Protonation constant of salicylidene (N-benzoyl)glycyl hydrazone and its coordination behaviour towards some bivalent metal ions

Protonation constant of an unsymmetrical Schiff base, salicylidene(N-benzoyl)glycyl hydrazone (SalBzGH), and formation constants of its complexes have been determined potentiometrically at different temperatures in aqueous dioxane medium. Complexes of SalBzGH with VO(IV), Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) have been prepared. Elemental analyses, pH-metric, molar conductance, magnetic susceptibility, electronic, IR, ESR, XRD (powder) and NMR studies have been carried out to study the coordination behaviour of SalBzGH toward these metal ions. pH-metric and 1H NMR studies show the presence of two dissociable protons in the ligand. IR and NMR spectra suggest the tridentate nature of the ligand, coordinating as a uninegative species in the Mn(II) complex and as a dinegative species in all the other complexes. Presence of two different conformers of the ligand at room temperature and stabilization of a single conformer upon complex formation have been established from¹H NMR spectra of the metal-free ligand, Zn(II) and Hg(II) complexes recorded at 296 K. Electronic and ESR spectra indicate highly distorted tetragonal geometry for VO(IV) and Cu(II) complexes. XRD powder patterns of the Zn(II) complexes are indexed for an orthorhombic crystal system.     

Quenching of fluorescence from Na(32P) and K(42P) atoms following photodissociation of NaCl and KCl at 193 nm

 Quenching of fluorescence from Na(3² P) and K(4² P) atoms by various collision partners was studied at 973 and 1273K. Excited alkali atoms were produced photolytically by excimer laser light at 193nm. For each collision pair, the appropriate relative velocity was computed and used to evaluate the quenching cross-section from the measured rate constants. Cross sections for CO₂, O₂ and N₂ are large (10–60Ų) while for Ar, the values are <1 Ų. The results are compared with those of previous investigations as a function of relative velocity. Finally, implications for combustion diagnostics are briefly discussed. Received: 29 March 1996     

A method for wave decomposition in computations for nonlinear dynamical three-dimensional towing systems

We propose a new method for computing multimode wave interactions in towing systems; our method is based on wave splitting of the equations of a model in such a way that each computational step requires computation for only one mode. The efficiency of the method is demonstrated by analysis of a concrete towing system with a turning towboat. Translated fromDinamicheskic Sistermy. Vol. 12, pp. 55–64, 1993.     

Criteria for controllability and observability in complex domain models of stationary systems

We propose criteria for controllability and observability of stationary systems specified by complex domain models. Conclusions concerning controllability and observability are made on the basis of coefficients in the corresponding transfer functions. Translated fromDinamicheskie Sistemy, Vol. 12, pp. 120–126, 1993.     

Experiments on two-step heating of a dense plasma in the GOL-3 facility

This paper presents the results of experiments on two-stage heating of a dense plasma by a relativistic electron beam in the GOL-3 facility. A dense plasma with a length of about a meter and a hydrogen density up to 10¹⁷ cm⁻³ was created in the main plasma, whose density was 10¹⁵ cm⁻³. In the process of interacting with the plasma, the electron beam (1 MeV, 40 kA, 4 μs) imparts its energy to the electrons of the main plasma through collective effects. The heated electrons, as they disperse along the magnetic field lines, in turn reach the region of dense plasma and impart their energy to it by pairwise collisions. Estimates based on experimental data are given for the parameters of the flux of hot plasma electrons, the energy released in the dense plasma, and the energy balance of the beam-plasma system. The paper discusses the dynamics of the plasma, which is inhomogeneous in density and temperature, including the appearance of pressure waves. Zh. éksp. Teor. Fiz. 113, 897–917 (March 1998)     

Choosing an adequate mathematical model in problems with high pulsed energy deposition

The problems of choosing the optimal mathematical model for a prescribed range of parameters of a pulsed action are discussed. A preliminary analysis performed by similarity and dimensional-analysis methods using interpolation equations of state of the matter shows that the complete system of equations of gasdynamics can be simplified by dropping individual terms which are not important in a given parameter range. The results of an analysis are presented in the form of nomograms, which also make it possible to identify the class of fast and energy-intensive gasdynamic processes more accurately than at an intuitive level. Zh. Tekh. Fiz. 68, 44–47 (May 1998)     

Chaos in duopoly pricing

The dynamics of two competing firms in a market is studied in terms of Cournot's duopoly theory. Assuming iso-elastic demand and constant unit production costs the iterative mapping

for the outputs of the two firms ensues. The two constants are the unit production costs. The fixed point, the Cournot equilibrium, has earlier been assumed to be the only interesting feature of this model. It is, however, shown that the model can produce persistent motion, periodic or chaotic.