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81.
P.K.A. De Witt Huberts L. Lapikás H. De Vries J.B. Bellicard J.M. Cavedon B. Frois M. Huet Ph. Leconte A. Nakada Phan Xuan Ho S.K. Platchkov I. Sick 《Physics letters. [Part B]》1977,71(2):317-320
Cross sections for magnetic elastic electron scattering of high multipolarity from 51V and 59Co have been measured. They are interpreted in terms of the rms radius of the proton orbit. The results for 51V and 59Co 1f rms radii are smaller by 3% and 9%, respectively, than predicted by the Hartree-Fock-Bogoliubov theory. 相似文献
82.
Rheologica Acta - Comme on le fait couramment en Thermodynamique des processus irréversibles, nous proposons d'inclure explicitement le bilan entropique dans la mise en équation des... 相似文献
83.
84.
Activated acetylnic reagents add to heterocyclic enamines 4,5-dihydro-1H-benzo[b]azepines and by electrocyclisation, give 6,7-dihydro-1H-benzo[b]azoninines. The structure of those new heterocycles is demonstrated by mass spectra, 1H and 13C nmr. 相似文献
85.
86.
Stéphane GuillarmeStéphanie Legoupy Anne-Marie AubertinCécile Olicard Nathalie BourgougnonFrançois Huet 《Tetrahedron》2003,59(12):2177-2184
The synthesis of several acyclic nucleosides 5 and 6, analogs of penciclovir, was achieved by Michael addition as the key step. This reaction worked not only for the protected natural bases but even for the less nucleophilic deaza purine and deaza pyrimidine. 相似文献
87.
Jiménez MV Sola E Egea MA Huet A Francisco AC Lahoz FJ Oro LA 《Inorganic chemistry》2000,39(21):4868-4878
The course of methyl iodide oxidative addition to various nucleophilic complexes, [Ir2(mu-1,8-(NH)2naphth)(CO)2(PiPr3)2] (1), [IrRh(mu-1,8-(NH)2naphth)(CO)2(PiPr3)2] (2), and [Rh2(mu-1,8-(NH)2naphth)(CO)2(PR3)2] (R = iPr, 3; Ph, 4; p-tolyl, 5; Me, 6), has been investigated. The CH3I addition to complex 1 readily affords the diiridium(II) complex [Ir2(mu-1,8-(NH)2naphth)I(CH3)(CO)2(PiPr3)2] (7), which undergoes slow rearrangement to give a thermodynamically stable stereoisomer, 8. The reaction of the Ir-Rh complex 2 gives the ionic compound [IrRh(mu-1,8-(NH)2naphth)(CH3)(CO)2(PiPr3)2]I (10). The dirhodium compounds, 3-5, undergo one-center additions to yield acyl complexes of the formula (Rh2(mu-1,8-(NH)2naphth)I(COCH3)(CO)(PR3)2] (R = iPr, 12; Ph, 13; p-tolyl, 14). The structure of 12 has been determined by X-ray diffraction. Further reactions of these Rh(III)-Rh(I) acyl derivatives with CH3I are productive only for the p-tolylphosphine derivative, which affords the bis-acyl complex [Rh2(mu-1,8-(NH)2naphth)(CH3CO)2I2(P(p-tolyl)3)2] (15). The reaction of the PMe3 derivative, 6, allows the isolation of the bis-methyl complex [Rh2(mu-1,8-(NH)2naphth)(mu-I)(CH3)2(CO)2(PMe3)2]I (16a), which emanates from a double one-center addition. Upon reaction with methyl triflate, the starting materials, 1, 2, 3, and 6, give the isostructural cationic methyl complexes 9, 11, 17, and 18, respectively. The behavior of these cationic methyl compounds toward CH3I, CH3OSO2CF3, and tetrabutylamonium iodide is consistent with the role of these species as intermediates in the SN2 addition of CH3I. Compounds 18 and 17 react with an excess of methyl triflate to give [Rh2(mu-1,8-(NH)2naphth)(mu-OSO2CF3)(CH3)2(CO)2(PMe3)2][CF3SO3] (19) and [Rh2(mu-1,8-(NH)2naphth)(OSO2CF3)(COCH3)(CH3)(CO)(PiPr3)2][CF3SO3] (20), respectively. Upon treatment with acetonitrile, complexes 17 and 18 give the isostructural cationic acyl complexes [Rh2(mu-1,8-(NH)2naphth)(COCH3)(NCCH3)(CO)(PR3)2][CF3SO3] (R = iPr, 21; Me, 22). A kinetic study of the reaction leading to 21 shows that formation of these complexes involves a slow insertion step followed by the fast coordination of the acetonitrile. The variety of reactions found in this system can be rationalized in terms of three alternative reaction pathways, which are determined by the effectiveness of the interactions between the two metal centers of the dinuclear complex and by the steric constraints due to the phosphine ligands. 相似文献
88.
