全文获取类型
收费全文 | 363514篇 |
免费 | 3523篇 |
国内免费 | 1162篇 |
专业分类
化学 | 186437篇 |
晶体学 | 5998篇 |
力学 | 16888篇 |
综合类 | 4篇 |
数学 | 40502篇 |
物理学 | 118370篇 |
出版年
2020年 | 2771篇 |
2019年 | 3071篇 |
2018年 | 4855篇 |
2017年 | 4937篇 |
2016年 | 6362篇 |
2015年 | 3914篇 |
2014年 | 6088篇 |
2013年 | 15263篇 |
2012年 | 12177篇 |
2011年 | 14516篇 |
2010年 | 10290篇 |
2009年 | 10329篇 |
2008年 | 13344篇 |
2007年 | 13094篇 |
2006年 | 12586篇 |
2005年 | 13925篇 |
2004年 | 12854篇 |
2003年 | 10686篇 |
2002年 | 9332篇 |
2001年 | 11595篇 |
2000年 | 8647篇 |
1999年 | 6742篇 |
1998年 | 5257篇 |
1997年 | 5272篇 |
1996年 | 4990篇 |
1995年 | 4576篇 |
1994年 | 4531篇 |
1993年 | 4446篇 |
1992年 | 5034篇 |
1991年 | 5231篇 |
1990年 | 4876篇 |
1989年 | 4819篇 |
1988年 | 4808篇 |
1987年 | 4712篇 |
1986年 | 4413篇 |
1985年 | 5817篇 |
1984年 | 6012篇 |
1983年 | 4805篇 |
1982年 | 4974篇 |
1981年 | 4785篇 |
1980年 | 4671篇 |
1979年 | 5023篇 |
1978年 | 5212篇 |
1977年 | 5082篇 |
1976年 | 5127篇 |
1975年 | 4705篇 |
1974年 | 4698篇 |
1973年 | 4790篇 |
1972年 | 3281篇 |
1971年 | 2701篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
Z.G. Xiao R.J. HuH.Y. Wu G.M. JinZ.Y. Li L.M. DuanH.W. Wang B.G. ZhangS.F. Wang Z.Y. WeiH.S. Xu Y.T. ZhuS.L. Li F. FuX.H. Yuan Z.Q. Feng 《Physics letters. [Part B]》2006
The inclusive reduced velocity correlation functions of the intermediate mass fragments were measured in the reactions of 36Ar + 112,124Sn at 35 MeV/u. The anti-correlation is observed to be stronger in 36Ar + 124Sn system than that in 36Ar + 112Sn. The difference of the correlation functions between the two reactions is mainly contributed by the particle pairs with high momenta. A three body Coulomb repulsive trajectory model is employed to calculate the emission time scale of the IMFs for the two systems. The time scale is 150 fm/c in 36Ar + 112Sn and 120 fm/c in the 36Ar + 124Sn, respectively. 相似文献
992.
Methods to synthesize magnetic Fe3O4 nanoparticles and to modify the surface of particles are presented in the present investigation. Fe3O4 magnetic nanoparticles were prepared by the co-precipitation of Fe3+ and Fe2+, NH3·H2O was used as the precipitating agent to adjust the pH value, and the aging of Fe3O4 magnetic nanoparticles was accelerated by microwave (MW) irradiation. The obtained Fe3O4 magnetic nanoparticles were characterized by Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), X-ray powder diffraction (XRD) and vibrating sample magnetometer (VSM). The average size of Fe3O4 crystallites was found to be around 8–9 nm. Thereafter, the surface of Fe3O4 magnetic nanoparticles was modified by stearic acid. The resultant sample was characterized by FT-IR, scanning electron microscopy (SEM), XRD, lipophilic degree (LD) and sedimentation test. The FT-IR results indicated that a covalent bond was formed by chemical reaction between the hydroxyl groups on the surface of Fe3O4 nanoparticles and carboxyl groups of stearic acid, which changed the polarity of Fe3O4 nanoparticles. The dispersion of Fe3O4 in organic solvent was greatly improved. Effects of reaction time, reaction temperature and concentration of stearic acid on particle surface modification were investigated. In addition, Fe3O4/polystyrene (PS) nanocomposite was synthesized by adding surface modified Fe3O4 magnetic nanoparticles into styrene monomer, followed by the radical polymerization. The obtained nanocomposite was tested by thermogravimetry (TG), differential scanning calorimetry (DSC) and XRD. Results revealed that the thermal stability of PS was not significantly changed after adding Fe3O4 nanoparticles. The Fe3O4 magnetic fluid was characterized using UV–vis spectrophotometer, Gouy magnetic balance and laser particle-size analyzer. The testing results showed that the magnetic fluid had excellent stability, and had susceptibility of 4.46×10−8 and saturated magnetization of 6.56 emu/g. In addition, the mean size d (0.99) of magnetic Fe3O4 nanoparticles in the fluid was 36.19 nm. 相似文献
993.
