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201.
The impedance spectra of Pb5Ge3O11 single crystals are measured in the frequency range from 5 Hz to 13 MHz at temperatures of 600 to 800 K in dry air and in
a dry or wet nitrogen gas. It is found that the temperature and the gas composition significantly affect the electrical properties
of the compound. The data obtained are used to discuss the origin of crystal lattice defects and their influence on charge
transfer. It is concluded that the conduction is mixed in character (p-type electronic and ionic due to oxygen ions). The proton conduction is shown experimentally to be feasible. The possible
mechanisms of proton transport in Pb5Ge3O11 are discussed. 相似文献
202.
203.
T. Rietmann S. Sohn M. Schröder D. Lipinsky H.F. Arlinghaus 《Applied Surface Science》2006,252(19):6640-6643
In order to improve quantification of high mass ions, the influence of cluster composition on detection efficiencies has been studied using a TOF-SIMS IV with the extended capability of postaccelerating ions up to 20 keV. In this experimental study, we focus on the comparison of detection efficiencies for three types of negatively charged secondary cluster ions: gold-alkanethiolate-clusters (AuxMy), gold-sulfur-clusters (AuxSy) and gold-clusters (Aux). The clusters were sputtered from self-assembled monolayers of hexadecanethiols on gold substrates using 10 keV Ar+ primary ions. The detection efficiencies were derived on the basis of a function for the secondary electron yield and a fourth-order approximated Poisson probability distribution for electron propagation and amplification within the microchannel plate.In addition to the well-known dependence of detection efficiencies on ion mass and energy, which has already been studied for positively charged ions, we were able to show a similar behaviour for the investigated negatively charged secondary ions. We have observed major variations among the three types of clusters at similar mass and energy as predicted in a theoretical approach. The observed differences are due to the different composition of the investigated clusters which has a major influence on the kinetic ion induced electron emission within the microchannel plate. For the first time it was possible to experimentally verify these predictions for detection efficiencies. 相似文献
204.
I. A. Begishev R. A. Ganeev V. V. Gorbushin A. A. Gulamov Sh. R. Kamalov T. Usmanov 《Journal of Applied Spectroscopy》1989,51(5):1218-1221
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 51, No. 5, pp. 867–870, November, 1989. 相似文献
205.
206.
In this paper, the effect of cubic zinc metaborate Zn4O(BO2)6 on the sintering of MnZn-ferrites for medium frequency power applications is investigated. Zinc metaborate is synthesized in the laboratory using zinc oxide and boric acid as metal precursors. As observed, when zinc metaborate is added to the MnZn-ferrites at an optimum amount of 0.02 wt%, it significantly enhances densification and therefore allows, for a given density, reduction of the firing temperature by almost 200 °C. MnZn-ferrites exhibiting power losses of 70 mW/cm3 (measured at a frequency of 400 kHz, magnetic field 50 mT and temperature of 90 °C) are synthesized from conventionally milled powders with average particle diameter 0.6 μm, compacted and fired at 1100 °C. Identical experiments conducted under the same conditions on specimens without zinc metaborate additions revealed power losses greater than 300 mW/cm3, because of insufficient densification. 相似文献
207.
The partition coefficient of strontium upon its extraction from the aqueous solutions of picric acid into chloroform containing DC-18-crown-6, B-15-crown-5 after their exposition to gamma radiation has been studied. A significant decrease of the partition coefficient in the studied range of doses 10–70 kGy was observed. This effect can be attributed to the radiolytic products of chloroform. The radiation destruction as well as dehydrogenation of crown ethers were not observed. 相似文献
208.
T. C. Devore 《Journal of Molecular Structure》1987,162(3-4):287-304
Fourier transform infrared spectroscopy has been used to investigate the IR spectra of the XNCO (X = Cl, Br, I, CN), the XSCN (X = Cl, Br, I) and the NCNCS vapor molecules from 4800 to 400 cm−1. Vibrational frequencies have been determined for each normal mode of vibration in each molecule in this region. 相似文献
209.
H. Sakuma T. Taniyama K. Ishii Y. Kitamoto Y. Yamazaki 《Journal of magnetism and magnetic materials》2006,300(2):284-292
The order parameter S of Fe–Pt nanoparticles is estimated from X-ray diffraction (XRD) patterns. The total intensity of a diffraction peak is obtained by Rietveld analysis as well as simply integrating the intensity. The Rietveld analysis is found to provide a plausible value of S even for a sample showing an XRD pattern with broad and overlapped peaks. Another order parameter Q, which is obtained from Mössbauer spectra, is introduced, and it is confirmed that Q is equivalent to the probability of Fe atoms being in the L10-type atomic arrangement. The coercivity of Fe–Pt nanoparticles is directly proportional to Q, while it vanishes at S=0.4, indicating that the magnetic property of Fe–Pt nanoparticles has a closer relationship to Q than S. 相似文献
210.
M. Köhl A. Öttl S. Ritter T. Donner T. Bourdel T. Esslinger 《Applied physics. B, Lasers and optics》2007,86(3):391-393
We report an experimental investigation of two-particle correlations between neutral atoms in a Hanbury Brown and Twiss experiment.
Both an atom laser beam and a pseudo-thermal atomic beam are extracted from a Bose–Einstein condensate and the atom flux is
measured with a single atom counter. We determine the conditional and the unconditional detection probabilities for the atoms
in the beam and find good agreement with the theoretical predictions.
PACS 03.75.Pp; 05.30.Jp; 07.77.Gx; 42.50.Pq 相似文献