Synthesis and application of mono-6-ammonium-6-deoxy-beta-cyclodextrin chloride as chiral selector for capillary electrophoresis

A facile synthetic approach for mono-6-amino-6-deoxy-beta-cyclodextrin (beta-CD-NH2) was proposed. Its hydroxy chloride salt, mono-6-ammonium-6-deoxy-beta-cyclodextrin chloride (beta-CD-NH3Cl) was further prepared and used for the enantioseparation of various anionic and ampholytic analytes by capillary electrophoresis (CE). The effect of background electrolyte (BGE) pH and selector concentration on the enantioseparation was studied. Results showed that beta-CD-NH3Cl displayed powerful chiral resolution ability towards anionic analytes. In addition, baseline separation of a standard mixture consisting of eight acids was achieved within 35 min.     

One‐Electron Oxidation of [M(PtBu3)2] (M=Pd,Pt): Isolation of Monomeric [Pd(PtBu3)2]+ and Redox‐Promoted C−H Bond Cyclometalation

Oxidation of zero‐valent phosphine complexes [M(P^tBu₃)₂] (M=Pd, Pt) has been investigated in 1,2‐difluorobenzene solution using cyclic voltammetry and subsequently using the ferrocenium cation as a chemical redox agent. In the case of palladium, a mononuclear paramagnetic Pd^I derivative was readily isolated from solution and fully characterized (EPR, X‐ray crystallography). While in situ electrochemical measurements are consistent with initial one‐electron oxidation, the heavier congener undergoes C?H bond cyclometalation and ultimately affords the 14 valence‐electron Pt^II complex [Pt(κ²_PC‐P^tBu₂CMe₂CH₂)(P^tBu₃)]⁺ with concomitant formation of [Pt(P^tBu₃)₂H]⁺.     

Mass-Related Dynamical Barriers in Triatomic Reactions

A methodology is given to determine the effect of different mass distributions for triatomic reactions using the geometry of shape space. Atomic masses are incorporated into the non-Euclidean shape space metric after the separation of rotations. Using the equations of motion in this non-Euclidean shape space, an averaged field of velocity-dependent fictitious forces is determined. This force field, as opposed to the force arising from the potential, dominates branching ratios of isomerization dynamics of a triatomic molecule. This methodology may be useful for qualitative prediction of branching ratios in general triatomic reactions.     

Maps preserving the nilpotency of products of operators

Let B(X) be the algebra of all bounded linear operators on the Banach space X, and let N(X) be the set of nilpotent operators in B(X). Suppose ?:B(X)→B(X) is a surjective map such that A,B∈B(X) satisfy AB∈N(X) if and only if ?(A)?(B)∈N(X). If X is infinite dimensional, then there exists a map f:B(X)→C?{0} such that one of the following holds:

(a)

There is a bijective bounded linear or conjugate-linear operator S:X→X such that ? has the form A?S[f(A)A]S^-1.

(b)

The space X is reflexive, and there exists a bijective bounded linear or conjugate-linear operator S : X′ → X such that ? has the form A ? S[f(A)A′]S⁻¹.

If X has dimension n with 3 ? n < ∞, and B(X) is identified with the algebra M_n of n × n complex matrices, then there exist a map f:M_n→C?{0}, a field automorphism ξ:C→C, and an invertible S ∈ M_n such that ? has one of the following forms:

     

On the study of the effects of sea views, greenery views and personal characteristics on noise annoyance perception at homes

Noise annoyance has caused significant adverse impacts on human beings and numerous efforts have been spent on mitigating annoyance problems. Natural greenery has been shown to be able to moderate annoyance problems at home but this conclusion was drawn without properly controlling the potential confounding factors. Furthermore, few have explored the moderation effect of a sea view. Accordingly, this study formulated a multivariate model to examine the impacts of natural views as well as personal characteristics on annoyance perception. A housing estate was selected in Hong Kong as the survey site for which some of the residents were exposed to greenery views, sea views, or both from their homes. Eight hundred and sixty-one responses were collected via questionnaire surveys and analyzed using an ordered logit model. The results suggest that both a greenery view and a sea view can moderate annoyance responses. Several individual's personal characteristics are found to affect individuals' annoyance perception. The duration of time spent daily at home is shown to have an influence on the moderation impact exerted by a greenery view, while the age of an individual is shown to have an influence on noise moderation effect exerted by a sea view.     

Perception of urban park soundscape

A number of studies have been initiated to explore how to improve the soundscape quality in urban parks. However, good soundscape quality in parks cannot be provided without a thorough understanding of the complex relationships among sound, environment, and individuals. As acoustic comfort is considered to be an important outcome of soundscape quality, this study investigates the relative impacts of the factors influencing acoustic comfort evaluation by formulating a multivariate ordered logit model. This study also explores the inter-relationships among acoustic comfort evaluation, acceptability of the environment, and preference to stay in a park using a path model. A total of 595 valid responses were obtained from interview surveys administered in four parks in Hong Kong while objective sound measurements were carried out at the survey spots concurrently. The findings unveil that acoustic comfort evaluation, besides visual comfort evaluation of landscape, also plays an important role on users' acceptability of the urban park environment. Compared with all the studied acoustic related factors, acoustic comfort evaluation serves as a better proxy for park users' preference to stay in urban parks. Hearing the breeze will significantly increase the likelihood of individuals in giving high acoustic comfort evaluation. Conversely, hearing the sounds from heavy vehicles or sounds from bikes will significantly reduce the likelihood in giving a high acoustic evaluation.     

以优化方法求解布料无摩擦接触变形问题

利用作者所提出的布料质点模型,用罚函数法解除布料和其它物体之间的接触约束,把接触约束条件下的极值问题转化为无约束极值问题,用F-R共轭梯度法求解,并用三次插值方法进行一维搜索.计算了有缝摺和裁剪开口的布料与球形物体的接触变形问题,得到的结果符合人们的日常实际观察.