Photoreaction of Benzenecarbothioamide with Aldehydes. Facile Synthesis of Tetracyclic Imidazoles.1)

Photoreaction of benzenecarbothioamide with various aldehydes in benzene solution gave 2-substituted phenanthroimidazoles.     

Effect of substrate orientation on the defect-induced bound exciton emissions in GaAs grown by molecular beam epitaxy

The dependence of photoluminescence (PL) spectra at 2 K on the substrate orientation is reported for GaAs grown by molecular beam epitaxy (MBE). Samples investigated are GaAs grown on (n11)A- and (n11)B-oriented substrates where n is 2, 3, 5 and 9, and those on (321)A- (110)B- and (100)A-oriented ones. It was demonstrated that emissions denoted by defect-induced bound excitons (DIBE) present strong crystal orientation dependence. In the (n11) series, DIBE was enhanced peculiarly in (211)A and (311)A substrates and two sharp emissions denoted by t^* and v₃ were specifically observed there, but they were completely quenched for the (211)B substrate. When n exceeds 3, DIBE was observed ubiquitously in (n11)A and (n11)B substrates. The (321)A substrate indicated a most idiosyncratic DIBE with a strong enhancement of t^* and v₃. These results show that the spectral features pertinent to DIBE fully reflect the whole stacking process of impinging molecular beams on the growth front which is governed by the surface structure inherent to the surface dangling bonds of the substrate.     

Preparation and characterization of thin films of monomeric and polymeric octacyanophthalocyanines

Thin films were prepared on substrates, cleavage surface of KCl single crystal, and metallic copper, by reaction of 1,2,4,5-tetracyanobenzene with the substrate at various temperatures. The films were characterized by elemental analysis, IR, and UV/VIS spectroscopies. The films were observed by scanning electron microscopy. The films produced on copper at temperatures between 300 and 400°C consisted of copper octacyanophthalocyanine and its polymer with ladder structure. The ratio of polymer to monomer increased with elevating the reaction temperature. The films were composed of ribbon-like crystals. The film produced on copper above 450°C was composed of an amorphous and continuous layer of polymeric copper phthalocyanine. The film produced on KCl at temperatures between 250 and 350°C consisted of potassium octacyanophthalocyanine and its polymer with ladder structure. The film produced on KCl above 450°C was polymeric potassium phthalocyanine. Those films contained more metal content than that required stoichiometrical.     

Fixed Width Confidence Region for the Mean of a Multivariate Normal Distribution

Srivastava gave an asymptotically efficient and consistent sequential procedure to obtain a fixed-width confidence region for the mean vector of any p-dimensional random vector with finite second moments. For normally distributed random vectors, Srivastava and Bhargava showed that the specified coverage probability is attained independent of the width, the mean vector, and the covariance matrix by taking a finite number of observations over and above T prescribed by the sequential rule. However, the problem of showing that E(T−n₀) is bounded, where n₀ is the sample size required if the covariance matrix were known, has not been available. In this paper, we not only show that it is bounded but obtain sharper estimates of E(T) on the lines of Woodroofe. We also give an asymptotic expansion of the coverage probability. Similar results have recently been obtained by Nagao under the assumption that the covariance matrix Σ=∑^k_i=1 σ_iA_i and ∑^k_i=1 A_i=I, where A_i's are known matrices. We obtain the results of this paper under the sole assumption that the largest latent root of Σ is simple.     

Numerical Study on Efficient Optical Switching Based on the Nonlinear Phenomenon in a Guided-Mode Resonant Grating with Kerr Medium

Optical switching in a guided-mode resonant grating (GMRG) with a Kerr medium was numerically simulated by the nonlinear finite differential time domain (FDTD) method. The asymmetric resonant grating was adopted to have two resonant reflection peaks for the pump light and the probe light. When the pump light had a wavelength which was slightly longer than the resonant wavelength, the light was suddenly enhanced at a certain intensity because of the nonlinear resonance phenomenon. This resonance is effective in reducing the pump intensity for optical switching. When we assumed the resonant grating of polydiacetylene toluene sulphonate (PTS) with a linear refractive index of 1.88, a third-order susceptibility of 8.5 × 10⊃−0 esu and Q factors of resonant reflection which were ∼800, the pump light of 15 kW/mm⊃ changed transmittance of the probe light from 0 to 80%. 2005 The Optical Society of Japan     

Radiative pion capture in 12C and 16O

Radiative pion capture in ¹²C and ¹⁶O is investigated. An effective interaction Hamiltonian based upon the CGLN theory is employed. Capture rates in ¹²C and ¹⁶O from Is and 2p pionic orbits are calculated by using the nuclear model of Kamimura, Ikeda and Arima for the odd parity states of ¹²C, and that of Walker with strong ground state correlations, for the odd parity states of ¹⁶O. The results are compared with those of the 1p-1h nuclear model under the Tamm-Dancoff and random phase approximations of Gillet and Vinh Mau. Detailed examinations are made for the transitions to low-lying states with 1⁺ and 2⁺ for ¹²C and with 1^?, 2^? and 3^? for ¹⁶O by using the Cohen-Kurath and the Walker models, respectively. The results are in good agreement with the recent experimental data from Berkeley.     

Mass spectra of some alkyl isoxazoles

The mass spectra of several compounds obtained during the process of Stork's isoxazole synthesis9 as well as the related isoxazoles have been investigated. The fragmentations of simple alkyl isoxazoles are nicely formulated via azirine intermediates. A striking difference between the spectra of isoxazoles and those of methylfurans as to the relative abundance of [M — l] peaks is noteworthy. The very low abundance of these peaks in the former reflects the unique character of isoxazole nucleus due to the preferential cleavage of N? O linkage rather than a benzylic C? H bond rupture. If an alkyl substituent is present at 4-position in 3,5-dimethylisoxazoles, strong peaks at m/e 110, 68 and 43 are common in their spectra. The analyses of metastable transitions and high resolution measurements have demonstrated that the formation of these ions can be interpreted by a mechanism involving the cleavage of N? O linkage.