the fundamental goals in materials science. In this study, we demonstrate the artificial construction of a ferrimagnetic lattice by doping electrons into acceptor sites of a neutral donor/acceptor metal–organic framework (D/A‐MOF). This doping was achieved by the insertion of Li‐ions into the D/A‐MOF, which was used as the cathode of a Li‐ion battery cell. The neutral D/A‐MOF is a layered system composed of a carboxylate‐bridged paddlewheel‐type diruthenium(II,II) complex as the donor and a TCNQ derivative as the acceptor. The ground state of the neutral form was a magnetically disordered paramagnetic state. Upon discharge of the cell, spontaneous magnetization was induced; the transition temperature was variable. The stability of the magnetically ordered lattice depended on the equilibrium electric potential of the D/A‐MOF cathode, which reflected the electron‐filling level. 相似文献
105.
Kachi-Terajima C Miyasaka H Saitoh A Shirakawa N Yamashita M Clérac R 《Inorganic chemistry》2007,46(15):5861-5872
The linear-type heterometallic tetramers, [Mn(III)(2)(5-MeOsaltmen)(2)M(II)(2)(L)(2)](CF(3)SO(3))(2) x 2H(2)O (MII = Cu, 1a; Ni, 2a), where 5-MeOsaltmen(2-) = N,N'-(1,1,2,2-tetramethylethylene) bis(5-methoxysalicylideneiminate), and H(2)L = 3-{2-[(2-hydroxy-benzylidene)-amino]-2-methyl-propylimino}-butan-2-one oxime, have been synthesized and characterized from structural and magnetic points of view. These two compounds are isostructural and crystallize in the same monoclinic P2(1)/n space group. The structure has a [M(II)-NO-Mn(III)-(O)(2)-Mn(III)-ON-M(II)] skeleton, where -NO- is a linking oximato group derived from the non-symmetrical Schiff-base complex [M(II)(L)] and -(O)(2)- is a biphenolato bridge in the out-of-plane [Mn(2)(5-MeOsaltmen)(2)](2+) dimer. The solvent-free compounds, 1b and 2b, have also been prepared by drying of the parent compounds, 1a and 2a, respectively, at 100 degrees C under dried nitrogen. After this treatment, the crystallinity is preserved, and 1b and 2b crystallize in a monoclinic P2(1)/c space group without significant changes in their structures in comparison to 1a and 2a. Magnetic measurements on 1a and 1b revealed antiferromagnetic Mn(III)---Cu(II) interactions via the oximato group and weak ferromagnetic Mn(III)---Mn(III) interactions via the biphenolato bridge leading to an S(T) = 3 ground state. On the other hand, the diamagnetic nature of the square planar Ni(II) center generates an S(T) = 4 ground state for 2a and 2b. At low temperature, these solvated (a) and desolvated (b) compounds display single-molecule magnet behavior modulated by their spin ground state. 相似文献
106.
Hayato Toda Shuhei Otake Akari Ito Prof. Dr. Makoto Miyasaka Prof. Dr. Michiya Fujiki Prof. Dr. Yoshitane Imai 《Chemphyschem》2021,22(20):2058-2062
This paper reports the first magnetic circularly polarized luminescence (MCPL) characteristics of racemic helicenes, including four unsubstituted [n]helicenes (n=3,4,5,7) and two [4]helicene derivatives bearing methoxy substituents, in tetrahydrofuran (THF) and dimethyl sulfoxide (DMSO) solutions. The value of |gMCPL| was calculated to be of the order of 10−3 T−1 within 350–430 nm under the north-up (N-up) and south-up (S-up) Faraday geometries in an external magnetic field of 1.6 T. The [n]-dependent MCPL signs were altered by the N-up and S-up geometries. 相似文献
107.
Sugiura K Kato A Iwasaki K Miyasaka H Yamashita M Hino S Arnold DP 《Chemical communications (Cambridge, England)》2007,(20):2046-2047
The reaction of Hg(CF3CO2)2 with metalloporphyrins produces mercurated porphyrins regioselectively, the reaction, surprisingly occurring at the most hindered betaB-position; this behavior is in marked contrast to the usual electrophilic substitution reactions of porphyrins, whose reactions produce meso-substituted porphyrins; the obtained mercurated porphyrins are active to transition metal-catalyzed coupling reactions, such as the Mizoroki-Heck reaction. 相似文献
108.
