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Perrine Pivette Vincent Faivre Georges Daste Michel Ollivon Sylviane Lesieur 《Journal of Thermal Analysis and Calorimetry》2009,98(1):47-55
Two lipid binders, glyceryl behenate and paraffin wax, were examined regarding their ability to be used in a prilling process.
Prilling has the advantage to produce microgranules very reproducible in size and shape but involves ultrafast cooling of
liquid droplets. The different steps to produce solid micropheres from the molten state were successfully modelled to predict
crystallisation time as a function of the binder used. Bulk versus microgranules characterization by differential scanning
calorimetry, X-ray diffraction and microscopies showed the peculiar suitability of the 50/50 mixture of the two lipid binders
for prilling, in agreement with the theoretical approach. 相似文献
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[reaction: see text] A convergent method has been found to prepare 4-aza-2,3-didehydropodophyllotoxin and derivatives in a one-pot procedure. The mechanism of the reaction between tetronic acid, anilines, and benzaldehydes is discussed. 相似文献
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Audrey Cassen Yann Gloaguen Laure Vendier Carine Duhayon Amalia Poblador‐Bahamonde Christophe Raynaud Eric Clot Gilles Alcaraz Sylviane Sabo‐Etienne 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(29):7699-7703
Tuning the nature of the linker in a L∼BHR phosphinoborane compound led to the isolation of a ruthenium complex stabilized by two adjacent, δ‐C H and ε‐Bsp2 H, agostic interactions. Such a unique coordination mode stabilizes a 14‐electron “RuH2P2” fragment through connected σ‐bonds of different polarity, and affords selective B H, C H, and B C bond activation as illustrated by reactivity studies with H2 and boranes. 相似文献
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Ronel Biré Guy Tufféry Hélène Lelièvre Sylviane Dragacci 《Accreditation and quality assurance》2004,9(11-12):711-716
The French Food Safety Agency is a public body incorporating 12 laboratories that perform research to support expertise and public decisions taken in the fields of sanitary safety of food, animal health, and veterinary drugs. On the request of the General Management of the Agency a quality-management system in research (QMSR) is being implemented in the Food and Food Process Quality Research Laboratory. The experimental QMSR is based on existing standards and documents, describing the provisions required for scientific and technical competence, quality management, and project management. Furthermore, this QMSR also incorporates specific notions of great importance for research activities such as the positive and negative non-conformities, the non-confirmation of hypotheses, and the principle of evaluation of a research activity by peers for both quality and scientific aspects. 相似文献
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Sylviane Sabo Bruno Chaudret Daniele Gervais 《Journal of organometallic chemistry》1983,255(1):C19-C22
Reactions of NaMn(CO)3 with RuCl2(PMe3)4, RuCl2(dppm)2 and RuCl2(PPh3)3 lead either to an ionic species [Ru2Cl3(PMe3)6]+[Mn(CO)5]? or to metal—metal bonded RuMn compounds such as RuMn(μ-CO)2(CO)3(μ-dppm)2 Cl, and, quite unexpectedly, to the μ-phosphido complex RuMn(μ-PPh2)(CO)6(PPh3)2 via a hydride intermediate. 相似文献
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L Mercklé J Dubois E Place S Thoret F Guéritte D Guénard C Poupat A Ahond P Potier 《The Journal of organic chemistry》2001,66(15):5058-5065
Two novel 5(20)-thia analogues of docetaxel have been synthesized from 10-deacetylbaccatin III or taxine B and isotaxine B. The key step of these syntheses is the concomitant thietane ring formation and acetylation of the tertiary alcohol at C-4. Both compounds are less cytotoxic than docetaxel but have divergent activity on microtubule disassembly. 相似文献
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Busnel O Bi L Dali H Cheguillaume A Chevance S Bondon A Muller S Baudy-Floc'h M 《The Journal of organic chemistry》2005,70(26):10701-10708
[structure: see text] A solid-phase fluorenylmethyloxycarbonyl (Fmoc)-based synthesis strategy is described for "mixed" aza-beta3-peptides as well as a convenient general approach for their required building blocks, the aza-beta3-amino acid residues (aza-beta3-aa). These monomers allow the synthesis of relatively large quantities of pure mixed aza-beta3-peptides. The required Fmoc-substituted aza-beta3-amino acids are accessible by convenient synthesis, and a number of monomers including those containing side chains with functional groups have been synthesized. The method was applied toward the solid-phase synthesis of aza-beta3-peptide mimetics of a biologically active histone H4 sequence. 相似文献