塞曼激光陀螺磁屏蔽设计与实现

为提高塞曼激光陀螺精度,分析了塞曼激光陀螺磁的磁敏感特性,指出敏感轴方向是塞曼激光陀螺的最大磁灵敏度方向,该方向为产生磁误差的主要方向。研究了低频磁场屏蔽理论与加工工艺关键技术,结合激光陀螺的环境适应性要求,实现了固态激光陀螺磁屏蔽结构。在三轴磁试验台上进行了陀螺磁敏感性测试,陀螺磁灵敏度值减少到原来的1/1000,实测系数达到2.0(°)/(h.mT),该值满足中等精度激光陀螺的实用要求。     

两大部类扩大再生产的充分必要条件与求解

两大部类扩大再生产的充分必要条件也就是马克思扩大再生产公式有解的充分必要条件.直到目前,由于还没有严谨地提出对于扩大再生产公式的一般求解方法,因而也没有严格地确定扩大再生产的充分必要条件.本文基于已经有研究获得的扩大再生产的一个必要条件,建立一种求解扩大再生产问题的一般方法,从而证明这个必要条件能够成为充分条件,由此确定它是充分必要条件.进而使用变量替换法,给出了通过直接求解两个部类的剩余价值积累率而求解扩大再生产问题的另一种方法.最后引用《资本论》中的两个实例,对所给出的两种求解扩大再生产问题的一般方法做了计算验证.     

Two-Photon Fluorescence Property and Ultrafast Dynamics of Two Dipolar Compounds with Dipicolinate as Electron Acceptor

Linear and nonlinear photophysical properties of two novel dipolar compounds named as trans- dimethyl-4-[4＇-（N,N-dimethylamino）-styry1]-pyridin-2,6-dicarboxylate （Xiao-1） and trans-dimethyl-4-[4＇-（N,N-diphenylamino）-styry1]-pyridin-2,6-dicarboxylate （Xiao-2） are investigated by steady-state absorption and fluorescence spectroscopy, Z-scan and two-photon excited fluorescence measurements. Strong two-photon fluorescence emission and the pronounced positive solvatochromism are observed from two compounds. The two-photon absorption cross section of Xiao-2 is about 1.5 times larger than that of Xiao-1. One-color and two-color femtosecond pump-probe experiments are employed to investigate the excited state dynamics of two compounds. The relaxation lifetime of the intra-molecular charge transfer state is determined to be in the hundreds of picosecond domain for both the compounds in THF, and several tens of picosecond in DMSO solutions.     

一类位置不变的Pickands型估计量

当极值指标大于0时, 本文提出了一种位置不变的Pickands型估计量,证明了该估计量的强弱相合性, 给出了其渐近展式和强收敛速度,并对$k_2$的最优选择进行了讨论,最后利用自适应性方法对该估计量和其它Pickands型估计量进行随机模拟分析,比较该估计量的优越性.     

算子空间的原子性

研究了算子空间的原子性.证明了算子空间V是原子当且仅当V是正合且有限内射; V内的任意一个有限维算子子空间是原子当且仅当V是原子且V内任意有限维算子子空间足V的完全补.因此作为推论,得到了无限维箅子空间V的任意有限维子空间是原子,则V是1-Hilbertian和1-齐次.     

核爆聚变电站发电时的冲击波超压传播规律

 核爆聚变电站在发电时会产生冲击波,其超压传播规律是核爆聚变电站洞壁设计的重要基础。现有公式在描述冲击波峰值超压时存在一定的不足（如相对误差大等）。通过理论分析得到新的冲击波峰值超压公式、正压作用时间τ₊和冲击波传播系数ω,最终得到冲击波超压的传播规律。通过对比分析表明,新公式比现有公式更加适合求解核爆聚变电站发电时所产生的冲击波峰值超压。     

Synthesis of Macrocyclic Arsinous Acid Estcrs

MacrocyclicarsinousacidestersareusuallypreparedbycondensationofdichloroalkylarsinesRAsCI,Iwithdidsinthepresenceoforganicalkali].ThemethoddescribedhereinvolvesthetransformationofintermediatefromItohis(dimethylamino)alkylarsineRAs(NMe,),2andthereactionof2withdidsindryTHFtoleadtotheformationoftitlecompounds.2canreactsmoothlywithdidsintheabsenceoforganicalkalitogeneratecorrespondingmacrocyclicarsinousacidesters4anddimethylaminewhichescapesfromthereactingsystemasagasinreflux.Althoughonemoreste…     

新型氮杂大环化合物的研究2: 四吡唑类卟啉大环化合物的合成 及配位性能

报道了几种四吡唑类卟啉大环化合物的合成及其对Ru^2^+离子的配位性能。结果表明,配体环中4个sp^2杂化N原子均参与对Ru^2^+配位,形成一个近似配位平面,另有两个相同或不同的轴向配体位于平面上下,形成稳定的八面体配位结构。根据轴向配体的配位稳定性可方便地将其进行交换。     

Theoretical Study of Small Water Clusters of Sulfur Dioxide

The intermolecular clusters of sulfur dioxide with water, SO2(H2O)n (n = 2～5), are studied by using B3LYP density functional theory and MP2 ab initio methods along with the large basis sets (6-311++G(d,p) and aug-cc-pVDZ). The equilibrium geometries, intermolecular binding energies, and anharmonic frequencies of the clusters are calculated and compared with those of pure water clusters and available experiments. SO2 tends to form cyclic hydrogen-bonded complexes with two or three water molecules. In the larger clusters, however, water molecules begin to retain the structure of pure water clusters and segregate from SO2. Infrared absorption assignments for the small clusters are discussed to resolve a possible incorrect assignment in a recent spectroscopic experiment on the clusters.