Khasanov R Strässle S Di Castro D Masui T Miyasaka S Tajima S Bussmann-Holder A Keller H 《Physical review letters》2007,99(23):237601
The temperature dependence of the London penetration depth lambda was measured for an untwinned single crystal of YBa_{2}Cu_{3}O_{7-delta} along the three principal crystallographic directions (a, b, and c). Both in-plane components (lambda_{a};{-2} and lambda_{b};{-2}) show an inflection point in their temperature dependence which is absent in the component along the c direction (lambda_{c};{-2}). The data provide convincing evidence that the in-plane superconducting order parameter is a mixture of (s+d)-wave symmetry whereas it is mainly s wave along the c direction. In conjunction with previous results it is concluded that coupled s+d-order parameters are universal and intrinsic to cuprate superconductors. 相似文献
109.
A thin solid-state photovoltaic cell of organic-inorganic hetero junctions was fabricated by forming a dye-metal charge-transfer complex as the sensitizer monolayer at the interface of crystalline state organic and inorganic semiconductors. The organic-inorganic hybrid thin-film photocell generates a high photovoltage of 1.2 V, yielding an energy conversion efficiency of up to 1.5%. 相似文献
110.
Cyano-bridged Mn(III)-M(III) single-chain magnets with M(III)=Co(III), Fe(III), Mn(III), and Cr(III)
Miyasaka H Madanbashi T Saitoh A Motokawa N Ishikawa R Yamashita M Bahr S Wernsdorfer W Clérac R 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(13):3942-3954
A series of isostructural cyano-bridged Mn(III)(h.s.)-M(III)(l.s.) alternating chains, [Mn(III)(5-TMAMsalen)M(III)(CN)(6)]?4H(2)O (5-TMAMsalen(2-)=N,N'-ethylenebis(5-trimethylammoniomethylsalicylideneiminate), Mn(III)(h.s.)=high-spin Mn(III), M(III)(l.s.)=low-spin Co(III), Mn-Co; Fe(III), Mn-Fe; Mn(III), Mn-Mn; Cr(III), Mn-Cr) was synthesized by assembling [Mn(III)(5-TMAMsalen)](3+) and [M(III)(CN)(6)](3-). The chains present in the four compounds, which crystallize in the monoclinic space group C2/c, are composed of an [-Mn(III)-NC-M(III)-CN-] repeating motif, for which the -NC-M(III)-CN- motif is provided by the [M(III)(CN)(6)](3-) moiety adopting a trans bridging mode between [Mn(III)(5-TMAMsalen)](3+) cations. The Mn(III) and M(III) ions occupy special crystallographic positions: a C(2) axis and an inversion center, respectively, forming a highly symmetrical chain with only one kind of cyano bridge. The Jahn-Teller axis of the Mn(III)(h.s.) ion is perpendicular to the N(2)O(2) plane formed by the 5-TMAMsalen tetradentate ligand. These Jahn-Teller axes are all perfectly aligned along the unique chain direction without a bending angle, although the chains are corrugated with an Mn-N(axis) -C angle of about 144°. In the crystal structures, the chains are well separated with the nearest inter-chain M???M distance being relatively large at 9?? due to steric hindrance of the bulky trimethylammoniomethyl groups of the 5-TMAMsalen ligand. The magnetic properties of these compounds have been thoroughly studied. Mn-Fe and Mn-Mn display intra-chain ferromagnetic interactions, whereas Mn-Cr is characterized by an antiferromagnetic exchange that induces a ferrimagnetic spin arrangement along the chain. Detailed analyses of both static and dynamic magnetic properties have demonstrated without ambiguity the single-chain magnet (SCM) behavior of these three systems, whereas Mn-Co is merely paramagnetic with S(Mn)=2 and D/k(B)=-5.3?K (D being a zero-field splitting parameter). At low temperatures, the Mn-M compounds with M=Fe, Mn, and Cr display remarkably large M versus H hysteresis loops for applied magnetic fields along the easy magnetic direction that corresponds to the chain direction. The temperature dependence of the associated relaxation time for this series of compounds systematically exhibits a crossover between two Arrhenius laws corresponding to infinite-chain and finite-chain regimes for the SCM behavior. These isostructural hetero-spin SCMs offer a unique series of alternating [-Mn-NC-M-CN-] chains, enabling physicists to test theoretical SCM models between the Ising and Heisenberg limits. 相似文献