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71.
72.
Hosni K Msaâda K Ben Taârit M Chahed T Marzouk B 《Natural product communications》2011,6(11):1731-1734
The chemical composition of the essential oils obtained by hydrodistillation from the aerial parts of the Tunisian Hypericum perforatum and H. ericoides ssp. roberti was elucidated by a combination of GC and GC-MS analyses. The main constituents of the oil of H. perforatum were alpha-pinene (11.8%), alpha-ylangene (10.4%), germacrene-D (9.5%), n-octane (6.5%) and alpha-selinene (5.9%). The oil of H. ericoides ssp. roberti exhibited a higher amount of aliphatic and branched hydrocarbons and the main constituents were n-octane (29.1%), alpha-pinene (10.9%), pulegone (7.7%) and acetophenone (7%). Both qualitative and quantitative differences were observed between the studied oils. This chemical variability seems likely to result from the genetic variability, since samples of both species were collected at the same location and processed under the same conditions. 相似文献
73.
A new reagent for spectrophotometric determination of Mo(VI) was developed utilizing micellar effects. For this purpose, differences in the ultraviolet and visible spectral properties of Mo(VI), gallic acid, L-serine, and their binary and ternary solutions were studied in the presence and absence of cationic, anionic, and non-ionic surface active agents. L-serine was observed to form binary complexes and a ternary complex with Mo(VI) and gallic acid below its isoelectric point. The maximum Mo(VI) sensitivity was exerted by the Mo(VI) + gallic acid + L-serine + hexadecyltrimethylammonium bromide system at pH of 4.5. This system was proposed for use in the spectrophotometric determination of Mo(VI) as a superior alternative to the Mo(VI) + gallic acid + hexadecyltrimethylammonium bromide system and to most of the instrumental analysis methods referred to in the literature. The mechanism of micellar effects was discussed on the basis of the spectral data obtained above and below the isoelectric point of L-serine and explained in terms of the molecular charge of the substrates and the surfactants. 相似文献
74.
2-(2-Aminoethylamino)ethanol (L) reacts with cupric bromide in dimethylformamide to give a mononuclear complex of Cu(II) [L2Cu]Br2, with six-coordinate distorted octahedral geometry, in which two molecules of tridentate (N,N,O) ligand are involved. The structure was confirmed by spectroscopic methods, elemental and thermogravimetric analyses, and magnetic measurements. Optimization of possible configurations indicated the formation of the trans structure of the complex. Experimental results indicate that the investigated complex, bis[2-(2-aminoethylamino)ethanol] copper(II) bromide, behaves as a semiconductor in the studied temperature range of 298–388 K. Gas sensing properties of the film for the volatile organic compounds (VOCs): acetone, tetra-chloromethane, chloroform, ethanol, and methanol, were also investigated as a function of vapor concentration and temperature in dark. The film showed maximum sensitivity to tetrachloromethane and ethanol vapors at room temperature. Responses of the film to the tested gases are reversible. 相似文献
75.
Bis‐benzimidazolium salts were prepared successfully from commercially available and inexpensive o‐phenylenediamine through a series of simple reactions. The bis‐NHC‐Pd complexes prepared in situ can catalyze Suzuki‐Miyaura cross‐coupling reaction under very mild conditions in aqueous media with excellent yields. The efficiency of this reaction is demonstrated by its compatibility with a range of functional groups. Di‐ortho‐substituted biaryls could be accomplished in 89–99% yields. Moreover, the rigorous exclusion of air or moisture is not required in these transformations. 相似文献
76.
Fatma Taşdelen Ali Olgun Gülen Başcanbaz-Tunca 《Proceedings Mathematical Sciences》2007,117(3):387-399
We introduce certain linear positive operators and study some approximation properties of these operators in the space of
functions, continuous on a compact set, of two variables. We also find the order of this approximation by using modulus of
continuity. Moreover we define an rth order generalization of these operators and observe its approximation properties. Furthermore, we study the convergence
of the linear positive operators in a weighted space of functions of two variables and find the rate of this convergence using
weighted modulus of continuity. 相似文献
77.
