Copolymers from Castor Oil Prepolymers (COP). 1. Copolymerization of Acrylonitrile with COP

The copolymerization of castor oil prepolymer (COP) was attempted with vinyl monomers in the presence of a free radical initiator at 75°C. It was found that acrylonitrile copolymerizes with COP in good yield, The copolymers were yellow brown in color and were soluble in hot dimethylformamide. The percentage composition of the copolymers was determined by the nitrogen of the copolymers. Their reactivity ratios were determined to be r₁ = 0.53, r₂ = 1.53.     

Copolymers from Castor Oil Prepolymers (COP). 2. Copolymerization of Styrene with COP

A study of copolymerization of castor oil prepolymers (COP) with styrene has been made at 75°C using benzoyl peroxide as initiator. It has been found that good yields of copolymers (high molecular weight M _n = 123,989) are obtained at a low concentration of COP. With an increasing concentration of COP in the binary mixture, copolymers with decreasing molecular weight are obtained. This is explained as due to presence of a high percentage of oxygen (from COP) in the system which is acting as a chain transfer agent.     

CH local mode overtone excitations in benzyl chloride—A conformational study

The CH local mode overtone spectrum of benzyl chloride in the visible and NIR regions studied by laser induced thermal lens and conventional NIR absorption is presented. The analysis shows that the −CH₂Cl group is symmetrically oriented with respect to the benzene ring, thus finalizing one of the two possible conformational models predicted by electron diffraction studies. The aryl CH bonds have a slightly larger force constant than that in benzene.     

Polarization of emission spectra from Ti3+-doped oxide crystals

The Ti³⁺ ion in YAlO₃ (YAP), Y₃Al₅O₁₂ (YAG), and Al₂O₃ crystals occupies distorted octahedral sites relative to the nearest neighbour ligand ions. Such distortions are of even-parity in YAG where the zero-phonon lines in emission occur via magnetic dipole transitions. In contrast, the zero-phonon transitions occur by electric dipole processes in Ti³⁺:YAP and Ti³⁺:Al₂O₃ where there are odd-parity distortions from octahedral symmetry. This paper reports measurements of the zero-phonon lines of Ti³⁺ ions in YAP, YAG, and Al₂O₃ at 10 K. The zero-phonon lines of Ti³⁺:YAP are strongly polarized perpendicular to the tetragonal axis and those of Ti³⁺:Al₂O₃ parallel to the trigonal axis. The experimental results are shown to be in accord with a molecular orbital model of the radiative transition according to which the transition intensities derive from odd-parity ligand wavefunctions induced into even-parity ground and excited Ti³⁺ wavefunctions by odd-parity crystal distortions.     

Characterisation of Plasmodium falciparum aspartic protease inhibition by piperidine derivatives

Piperidine derivatives are reported to exhibit a variety of pharmacological activities. In this article, synthesis and aspartic protease inhibitory activity of three nitrophenacyl derivatives of N-methyl-4-hydroxy piperidine are reported. Enzyme assays showed that the attachment of a nitro group in the benzene ring plays an important role in the inhibition of plasmepsin-II of Plasmodium falciparum. The compound 1-methyl-1-(4'-nitrophenacyl)-4-hydroxypiperidinium bromide (3), consisting of a nitro group at the para position, was the most active at the concentration of 1.0?μM. The activity of the compounds was evaluated through the observed orientation and diagrammatic representation of nitrophenacyl derivatives of 4-hydroxy piperidine.     

Production of Biodegradable Polymer from Agro-Wastes in Alcaligenes sp. and Pseudomonas sp.

The present study was aimed to evaluate the suitability of agro-wastes and crude vegetable oils for the cost-effective production of poly-β-hydroxybutyrate (PHB), to evaluate growth kinetics and PHB production in Alcaligenes faecalis RZS4 and Pseudomonas sp. RZS1 with these carbon substrates and to study the biodegradation of PHB accumulated by these cultures. Alcaligenes faecalis RZS4 and Pseudomonas sp. RZS1 accumulates higher amounts of PHB corn (79.90% of dry cell mass) and rice straw (66.22% of dry cell mass) medium respectively. The kinetic model suggests that the Pseudomonas sp. RZS1 follows the Monod model more closely than A. faecalis RZS4. Both the cultures degrade their PHB extract under the influence of PHB depolymerase. Corn waste and rice straw appear as the best and cost-effective substrates for the sustainable production of PHB from Alcaligenes faecalis RZS4 and Pseudomonas sp. RZS1. The biopolymer accumulated by these organisms is biodegradable in nature. The agro-wastes and crude vegetable oils are good and low-cost sources of nutrients for the growth and production of PHB and other metabolites. Their use would lower the production cost of PHB and the low-cost production will reduce the sailing price of PHB-based products. This would promote the large-scale commercialization and popularization of PHB as an ecofriendly bioplastic/biopolymer.