排序方式: 共有80条查询结果,搜索用时 46 毫秒
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Francesca Cardona Andrea Goti Sylviane Picasso Pierre Vogel Alberto Brandi 《Journal of carbohydrate chemistry》2013,32(4-5):585-601
ABSTRACT (+)-Lentiginosine (14) and (7R)-7-hydroxylentiginosine (26), powerful inhibitors of amyloglucosidases, and their enantiomers were obtained in high overall yields by a multistep synthesis involving 1,3-dipolar cycloaddition of enantiopure tartaric acid derived pyrroline N-oxides. Structurally related (S,S)-3,4-dihydroxypyrrolidines 29-33 were synthesized as simpler models and tested towards 24 glycosidases. 相似文献
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Bénac-Lestrille G Helmstedt U Vendier L Alcaraz G Clot E Sabo-Etienne S 《Inorganic chemistry》2011,50(21):11039-11045
The reaction of cyclodiborazane [Me(2)N-BH(2)](2) with the chloro(dihydrogen) ruthenium complex RuHCl(η(2)-H(2))(P(i)Pr(3))(2) (1) led to the formation of the unsymmetricaly coordinated dimethylaminoborane complex RuHCl(H(2)BNMe(2))(P(i)Pr(3))(2) (2). The dimethylaminoborane coordination (H(2)BNMe(2)) to the ruthenium center in 2 was carefully studied by combining X-ray, multinuclear NMR, and density functional theory (DFT) techniques, and compared with the recently reported osmium analogue which was originally formulated as a σ-B-H borinium complex [OsH(2)Cl(HBNMe(2))(P(i)Pr(3))(2)] (4). All our data are in favor of a bis(σ-B-H) coordination mode at a very activated stage in the case of the ruthenium complex 2, whereas in the osmium complex 4, full oxidative addition is favored leading to a complex better formulated as an osmium(IV) boryl species with an α-agostic B-H interaction. The synthesis and characterization of the symmetrical dihydride complex RuH(2)(H(2)BNMe(2))(P(i)Pr(3))(2) (3) from addition of the lithium dimethylaminoborohydride to 1 is reported for comparison. 相似文献
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Montiel-Palma V Muñoz-Hernández MA Ayed T Barthelat JC Grellier M Vendier L Sabo-Etienne S 《Chemical communications (Cambridge, England)》2007,(38):3963-3965
Reaction of a phosphinobenzylsilane compound with ruthenium complexes leads to C-H and/or Si-H activation. The new complex Ru{eta(2)-H-SiMe2CH(o-C(6)H(4))PPh2}2 (5) was isolated and X-ray, NMR and DFT studies reveal that 5 displays two agostic Si-H interactions and two carbon-metallated bonds. 相似文献
55.
Angelov B Angelova A Garamus VM Lebas G Lesieur S Ollivon M Funari SS Willumeit R Couvreur P 《Journal of the American Chemical Society》2007,129(44):13474-13479
The structural evolution of a diamond-type bicontinuous lipid cubic phase upon application of thermal and chemical (hydration agent) stimuli is investigated by means of small-angle neutron (SANS) and X-ray scattering (SAXS). The soft-matter cubic architecture responds by dramatic swelling (DLarge cubic structure) upon incorporation of a hydration-enhancing guest component (octyl glucoside) at low and ambient temperatures, the aqueous channel diameter increasing twice to approximately 7 nm. DLarge appears to be built up from an assembly of cubosomic domains, which may coexist with an amphiphilic lamellae domain at low temperatures. The chemical stimulus concentration can be selected as to tune the hydration of the nanochannels in the DLarge phase and its transformation into a DNormal phase at temperatures above the body temperature. Two-dimensional SANS images recorded upon heating scan reveal growth of spontaneously oriented domains of single-crystal cubic nature. Phase separation and squeezing out the guest-hydrating agent from the higher-curvature regions of the amphiphilic bilayer suggest a possible mechanism for the established transformations. The order-order structural transition, cubic DLarge-cubic DNormal, is found to be reversible upon cooling. The obtained results put forward a structure-based concept for release of encapsulated guest molecules from stimuli-responsive and self-regulated cubosomic nanocarriers. 相似文献
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Audrey Cassen Yann Gloaguen Laure Vendier Carine Duhayon Amalia Poblador‐Bahamonde Christophe Raynaud Eric Clot Gilles Alcaraz Sylviane Sabo‐Etienne 《Angewandte Chemie (International ed. in English)》2014,53(29):7569-7573
Tuning the nature of the linker in a L~BHR phosphinoborane compound led to the isolation of a ruthenium complex stabilized by two adjacent, δ‐C? H and ε‐Bsp2? H, agostic interactions. Such a unique coordination mode stabilizes a 14‐electron “RuH2P2” fragment through connected σ‐bonds of different polarity, and affords selective B? H, C? H, and B? C bond activation as illustrated by reactivity studies with H2 and boranes. 相似文献
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Delphine Gallois-Montbrun Nicolas Thiebault Vincent Moreau Geneviève Le Bas Jean-Christophe Archambault Sylviane Lesieur Florence Djedaïni-Pilard 《Journal of inclusion phenomena and macrocyclic chemistry》2007,57(1-4):131-135
A novel amphiphilic cyclodextrin derivative was obtained by controlled esterification of lauric acid chloride on the primary
face of the native β-cyclodextrin in a one step synthesis. The characterization of the substitution degree and isomer structure
was performed by mass and NMR spectroscopies. A specific purification procedure by sublimation was developed in order to eliminate
the excess of lauric acid molecules in the reaction product. The sublimation efficiency was assessed by differential scanning
calorimetry (DSC) in quantifying the remaining fatty acid. In this way the duration of the sublimation process could be optimized. 相似文献
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Sylviane R Schwer 《Comptes Rendus Mathematique》2002,334(4):261-266
We study natural correspondances between the set of arrangements of subsets with repetitions and families of objects met in various areas of mathematics (walks in lattices, pre-order) and computer science (formal languages, Petri nets, Artificial Intelligence), using the framework of formal languages. For n=2, they are enumerated by Delannoy numbers. To cite this article: S.R. Schwer, C. R. Acad. Sci. Paris, Ser. I 334 (2002) 261–266. 相似文献
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Gloaguen Y Alcaraz G Petit AS Clot E Coppel Y Vendier L Sabo-Etienne S 《Journal of the American Chemical Society》2011,133(43):17232-17238
The reactivity of the (o-phosphinophenyl)(amino)borane compound HB(N(i)Pr(2))C(6)H(4)(o-PPh(2)) prepared from Li(C(6)H(4))PPh(2) and HBCl(N(i)Pr(2)) toward the bis(dihydrogen) complex RuH(2)(H(2))(2)(PCy(3))(2) (1) was studied by a combination of DFT, X-ray, and multinuclear NMR techniques including solid-state NMR, a technique rarely employed in organometallic chemistry. The study showed that the complex RuH(2){HB(N(i)Pr(2))C(6)H(4)(o-PPh(2))}(PCy(3))(2) (3), isolated in excellent yield as yellow crystals and characterized by X-ray diffraction, led in solution to PCy(3) dissociation and formation of an unsaturated 16-electron complex RuH(2){HB(N(i)Pr(2))C(6)H(4)(o-PPh(2))}(PCy(3)) (4), with a hydride trans to a vacant site. In both cases, the (phosphinoaryl)(amino)borane acts as a bifunctional ligand through the phosphine moiety and a Ru-H-B interaction, thus featuring an agostic interaction. 相似文献