Bufadienolides and a new lignan from the bulbs of Urginea maritima

Thirty three compounds were obtained from the bulbs of Urginea maritima (Liliaceae). The compounds were identified by means of fast atom bombardment mass spectrometry (FAB-MS), nuclear magnetic resonance (1H-NMR), (13C-NMR), nuclear overhauser effects (NOE) and two dimensional (2D) NMR. Ten of them were new natural compounds. Nine were bufadienolides and only one was lignan in these compounds.     

Temperature-induced crystallization and compactibility of spray dried composite particles composed of amorphous lactose and various types of water-soluble polymer

The purpose of this study was to investigate the temperature-induced crystallization and the compactibility of the composite particles containing amorphous lactose and various types of polymers. The composite particles were prepared by spray-drying an aqueous solution of lactose and various types of gel forming water-soluble polymers at various formulating ratios. The stabilizing effect of hydroxypropylcellulose (HPC) and polyvinyl pyrrolidone (PVP) on amorphous lactose in the composite particles was smaller than that of sodium alginate in comparing at the same formulating ratios. The difference in the stability of amorphous lactose in the composite particles was attributed to the difference in the glass transition temperature (Tg) of the composite particles caused by the polymers formulated. The tensile strength of compacted spray-dried composite particles containing the polymers was higher than commercial lactose for direct tabletting (DCL21). The tensile strength of the composite particles was increased with an increase in water content in the particles. The difference in compactibility of the composite particles containing the different amount of polymer and water could be explained by the difference in Tg of the particles.     

Influence of Ionic Surfactants on Tetrabromophenylfluorone Ionic Associates

Stability constants of ionic associates of a hydroxyxanthene dye, tetrabromophenylfluorone, with a series of organic cations were determined spectrophotometrically. The possibility of quantitative determination of anionic surfactants (alkyl sulfates) in an aqueous solution in the form of a dye anion associate with tetrabutylammonium cation was considered.     

Modification of Synthetic Latexes with Colloidal Silver

Butadiene-styrene and acrylate latexes were studied as matrices for preparing colloidal silver. Colloidal-chemical and strength properties of the modified latexes and Primal E1950 latex films were studied. The heat resistance of these materials was determined.     

ESR study of products of transformation of 3,6-tert-butylpyrocatechol on alumina, zinca, silica, and titania

The formation of semiquinone and phenoxazyl radicals and metallocomplexes with semiquinone ligands was observed by ESR during the interaction of di-tert-butylpyrocatechol with Al₂O₃, ZnO, SiO₂, and TiO₂. In the case of different modifications of SiO₂, admixtures of TiO₂ exhibit a higher reactivity in complex formation with the organic substrate. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1975–1978, October, 1998.     

Workshop on Sample Controlled Thermal Analysis

Journal of Thermal Analysis and Calorimetry -