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排序方式: 共有241条查询结果,搜索用时 93 毫秒
51.
Arne Johansen Randi Midtkandal Heidi Roggen Carl Henrik Grbitz 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(4):o198-o200
The valine side chains in the crystal structure of the title compound [systematic name: 2‐(2‐ammonio‐3‐methylbutanamido)‐3‐hydroxypropanoate trihydrate], C8H16N2O4·3H2O, stack along an a axis of 4.77 Å to form hydrophobic columns surrounded by remarkable water/hydroxyl shells. The peptide main chains are connected by hydrogen bonds in two‐dimensional layers. The peptide molecules in each layer are related only by translation, and generate a very rare pattern. This is rendered possible through the formation of the shortest Cα—H·O(carboxylate) interaction ever recorded. 相似文献
52.
The separation and shock wave formation on the aft-body of a hypersonic adiabatic circular cylinder were studied numerically using the open source software OpenFOAM. The simulations of laminar flow were performed over a range of Reynolds numbers (\(8\times 10^3 < Re < 8\times 10^4\)) at a free-stream Mach number of 5.9. Off-body viscous forces were isolated by controlling the wall boundary condition. It was observed that the off-body viscous forces play a dominant role compared to the boundary layer in displacement of the interaction onset in response to a change in Reynolds number. A modified free-interaction equation and correlation parameter has been presented which accounts for wall curvature effects on the interaction. The free-interaction equation was manipulated to isolate the contribution of the viscous–inviscid interaction to the overall pressure rise and shock formation. Using these equations coupled with high-quality simulation data, the underlying mechanisms resulting in Reynolds number dependence of the lip-shock formation were investigated. A constant value for the interaction parameter representing the part of the pressure rise due to viscous–inviscid interaction has been observed at separation over a wide range of Reynolds numbers. The effect of curvature has been shown to be the primary contributor to the Reynolds number dependence of the free-interaction mechanism at separation. The observations in this work have been discussed here to create a thorough analysis of the Reynolds number-dependent nature of the lip-shock. 相似文献
53.
This paper presents a novel method used to manufacture stacks of multiple matching layers for 15 MHz piezoelectric ultrasonic transducers, using fabrication technology derived from the MEMS industry. The acoustic matching layers were made on a silicon wafer substrate using micromachining techniques, i.e., lithography and etch, to design silicon and polymer layers with the desired acoustic properties. Two matching layer configurations were tested: a double layer structure consisting of a silicon–polymer composite and polymer and a triple layer structure consisting of silicon, composite, and polymer. The composite is a biphase material of silicon and polymer in 2-2 connectivity. The matching layers were manufactured by anisotropic wet etch of a (1 1 0)-oriented Silicon-on-Insulator wafer. The wafer was etched by KOH 40 wt%, to form 83 μm deep and 4.5 mm long trenches that were subsequently filled with Spurr’s epoxy, which has acoustic impedance 2.4 MRayl. This resulted in a stack of three layers: The silicon substrate, a silicon–polymer composite intermediate layer, and a polymer layer on the top. The stacks were bonded to PZT disks to form acoustic transducers and the acoustic performance of the fabricated transducers was tested in a pulse-echo setup, where center frequency, −6 dB relative bandwidth and insertion loss were measured. The transducer with two matching layers was measured to have a relative bandwidth of 70%, two-way insertion loss 18.4 dB and pulse length 196 ns. The transducers with three matching layers had fractional bandwidths from 90% to 93%, two-way insertion loss ranging from 18.3 to 25.4 dB, and pulse lengths 326 and 446 ns. The long pulse lengths of the transducers with three matching layers were attributed to ripple in the passband. 相似文献
54.
