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991.
M. G. Voronkov E. A. Grebneva O. M. Trofimova A. I. Albanov N. F. Chernov N. N. Chipanina 《Russian Journal of General Chemistry》2006,76(12):1851-1853
Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N → Si) F2Si(OCH2CH2)2NR (R = H, Me) containing donor-acceptor bond N → Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by 1H, 13C, 15N, 19F, 29Si NMR and IR spectroscopy. 相似文献
992.
Summary In this note we use Theorem 2.4 in<span lang=EN-US style='font-size:10.0pt;mso-ansi-language:EN-US'>[1]to give a very short
proof of a recent result due to M. Bognár (Theorem A in [3]). We also prove that Bognár's result is in fact equivalent to
the classical Hahn-Mazurkiewicz Theorem. Finally we give generalizations in the non-compact setting. 相似文献
993.
This paper proposes a new method that extends the efficient global optimization to address stochastic black-box systems. The
method is based on a kriging meta-model that provides a global prediction of the objective values and a measure of prediction
uncertainty at every point. The criterion for the infill sample selection is an augmented expected improvement function with
desirable properties for stochastic responses. The method is empirically compared with the revised simplex search, the simultaneous
perturbation stochastic approximation, and the DIRECT methods using six test problems from the literature. An application
case study on an inventory system is also documented. The results suggest that the proposed method has excellent consistency
and efficiency in finding global optimal solutions, and is particularly useful for expensive systems. 相似文献
994.
L. T. Ashchepkov D. V. Davydov 《Computational Mathematics and Mathematical Physics》2006,46(11):1910-1917
Noncooperative games of a finite number of persons with interval-valued payoff functions are considered. The concept of an equilibrium situation is introduced. A reduction of such games to deterministic noncooperative games is proposed. Properties of the reduced games are discussed. Interval antagonistic and bimatrix games are examined, and illustrative examples are considered. 相似文献
995.
The effect of gradients in hardness, structure and composition in the surface layers on magnetic Barkhausen noise (MBN) was investigated in two widely used low alloy steels. One material was case hardened by induction hardening. The other was case carburised. Similar hardness profiles were produced by the two treatments. It was found that the variation in structure and hardness through the case in the induction-hardened steel had a minor effect on the MBN profile. In contrast, the inhomogeneity in the case-carburised material showed up clearly. This took the form of a broadened or two-peak MBN profile. When the surface layer containing the case was removed by etching, the broadened profile was replaced by a profile with a single peak. It is concluded that the shape and position of the MBN profile is significantly affected when a gradient in microstructure is induced by a gradient in carbon content. On the other hand, a gradient in microstructure induced by heat treatment with a constant carbon level has much less affect on the MBN profile for the induction-hardened steel. 相似文献
996.
997.
John T. Herron 《国际化学动力学杂志》1987,19(2):129-142
The gas phase chemical kinetics of SF4, SF5, and S2F10 are reviewed with particular emphasis on relevance to the general problem of the dielectric breakdown of SF6. Specific reaction systems treated are SF4 + F2, SF5 + SF5, and the pyrolysis of S2F10. Computer modeling calculations were carried out to arrive at the best estimates of rate parameters. Based on the results of these calculations, sets of recommended rate parameters are provided. The major discrepancies and problems in establishing the kinetic data base are described. Thermochemical consequences of different model calculations are given. 相似文献
998.
999.
G. McCartor 《Zeitschrift fur Physik C Particles and Fields》1987,36(2):329-336
A method of performing perturbation calculations for infrared divergent problems is formulated for problems in quantum field theory and is illustrated by applying it to the Schwinger Model and to QCD in 1+1 dimensions. 相似文献
1000.
A high-performance liquid chromatographic procedure was developed for the quantitation of homoharringtonine in plasma. Harringtonine was used as an internal standard, and 1 ml of sample was required. The single-step extraction with dichloromethane resulted in almost 100% recovery for homoharringtonine and harringtonine. Analysis was performed on a reversed-phase CN column with amperometric detection. Chromatography was completed in 12 min. At an oxidation potential of +1.0 V, the detection limit was 1 ng/ml at a signal-to-noise ratio of 2. The mean analytical recovery for homoharringtonine was 99.5%. The within-run precision and between-run precision were both less than 11%. The method is equally applicable for plasma or serum, and it has been demonstrated to be applicable for study of the pharmacokinetics of homoharringtonine in patients suffering from acute non-lymphocytic leukaemia. 相似文献