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121.
Dr. Ravi B. Shankar Elan D. R. Mistry Dr. Daphné Lubert-Perquel Dr. Irena Nevjestic Prof. Sandrine Heutz Prof. Camille Petit 《Chemphyschem》2022,23(13):e202100854
Porous boron nitride (BN), a combination of hexagonal, turbostratic and amorphous BN, has emerged as a new platform photocatalyst. Yet, this material lacks photoactivity under visible light. Theoretical studies predict that tuning the oxygen content in oxygen-doped BN (BNO) could lower the band gap. This is yet to be verified experimentally. We present herein a systematic experimental route to simultaneously tune BNO's chemical, magnetic and optoelectronic properties using a multivariate synthesis parameter space. We report deep visible range band gaps (1.50–2.90 eV) and tuning of the oxygen (2–14 at.%) and specific paramagnetic OB3 contents (7–294 a.u. g−1). Through designing a response surface via a design of experiments (DOE) process, we have identified synthesis parameters influencing BNO's chemical, magnetic and optoelectronic properties. We also present model prediction equations relating these properties to the synthesis parameter space that we have validated experimentally. This methodology can help tailor and optimise BN materials for heterogeneous photocatalysis. 相似文献
122.
Grace K. Poon Graham M. F. Bisset Prakash Mistry 《Journal of the American Society for Mass Spectrometry》1993,4(7):588-595
In this study, several anticancer drugs and their analogues consisting of organic and organometallic compounds were analyzed by electrospray ionization mass spectrometry (ESI/MS) using a quadrupole mass spectrometer. Protonated molecular ions [M+H]+ were observed for all of the compounds studied, and in the case of the two steroid sulfates, deprotonated molecular ions [M-H]? were obtained. Tandem mass spectrometry was performed on these quasimolecular ions, and the product ions formed provided useful fragmentation patterns that were characteristic for the compounds. This study provides evidence that ESI/MS is a sensitive technique for structure confirmation and identification of small organic and organometallic molecules. 相似文献
123.
Bebek C Berkelman K Blucher E Byrd J Cassel DG Cheu E Coffman DM Copie T Crawford G DeSalvo R DeWire JW Drell P Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Kowalewski R Kreinick DL Kubota Y Lewis JD Mistry NB Mueller J Namjoshi R Nandi S Nordberg E O'Grady C Perticone D Peterson D Pisharody M Riley D Sapper M Silverman A Stone S Worden H Worris M Sadoff AJ Avery P Besson D Garren L Yelton J Bowcock T Kinoshita K Pipkin FM Procario M Wilson R Wolinski J 《Physical review letters》1989,62(1):8-11
124.
Baringer P McIlwain RL Miller DH Shibata EI Behrends S Guida JM Guida JA Morrow F Poling R Thorndike EH Tipton P Alam MS Katayama N Kim IJ Li WC Lou XC Sun CR Tanikella V Bortoletto D Goldberg M Holmes R Horwitz N Jawahery A Lubrano P Moneti GC Sharma V Shipsey IP Thoma P Csorna SE Letson T Mestayer MD Panvini RS Word GB Bean A Bobbink GJ Brock IC Engler A Ferguson T Kraemer RW Rippich C Vogel H Bebek C Berkelman K Blucher E Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Galik RS Gilchriese MG 《Physical review letters》1987,59(18):1993-1996
125.
Bortoletto D Chen A Garren L Goldberg M Horwitz N Jawahery A Lubrano P Moneti GC Trahern CG van Hecke H Csorna SE Mestayer MD Panvini RS Word GB Yi X Bean A Ferguson T Avery P Bebek C Berkelman K Blucher E Cassel DG Copie T DeSalvo R DeWire JW Ehrlich R Galik RS Gilchriese MG Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Holzner S Ito M Kandaswamy J Kowalewski R Kreinick DL Kubota Y Mistry NB Mueller J Nordberg E Ogg M Peterson D Perticone D Pisharody M Read K Riley D Silverman A 《Physical review letters》1986,56(8):800-803
126.