Anke Hagen Marie Lund Traulsen Wolff‐Ragnar Kiebach Bjoern Sejr Johansen 《Journal of synchrotron radiation》2012,19(3):400-407
Solid oxide fuel cells (SOFCs) are able to produce electricity and heat from hydrogen‐ or carbon‐containing fuels with high efficiencies and are considered important cornerstones for future sustainable energy systems. Performance, activation and degradation processes are crucial parameters to control before the technology can achieve breakthrough. They have been widely studied, predominately by electrochemical testing with subsequent micro‐structural analysis. In order to be able to develop better SOFCs, it is important to understand how the measured electrochemical performance depends on materials and structural properties, preferably at the atomic level. A characterization of these properties under operation is desired. As SOFCs operate at temperatures around 1073 K, this is a challenge. A spectroelectrochemical cell was designed that is able to study SOFCs at operating temperatures and in the presence of relevant gases. Simultaneous spectroscopic and electrochemical evaluation by using X‐ray absorption spectroscopy and electrochemical impedance spectroscopy is possible. 相似文献
55.
Prieur F Johansen TF Holm S Torp H 《The Journal of the Acoustical Society of America》2012,131(6):4365-4375
Nonlinear propagation of sound has been exploited in the last 15 years in medical ultrasound imaging through tissue harmonic imaging (THI). THI creates an image by filtering the received ultrasound echo around the second harmonic frequency band. This technique produces images of enhanced quality due to reduced body wall reverberation, lower perturbations from off-axis echoes, and multiple scattering of reduced amplitude. In order to optimize the image quality it is essential to be able to predict the amplitude level and spatial distribution of the propagating ultrasound pulse. A method based on the quasi-linear approximation has been developed to quickly provide an estimate of the ultrasound pulse. This method does not need to propagate the pulse stepwise from the source plane to the desired depth; it directly computes a transverse profile at any depth from the definitions of the transducer and the pulse. The computation handles three spatial dimensions which allows for any transducer geometry. A comparison of pulse forms, transverse profiles, as well as axial profiles obtained by this method and state-of-the-art simulators, the KZKTexas code, and Abersim, shows a satisfactory match. The computation time for the quasi-linear method is also smaller than the time required by the other methods. 相似文献
56.
Untersuchung von Heterostrukturen der Mischkristallreihe GaAs/AlAs mit dem Rasterelektronenmikroskop
The investigation of heterojunctions of the mixed crystals series GaAs/AlAs by means of different scanning electron microscopic techniques yields that the utilization of the cathodoluminescence is highly suited for detecting small energy gap differences. Compared with the secondary electron contrast and the imaging by backscattered electrons, resp., it is clearly advantagoeus with respect to an identification specific tot he material. The course of the intensity profile with increasing primary electron energy permits to indicate a qualitative correlation with the value of the band gap. This is demonstrated with two heterojunctions with strongly different dopings. The Y-modulation technique is successful in displaying an orientation-dependent portion of the image contrast of homo- and heterojunctions of multiple structures. 相似文献
57.
In the late 1920s several mathematicians were on the verge of discovering a theorem for characterizing planar graphs. The proof of such a theorem was published in 1930 by Kazimierz Kuratowski, and soon thereafter the theorem was referred to as the Kuratowski Theorem. It has since become the most frequently cited result in graph theory. Recently, the name of Pontryagin has been coupled with that of Kuratowski when identifying this result. The events related to this development are examined with the object of determining to whom and in what proportion the credit should be given for the discovery of this theorem. 相似文献
58.
In this paper we study the stochastic joint replenishment problem. We compare the class of periodic replenishment policies and the class of can-order policies for this problem. We present a method, based on Markov decision theory, to calculate near-optimal can-order policies for a periodic-review inventory system. Our numerical study shows that the can-order policy behaves as well as, if not better than, the periodic replenishment policies. In particular, for examples where the demand is irregular, we find cost differences up to 15% in favour of the can-order policy. 相似文献
59.
The recognition of very stiff axial elastic motion compared to the motion in the transverse direction for cable dynamics motivates separation of the axial and transversal dynamics. For certain applications, e.g. real-time model-based control, fast calculation of the transverse motion may be of high importance, motivating the development of numerically efficient software code. Separation of axial dynamics renders possible neglection or simplification of the axial dynamics if appropriate for the system studied. A model is proposed with the assumption of axial inextensible material and negligible bending, torsion and shear stiffness in the cable. Experiments are carried out to verify the model, and the results are compared with simulations. The comparison between the experiments and numerical simulations showed good agreement up to the second frequency range with resonant behavior and the corresponding motion amplitudes. 相似文献
60.