The Rayleigh wave, that propagates at the free surface of semi-infinite anisotropic medium, is composed of three inhomogeneous partial waves, each propagating along the surface with a different attenuation along the depth. Since this wave does not exhibit an attenuation on the surface, let us call it the homogeneous Rayleigh wave. The associated slowness corresponds to the real solution of the Rayleigh dispersion equation. Besides this classical solution, an infinite number of complex solutions of the Rayleigh dispersion equation exits. For such particular Rayleigh waves, the slowness vector, i.e. the identical component on the surface of the slowness of each partial waves, is taken to be complex. Thus, these Rayleigh waves are attenuated on the surface and as shown here, their attenuation is normal to the ray direction (or the energy velocity direction). Similarly to the infinite inhomogeneous plane waves which can be associated with complex rays, we call these waves, inhomogeneous Rayleigh waves. We use the inhomogeneous skimming waves, which are inhomogeneous plane waves, and the inhomogeneous Rayleigh waves to explain differently the usual diffraction phenomena on the free surface which cannot be explained by the real ray theory. For example, the arrival time of the wave packet observed beyond the cusp is in perfect accordance with the arrival time of some specific inhomogeneous Rayleigh waves. We show that these results are in agreement with the computation of the Green function. They apply to the theory of surface waves in linear elastodynamics with intrinsic anisotropy as well as to the theory of surface waves in linearised (incremental) elastodynamics with strain-induced anisotropy (also known as small-amplitude waves superimposed on the large static homogeneous deformation of a non-linear solid). 相似文献
89.
S.A. Tashkun V.I. Perevalov J.-L. Teffo M. Lecoutre T.R. Huet A. Campargue D. Bailly M.P. Esplin 《Journal of Molecular Spectroscopy》2000,200(2)
The effective operator approach is applied to the calculation of both line positions and line intensities of the 13C16O2 molecule. About 11 000 observed line positions of 13C16O2 selected from the literature have been used to derive 84 parameters of a reduced effective Hamiltonian globally describing all known vibrational–rotational energy levels in the ground electronic state. The standard deviation of the fit is 0.0015 cm−1. The eigenfunctions of this effective Hamiltonian have then been used in fittings of parameters of an effective dipole-moment operator to more than 600 observed line intensities of the cold and hot bands covering the ν2 and 3ν2 regions. The standard deviations of the fits are 3.2 and 12.0% for these regions, respectively. The quality of the fittings and the extrapolation properties of the fitted parameters are discussed. A comparison of calculated line parameters with those provided by the HITRAN database is given. Finally, the first observations of the 2ν1 + 5ν3 and ν1 + 2ν2 + 5ν3 absorption bands by means of photoacoustic spectroscopy (PAS) is presented. The deviations of predicted line positions from observed ones is found to be less than 0.1 cm−1, and most of them lie within the experimental accuracy (0.007 cm−1) once the observed line positions are included in the global fit. 相似文献
90.
A short stereoselective synthesis of N-acylamino-1,3-dienes was developed starting from the cyclobutene lactam 8, which was obtained from 2-hydroxypyridine by a photochemical electrocyclic reaction. The tert-butoxycarbonyl derivative 17 was prepared to facilitate nucleophilic attacks to the carbonyl group, and the subsequent thermal ring opening provided dienes 18-21. One of these (20) was used in the synthesis of the cyclohexene nucleoside 30. A Diels-Alder reaction between diene 20 and maleic anhydride provided the endo-cycloadduct 22a. Three additional steps yielded amine 26. Construction of the uracil moiety afforded intermediate 29. Cyclization and removal of the protecting groups occurred in one step in the presence of ammonia, giving the target molecule 30. Diene 20 also underwent [4 + 2] cycloaddition with methyl acrylate to provide predominantly the endo-product 23a, regioselectively. 相似文献