Asner DM Athanas M Bliss DW Brower WS Masek G Paar HP Gronberg J Korte CM Kutschke R Menary S Morrison RJ Nakanishi S Nelson HN Nelson TK Qiao C Richman JD Roberts D Ryd A Tajima H Witherell MS Balest R Cho K Ford WT Lohner M Park H Rankin P Roy J Smith JG Alexander JP Bebek C Berger BE Berkelman K Bloom K Cassel DG Cho HA Coffman DM Crowcroft DS Dickson M Drell PS Dumas DJ Ehrlich R Elia R Gaidarev P Gittelman B Gray SW Hartill DL Heltsley BK Jones CD Jones SL Kandaswamy J Katayama N Kim PC 《Physical review D: Particles and fields》1996,54(7):4211-4220
127.
Alexander JP Bebek C Berkelman K Bloom K Browder TE Cassel DG Cho HA Coffman DM Crowcroft DS Drell PS Dumas D Ehrlich R Gaidarev P Garcia-Sciveres M Geiser B Gittelman B Gray SW Hartill DL Heltsley BK Henderson S Jones CD Jones SL Kandaswamy J Katayama N Kim PC Kreinick DL Ludwig GS Masui J Mevissen J Mistry NB Ng CR Nordberg E Patterson JR Peterson D Riley D Salman S Sapper M Würthwein F Avery P Freyberger A Rodriguez J Yang S Yelton J Cinabro D Liu T Saulnier M Wilson R Yamamoto H Bergfeld T 《Physical review letters》1995,74(16):3113-3117
128.
Balest R Daoudi M Ford WT Johnson DR Lingel K Lohner M Rankin P Smith JG Alexander JP Bebek C Berkelman K Besson D Browder TE Cassel DG Cho HA Coffman DM Drell PS Ehrlich R Galik RS Garcia-Sciveres M Geiser B Gittelman B Gray SW Hartill DL Heltsley BK Honscheid K Jones CD Kandaswamy J Katayama N Kim PC Kreinick DL Ludwig GS Masui J Mevissen J Mistry NB Ng CR Nordberg E Ogg M O'Grady C Patterson JR Peterson D Riley D Sapper M Selen M Worden H Worris M Würthwein F Avery P Freyberger A Rodriguez J 《Physical review D: Particles and fields》1993,47(9):R3671-R3675
129.
Mistry S Arnold DC Nuttall CJ Lappas A Green MA 《Chemical communications (Cambridge, England)》2004,(21):2440-2441
We report a new series of sodium cobalt oxyhydrates that contains the same two dimensional building blocks as superconducting NaxCoO2.yH2O. The absence of superconductivity emphasises the importance of the CoO2 stacking arrangement on the resultant electronic properties. 相似文献
130.
Metcalfe CL Ott M Patel N Singh K Mistry SC Goff HM Raven EL 《Journal of the American Chemical Society》2004,126(49):16242-16248
The mammalian heme peroxidases are distinguished from their plant and fungal counterparts by the fact that the heme group is covalently bound to the protein through ester links from glutamate and aspartate residues to the heme 1- and 5-methyl groups and, in the case of myeloperoxidase, through an additional sulfonium link from the Cbeta of the 2-vinyl group to a methionine residue. To duplicate the sulfonium link in myeloperoxidase and to obtain information on its mechanism of formation, we have engineered a methionine residue close to the 2-vinyl group in recombinant pea cytosolic ascorbate peroxidase (rpAPX) by replacement of Ser160 by Met (S160M variant). The S160M variant is isolated from Escherichia coli as apo-protein. Reconstitution of apo-S160M with exogenous heme gives a red protein (S160M(R)) which has UV-visible (lambda(max)/nm = 407, 511, 633) and steady-state kinetic (kcat = 156 +/- 7 s(-1), KM = 102 +/- 15 microM) properties that are analogous to those of rpAPX. The reaction of S160M(R) with H2O2 gives a green protein (S160M(G)). Electronic spectroscopy, mass spectrometry, and HPLC analyses are consistent with the formation of a covalent linkage between the methionine residue and the heme vinyl group in S160M(G). Single-wavelength and photodiode array stopped-flow kinetic analyses identify a transient Compound I species as a reaction intermediate. The results provide the first direct evidence that covalent heme linkage formation occurs as an H2O2-dependent process that involves Compound I formation. A mechanism that is consistent with the data is presented. 相似文献