High-performance liquid chromatography was used to determine cyclosporin A (CsA) concentrations in the serum of kidney transplant patients by rapid-flow fractionation (RFF) followed by silica gel normal-phase high-performance liquid chromatography (HPLC). The extraction of CsA from serum was achieved by RFF using a short diatomaceous earth column eluted with diethyl ether-n-hexane (50:50, v/v). The recovery was more than 80% at concentrations of 50-150 micrograms/l. The concentration of this compound was determined by HPLC using a conventional silica gel column with 3.3 M ammonia solution-ethanol-n-hexane (0.31:10.69:89, v/v) as eluent. Concentration calibration was made on the basis of the peak-height ratio of CsA to CsD as the internal standard. The coefficient of variation of this assay was less than 6.5% and the results were used for the therapeutic drug monitoring of CsA administered to kidney transplant patients. Measurements of the CsA concentrations in 160 serum specimens were also made by conventional radioimmunoassay (RIA) using commercial kits. The data obtained by RIA were on average 2.5 times those obtained by HPLC. Higher values in RIA were observed characteristically with patients with severe disfunction resulting from CsA hepatotoxicity. From the results, it appeared that HPLC rather than RIA provides more precise and reliable values for the concentration of this drug. 相似文献
994.
Correlation between the particles from the proton-nucleus interactions in emulsion at 70 GeV/c is presented through the study of the rapidity gap analysis and compared with the two-particle rapidity correlations. It is observed that the strength of correlation decreases as the size of cluster increases. Asymmetry between the forward and backward components were also studied.Authors are thankful to Prof. K. D. Tolstov, JINR, Dubna, USSR for sending the exposed emulsion plates. Thanks are also due to UGC for financial assistance. We sincerely acknowledge the encouragement from Prof. T. Roy. 相似文献
995.
996.
997.
This paper presents results of studies on dc electrical conductivity and transference number measurements on potassium bromate
(KBrO3) complexed polyvinyl chloride (PVC) films prepared by solution cast technique. Temperature dependence of dc electrical conductivity
and transference number data indicated the dominance of ion type charge transport in these specimens. The magnitude of conductivity
increased with increase in concentration of the salt and temperature. Using this (PVC + KBrO3) electrolyte, solid-state electrochemical cells were fabricated, and their discharge profiles were studied under a constant
load of 100 kΩ. Several cell profiles such as open circuit voltage, short circuit current, power density, and energy density
associated with these cells were evaluated and were reported. The features of complexation of the electrolytes were studied
by X-ray diffraction and Fourier transform infrared spectroscopy.
Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006 相似文献
998.
A. G. Zhdanov A. K. Zvezdin A. P. Pyatakov T. B. Kosykh D. Viehland 《Physics of the Solid State》2006,48(1):88-95
The specific features of the “incommensurate-commensurate” phase transitions induced by a magnetic field in multiferroics
(materials with coexisting magnetic and electric ordering) are considered. These materials are ferroelectromagnets, for example,
bismuth ferrite BiFeO3 and BiFeO3-based compounds, which have spatially modulated spin structures. It is shown that the interaction between the electric and
magnetic subsystems of the multiferroic material can lead to an electric-field-induced shift of the critical magnetic field
corresponding to the transition from a spatially modulated state to a homogeneous antiferromagnetic state. According to the
theoretical estimates obtained for material parameters characteristic of the bismuth ferrite, this shift is of the order of
0.5 T in an electric field of 50 kV/cm. The phase diagrams are constructed in the “electric field-magnetic field” coordinates.
The results of calculations performed in the harmonic incommensurate structure approximation are compared with the exact soliton
solution. 相似文献
999.
A. P. Suponina L. G. Kolzunova M. A. Karpenko 《Russian Journal of Applied Chemistry》2006,79(6):924-929
The effect of coatings based on a copolymer of acrylamide, N,N′-methylenebisaxcrylamide and formaldehyde deposited by electrochemical polymerization on the corrosion resistance of 08Kh18N10T stainless steel (field studies at sea) and low-carbon steel (laboratory experiments) was examined. 相似文献
1000.
T. Yu. Gumerov A. F. Dobrynina R. A. Yusupov V. P. Barabanov 《Russian Journal of Applied Chemistry》2006,79(12):1935-1939
The behavior of real disperse systems with organic impurities was examined under conditions of destabilization by inorganic coagulants. A number of physicochemical methods of analysis and a simulation method were used to identify the character and type of the complexes formed and to calculate their stability constants. 相似文献