含氧空位的氟掺杂二氧化锰助力稳定锌离子电池

将无机盐NH₄F加入到MnO₂的前驱体溶液中,通过高效、简单的一步水热法制备了具有氧缺陷的F掺杂α-MnO₂纳米棒(记为F-MnO₂)。氧空位和F掺杂对提高F-MnO₂的导电性、促进离子扩散、提高倍率性能起着至关重要的作用。另外,由于F掺杂,形成了F—Mn键,这可以有效地抑制放电产物中Mn³⁺的Jahn-Teller畸变,从而提高结构的稳定性。得益于这些协同效应,组装的Zn||F-MnO₂全电池在0.5 A·g^-1下,首圈放电比容量高达274 mAh·g^-1,且具有较长的循环寿命和优异的倍率性能。同时,通过循环伏安(CV)和恒流充放电(GCD)曲线证明了F-MnO₂的储能机制为H⁺和Zn²⁺的共嵌入/脱出过程。     

Magnetic properties and magnetocaloric effects in amorphous and crystalline Gd55Co35Ni10 ribbons

The magnetic properties and magnetocaloric effects of amorphous and crystalline Gd55Co35Ni10 ribbons are investigated.A main phase with a Ho 12 Co 7-type monoclinic structure(space group P21/c) and a minor phase with a Ho4Co3-type hexagonal structure(space group P63/m) are obtained for crystalline ribbon after annealing.The amorphous ribbons order ferromagnetically and undergo a second-order transition at 192 K.For crystalline Gd55Co35Ni10 ribbons,two magnetic phase transitions occur at 158 and 214 K,respectively.The peak value of-△SM under a field change of 0-5 T is 6.5 J/kg K at 192 K for amorphous Gd55Co35Ni10 ribbons.A relatively large magnetic entropy change(～5.0 J/kg K) under a field change of 0-5 T for the crystalline Gd55Co35Ni10 ribbons is obtained in the temperature interval range of 154-214 K.The large platform of magnetic entropy change and the negligible thermal/magnetic hysteresis loss mean the crystalline Gd55Co35Ni10 compound can satisfy the requirement of the Ericsson-type refrigerator working in the temperature range from 154K to 214K.     

Influence of structural defects on the optical properties of strongly coupled Au nanoshell arrays

The effects of different defects on optical properties and plasmon resonances properties of Au nanoshell arrays were investigated by using the finite-difference time-domain(FDTD) theory.It is found that the optical properties of the nanoshell arrays are strongly influenced by different defects.We show that when the hollow Au nanoshell arrays are placed in air,there is a wide photonic band gap(PBG) in the infrared region,but the band gap becomes narrower as we introduced different defects.Based on the distributions of electric field component E z and the total energy distribution of the electric and the magnetic field,we show that there exhibit dipoles field distributions for the plasmon mode at the long-wavelength edge of the band gap,but composite higher order modes are excited at the short-wavelength edge of the band gap.The plasmon resonant modes also can be controlled by introducing defects.     

Precise absolute positioning for a single-frequency user

A new strategy to realize precise absolute positioning for a single-frequency user is presented. In the presented strategy, the receiver clock and ambiguities are removed using the satelliteand epoch-differenced (SDED) algorithm. As a further development of the SDED algorithm, a regional augmentation network is used to generate the SDED atmospheric delays at the user. The weakened mathematic property due to the epoch-differenced operation is improved by adding the generated atmospheric delays and applying the robust estimation. To test the new approach, the 24-h data at 5 Continuous Operation Reference Station (CORS) stations in Shanghai is processed. The results show a more than 96% success rate, defined as the case where three directions achieve the desired positioning accuracy of 10 cm, when the observation is longer than 20 min. The 20-min static results show that the new method can reach an accuracy of 3.42, 4.76 and 9.26 cm in the North, East and Up directions, respectively. An experiment was carried out to assess the kinematic positioning. The results show that the kinematic positioning accuracy is 4.11, 5.31 and 4.05 cm in the north-south, east-west and height directions,respectively.     

伊辛模型的四分支临界面及其临界行为

本文通过等标度同普适类变换理论,使严格的重正化群递推方程得以直接应用。对伊辛模型的计算产生了四个不动点、四支临界面。对应于铁磁及反铁磁相变,其结果与已知的严格解及最好近似解一致。对于超反铁磁相变,本文提出临界曲面方程为—ch(h)=sh(2K_x)sh(2K_y)。 关键词：     

基于SESAM被动调Q的激光二极管泵浦Yb∶CaYAlO_4脉冲激光器

采用发射波长约为976 nm的半导体激光器作为泵浦源,Yb~(3+)掺杂浓度为1. 5at.%、通光长度为2 mm的Yb∶CaYAlO_4晶体作为增益介质,本文提出了一种基于半导体可饱和吸收镜(SESAM)被动调Q的激光二极管泵浦Yb∶CaYAlO_4以获取稳定脉冲输出的方案。通过合理设计谐振腔,实现了稳定的被动调Q激光脉冲输出,并分析了泵浦功率的大小对输出脉冲的重复频率、脉冲宽度、单脉冲能量以及脉冲峰值功率的影响。     

消除热库中量子位的消相干性

以二能级原子作为量子位,利用求解相互作用系统约化密度矩阵非对角元的方法,分别研究热库中量子位模型和依赖强度耦合Jaynes-Cummings模型的消相干特性.当外加驱动场消除消相干时,得到两种模型下驱动场必须满足的约束方程.?     

三倍频激光等离子体X射线转换研究

利用“星光Ⅱ”高功率激光装置三倍频激光（波长０.３５μｍ,能量５—９０Ｊ,焦斑直径约２００μｍ,脉冲宽度４００—８００ｐｓ）辐照多种材料（Ｃ,Ａｌ,Ｃｕ,Ａｕ）靶,对于不同激光功率密度,研究软Ｘ射线转换和发射能谱．结合０.３５μｍ激光辐照Ａｌ靶的质量烧蚀率和等离子体喷射速度与激光功率密度的定标关系进行数值模拟,对于激光功率在１０^１３—１０^１５Ｗ／ｃｍ²理论模拟结果与实验结果符合得很好 关键词：     

退火处理对W:Bi4Ge3O12和Bi12GeO20晶体发光性能的影响

通过提拉法制备了W:Bi4 Ge3 O12和Bi12GeO20晶体,测试了晶体的吸收光谱、光致发光谱和发光衰减时间等.W:Bi4 Ge3 O12的可见光发光强度比纯Bi4 Ge3 O12有所增强,而且N2中退火处理对W:Bi4Ge3O12发光有进一步增强作用.Bi12GeO20在N2中退火处理后在745 nm附近有发光...     

基于波长扫描的差分吸收光纤煤矿瓦斯传感系统设计

以1 330 nm波段的超辐射发光二极管为光源,利用可调谐光纤法珀滤波器为滤光元件,设计了一套光纤煤矿瓦斯传感系统.该系统采用了参考测量方法和差分吸收技术:一路参考光被引出用以消除光源波动的影响;扫描光纤法珀滤波器获得信号光波长和参考光波长,在实现差分吸收测量的同时,避免了不同滤光元件性能差异和中心波长漂移的影响.实验结果表明,所设计的光纤煤矿瓦斯传感系统的最低可探测甲烷浓度为0.15%.