Catalytic selective oxidation or oxidative functionalization of methane and ethane to organic oxygenates

Selective oxidation or oxidative functionalization of methane and ethane by both homogeneous and heterogeneous catalysis is presented concerning: (1) selective oxidation of methane and ethane to organic oxygenates by hydrogen peroxide in a water medium in the presence of homogeneous osmium catalysts, (2) selective oxidation of methane to formaldehyde over highly dispersed iron and copper heterogeneous catalysts, (3) selective oxidation of ethane to acetaldehyde and formaldehyde over supported molybdenum cat...     

Ni/MH电池过充电过程热效应分析

论文采用二维热模型分析了圆柱型Ni/MH电池在过充电过程中的热效应.实验提供了更为精准的数据以建立精确的热模型.利用石英频率微量热仪对电池的热容量以及电池在不同电流过充电时的发热量和散热速率进行了测量,继而将散热速率曲线拟合成线性函数和三段不同的指数函数.线性阶段之后的散热过程符合数学微分表达式,这些表达式有助于理解过渡阶段和过充电阶段散热速率的变化规律.热传导方程中产热速率采用理论计算值.最后使用FEM模拟了电池在1C,3C,5C充电过程每一阶段末时刻的电池内部温度场分布,结果相对准确.     

[(NHC)CrCl(μ-Cl)(THF)]_2 and(NHC)_2CrCl_2(NHC=1,3-Diisopropyl-4,5-dimethylimidazole-2-ylidene):Syntheses,Structures,and Polymerization Activities

The preparation of divalent chromium N-heterocyclic carbene(NHC,1,3-diisopropyl4,5-dimethylimidazole-2-ylidene) compounds is reported.The reaction of 1:1 molar ratio of NHC with CrCl2 led to an isolation of [(NHC)CrCl(μ-Cl)(THF)]2(1),while that of 2:1 ratio resulted in the formation of(NHC)2CrCl2(2).1 can be considered as an intermediate in the formation of 2 and further converted into 2 by the addition of another equiv.of NHC.The reaction of 2 with CpNa afforded an ion pair compound [(NHC)2CrCp]+[Cp]-(3),indicating a strong coordination ability of NHC supplanting one of the ionic Cr-Cp bonding.In combination of methylalumoxane(MAO) as cocatalyst 1 and 2 both are active for catalyzing ethylene polymerization.     

基于空间光调制器的波面重建优化方法研究

针对不同非球面面形的实时检测需求,研究了基于空间光调制器的标准波面重建技术.基于空间光调制器波面重建的原理设计了干涉测量系统,依据空间光调制器的自身特点选取修正离轴计算全息编码方式实现对标准球波面的编码.针对实验中空间光调制器作为全息再现介质引起重建波面质量下降问题,提出了错位叠加优化方案,并将这一过程进行了模拟实验....     

单纵模671nm红光激光器

利用全波片和Nd:YVO4激光器的偏振特性构成双折射滤光片,使用I类临界相位匹配LBO作为倍频晶体,在注入泵浦功率2.7W的情况下获得149mW的671nm单纵模红光输出,光-光转换率5.6%,该结构简单、紧凑,适合用于中低功率激光器。     

Study of the THGEM detector with a reflective CsI photocathode

The THGEM detector without and with a CsI has been tested successfully. The optimal parame- ters of THGEM have been determined from eight samples. The UV photoelectric effect of the CsI photocathode is observed. The changing tendency related to the extraction efficiency (ε<,extr>) versus the extraction electric field is measured, and several electric fields influencing the anode current are adjusted to adapt to the THGEM detector with a reflective CsI photocathode.     

基于单色捕捉技术的透平导叶传热系数测量

采用窄带热敏液晶瞬态单色捕捉技术测量叶片全表面传热系数,以预先加热被测叶片并在主流中快速冷却的方法引入温度阶跃,利用3台3CCD（电荷耦合元件）相机对叶片表面的不同区域进行图像采集记录,将图像坐标转换至叶片空间坐标,通过后处理得到叶片表面传热系数。由实验结果分析可知,叶片前缘区域传热系数最大值位于加速最剧烈处,在吸力面...     

Study of the THGEM detector with a reflective CsI photocathode

The THGEM detector without and with a CsI has been tested successfully. The optimal parameters of THGEM have been determined from eight samples. The UV photoelectric effect of the CsI photocathode is observed. The changing tendency related to the extraction efficiency (ε_extr) versus the extraction electric field is measured, and several electric fields influencing the anode current are adjusted to adapt to the THGEM detector with a reflective CsI photocathode.     

算子代数上的Lie可导映射

设A为有单位且包含一非平凡幂等元的环,M为A双模.称δ:A→M为Lie可导映射(无可加或连续假设),若δ([A,B])=[δ(A),B]+[A,δ(B)],(?)A,B∈A.在一定条件下该文证明了Lie可导映射δ具有形式δ(A)=τ(A)+f(A),其中r:A→M是可加导子,f是从A到M的中心且满足f([A,B])=0,(?)A,B∈A的映射.由此刻画了因子von Neuamnn代数和套代数上的Lie可导映射.