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991.
Within the framework of the kinetic theory of strength, relations for estimation of durability of thermoplastic materials
under stationary and non-stationary thermomechanical impacts are obtained It is shown that durability decreases linearly with
increase in the natural (Napierian) logarithm of the mean size of microcracks formed during manufacturing of polymer products.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 3–6, July, 2007. 相似文献
992.
T. Grenet J. Delahaye M. Sabra F. Gay 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,56(3):183-197
We present a study of non-equilibrium phenomena observed
in the electrical conductance of insulating granular aluminium thin films.
An anomalous field effect and its slow relaxation are studied in some
detail. The phenomenology is very similar to the one already observed in
indium oxide. The origin of the phenomena is discussed. In granular systems,
the present experiments can naturally be interpreted along two different
lines. One relies on a slow polarisation in the dielectric surrounding the
metallic islands. The other one relies on a purely electronic mechanism: the
formation of an electron Coulomb glass in the granular metal. More selective
experiments and/or quantitative predictions about the Coulomb glass
properties are still needed to definitely distinguish between the two
scenarios. 相似文献
993.
Scott T. Knauert Jack F. Douglas Francis W. Starr 《Journal of Polymer Science.Polymer Physics》2007,45(14):1882-1897
Nanoparticles can influence the properties of polymer materials by a variety of mechanisms. With fullerene, carbon nanotube, and clay or graphene sheet nanocomposites in mind, we investigate how particle shape influences the melt shear viscosity η and the tensile strength τ, which we determine via molecular dynamics simulations. Our simulations of compact (icosahedral), tube or rod‐like, and sheet‐like model nanoparticles, all at a volume fraction ? ≈ 0.05, indicate an order of magnitude increase in the viscosity η relative to the pure melt. This finding evidently can not be explained by continuum hydrodynamics and we provide evidence that the η increase in our model nanocomposites has its origin in chain bridging between the nanoparticles. We find that this increase is the largest for the rod‐like nanoparticles and least for the sheet‐like nanoparticles. Curiously, the enhancements of η and τ exhibit opposite trends with increasing chain length N and with particle shape anisotropy. Evidently, the concept of bridging chains alone cannot account for the increase in τ and we suggest that the deformability or flexibility of the sheet nanoparticles contributes to nanocomposite strength and toughness by reducing the relative value of the Poisson ratio of the composite. The molecular dynamics simulations in the present work focus on the reference case where the modification of the melt structure associated with glass‐formation and entanglement interactions should not be an issue. Since many applications require good particle dispersion, we also focus on the case where the polymer‐particle interactions favor nanoparticle dispersion. Our simulations point to a substantial contribution of nanoparticle shape to both mechanical and processing properties of polymer nanocomposites. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1882–1897, 2007 相似文献
994.
We study two estimators of the long-range parameter of a covariance stationary linear process. We show that one of the estimators
achieve the optimal semiparametric rate of convergence, whereas the other has a rate of convergence as close as desired to
the optimal rate. Moreover, we show that the estimators are asymptotically normal with a variance, which does not depend on
any unknown parameter, smaller than others suggested in the literature. Finally, a small Monte Carlo study is included to
illustrate the finite sample relative performance of our estimators compared to other suggested semiparametric estimators.
More specifically, the Monte-Carlo experiment shows the superiority of the proposed estimators in terms of the Mean Squared
Error.
The first author research was funded by the Economic and Social Research Council (ESRC) reference number: R000238212. The
second author research was funded by the Ministry of Education, Culture, Sports and Technology of Japan, reference number:
09CE2002 and B(2)10202202. 相似文献
995.
T. Ramanathan S. Stankovich D. A. Dikin H. Liu H. Shen S. T. Nguyen L. C. Brinson 《Journal of Polymer Science.Polymer Physics》2007,45(15):2097-2112
Mechanical, thermal, and electrical properties of graphite/PMMA composites have been evaluated as functions of particle size and dispersion of the graphitic nanofiller components via the use of three different graphitic nanofillers: “as received graphite” (ARG), “expanded graphite,” (EG) and “graphite nanoplatelets” (GNPs) EG, a graphitic materials with much lower density than ARG, was prepared from ARG flakes via an acid intercalation and thermal expansion. Subsequent sonication of EG in a liquid yielded GNPs as thin stacks of graphitic platelets with thicknesses of ~10 nm. Solution‐based processing was used to prepare PMMA composites with these three fillers. Dynamic mechanical analysis, thermal analysis, and electrical impedance measurements were carried out on the resulting composites, demonstrating that reduced particle size, high surface area, and increased surface roughness can significantly alter the graphite/polymer interface and enhance the mechanical, thermal, and electrical properties of the polymer matrix. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2097–2112, 2007 相似文献
996.
997.
M. T. Viciosa J. Quiles Hoyo M. Dionísio J. L. Gómez Ribelles 《Journal of Thermal Analysis and Calorimetry》2007,90(2):407-414
Temperature modulated differential scanning calorimetry (TMDSC) is used to study the kinetics of the free radical isothermal polymerization of triethyleneglycol dimethacrylate (TEGDMA). Azo-bis-isobutironitrile was used as initiator. The polymerization’s temperature is lower than the final glass transition temperature of the polymer network. The measurement of the average heat flow released and the heat capacity during the reaction allows identifying the different stages of the reaction. The presence of double peaks in the heat flow is ascribed to the autoacceleration. The influence of temperature, measuring conditions and oxygen are described. Vitrification is detected by the drop in heat capacity. It occurs at increasing conversion rates for increasing temperatures. After vitrification, the diffusion-controlled reaction continues. 相似文献
998.
A. V. Porfir’eva G. A. Evtyugin E. Yu. Podshivalina L. I. Anchikova G. K. Budnikov 《Journal of Analytical Chemistry》2007,62(12):1180-1186
A new technique is proposed for detecting interactions between DNA and DNA autoimmune antibodies using a potentiometric sensor based on a glassy-carbon electrode modified with polyaniline and native DNA from chicken erythrocytes. It is shown that the DNA-antibody interaction changes the rate of polyaniline doping in transferring the DNA sensor from an alkaline (pH 7.5) solution, which is optimum for the immunochemical reaction, to an acidic (pH 3.0) solution. The dynamics of the variation of the DNA sensor potential depends on the titer of antibodies and their origin. The dependence of the DNA sensor signal on the dilution of the blood sera from systemic lupus erythematosus and autoimmune thyroiditis patients shows that DNA antibodies can be diagnosed by the characteristic maximum in the dilution curve found in the range of serum dilutions from 1: 20 to 1: 50. 相似文献
999.
D. V. Treschev 《Proceedings of the Steklov Institute of Mathematics》2007,259(1):196-235
We propose a method for constructing noncommutative analogs of objects from classical calculus, differential geometry, topology,
dynamical systems, etc. The standard (commutative) objects can be obtained from noncommutative ones by natural projections
(a set of canonical homomorphisms). The approach is ideologically close to the noncommutative geometry of A. Connes but differs
from it in technical details. 相似文献
1000.
Martin I. Karakhanyan 《Journal of Contemporary Mathematical Analysis (Armenian Academy of Sciences)》2007,42(3):146-150
The paper proves some general facts on commutators that refer to Fuglede-Putnam classical theorem in the spectral theory of not necessarily selfadjoint operators. 相似文献