A. Gadea B. Rubio J. L. Taín J. Rico J. Bea L. M. García-Raffi P. Kleinheinz D. Schardt E. Roeckl R. Kirchner J. Blomqvist 《Zeitschrift für Physik A Hadrons and Nuclei》1996,355(1):253-259
Decay experiments for148Ho 6? and150Tm 6? were carried out at the GSI On-line mass separator using 5 MeV/A58Ni-beams on94Mo and96Ru targets. Gammaγ-andγX-coincidences established the150Tm 6? decay scheme, and e? gave firm I π assignments for148Dy and150Er levels fed in the decays. It was found that the previously unknown 6 1 ? state in150Er receives significantβ-strength, which strongly suggestsπh 11/2 νs 1 2/?1 character for the150Tm 6? isomer. The results are discussed in terms of the expected GT strength function. Shell model calculations for theπh 11 2/4 yrast states are presented. 相似文献
78.
Iridoid glycosides from Globularia davisiana 总被引:1,自引:0,他引:1
Caliş I Kirmizibekmez H Taşdemir D Ireland CM 《Chemical & pharmaceutical bulletin》2002,50(5):678-680
From the ethanolic extract of the aerial parts of Globularia davisiana, a new iridoid glycoside, davisioside (1), was isolated. Davisioside (1) comprises a rare iridoid aglycone structure with a saturated double bond between C-3 and C-4. Nine known iridoid glycosides, asperuloside (2), alpinoside (3), geniposide (4), globularin (5), globularicisin (6), 10-O-benzoylcatalpol (7), lytanthosalin (8), melampyroside (9), agnuside (10), and three known phenylethanoid glycosides, verbascoside, isoacteoside and leucosceptoside A were also isolated and characterized. The structures of the isolates were established by spectroscopic methods (one-dimensional (1D)- and two-dimensional (2D)-NMR, MS). 相似文献
79.
Turgut Gündüz Esma Kiliç Güleren Özkan Muhammed F. Awaad Mustafa Taştekin 《Analytica chimica acta》1990
Nineteen phenolic acids, namely phenol, 2-nitrophenol, 3-nitrophenol, 4-nitrophenol, 2,4-dinitrophenol, 2,5-dinitrophenol, 2,6-dinitrophenol, 2,4,6-trinitrophenol, 4-chlorophenol, 2,4,6-trichlorophenol, 1,2-dihydroxybenzene, 1,3-dihydroxybenzene, 1,4-dihydroxybenzene, 1,2,3-trihydroxybenzene, 2-aminophenol, 3-aminophenol, 4-aminophenol, 3-cresol and 4-cresol, were titrated conductimetrically and potentiometrically with triethylamine and tetrabutylammonium hydroxide in acetonitrile under a nitrogen atmosphere at 25°C. Most exhibited normal behaviour on titration with triethylamine, but only 2,4-dinitrophenol, 2,6-dinitrophenol and 2,4,6-trinitrophenol gave useful characteristic and stoichiometric conductimetric titration curves. None of the compounds gave a meaningful conductimetric titration curve on titration with tetrabutylammonium hydroxide, which is a much stronger base than triethylamine. With three exceptions, all compounds exhibited stoichiometric well shaped potentiometric titration curves. Potentiometric titration curves of the phenolic acids with tetrabutylammonium hydroxide in acetonitrile are very similar to those of strong acids obtained in aqueous media with strong bases. Acetonitrile is a suitable solvent for titrating some of the weak phenolic acids conductimetrically with triethylamine, and is an excellent medium for titrating them potentiometrically with tetrabutylammonium hydroxide under a nitrogen atmosphere at 25°C. 相似文献
80.
This is the first of a series of papers on the perturbative treatment of screened coulomb potential systems in quantum mechanics. Its content is mainly devoted to the evaluation of first four terms in a convergent energy expansion of Yukawa potential. For this purpose, a weighted eigenvalue problem of Laplacian accompanied by spherical symmetry is employed to find the inverse of the Schrödinger operator for unperturbed case (which is assumed to be the Hamiltonian of Hydrogen-like systems). Some very encouraging numerical results are also given for illustrative purposes. 相似文献