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61.
M. Fechner F. Reichert N.-O. Hansen K. Petermann G. Huber 《Applied physics. B, Lasers and optics》2011,102(4):731-735
Polarization dependent ground state absorption, excited state absorption and emission cross sections of Pr,?Mg:SrAl12O19 are determined in the visible and ultraviolet spectral region. It is shown that excited state absorption to the 4f5d configuration does neither occur on the pump wavelength in the blue region nor on any of the visible laser transitions. Efficient laser action at 643.5?nm is demonstrated with slope efficiencies of up to 47% with respect to the absorbed pump power. Output powers up to 75?mW are achieved by pumping with an InGaN laser diode at 444?nm. 相似文献
62.
Calmano T Siebenmorgen J Reichert F Fechner M Paschke AG Hansen NO Petermann K Huber G 《Optics letters》2011,36(23):4620-4622
We fabricated waveguides in Pr:SrAl(12)O(19) crystals by direct femtosecond laser writing. The propagation losses were calculated to be as low as 0.16 dB/cm at a wavelength of 633 nm. Laser oscillation in a diode-pumped waveguide at a wavelength of 643.5 nm was realized. The output power of the waveguide laser was 28.1 mW at a slope efficiency of 8%. 相似文献
63.
Andreas Hilgeroth Günter Hempel Ute Baumeister Detlef Reichert 《Solid state nuclear magnetic resonance》1999,13(4):4125-243
13C CPMAS NMR spectroscopy has been applied to monitor the solid-state reaction of two different photodimerizing 4-phenyl-1,4-dihydropyridines yielding a cage dimer in one case and an anti-dimer in the other case. The spectra of the reacting monomers exhibit a magnetical inequivalence of chemically equivalent CO and C2/4 carbon atoms caused by a rotation of the pseudoaxially oriented 4-phenyl substituent out off the plane through N1, C3, C8 which could be determined by X-ray crystal structure analyses of the centrosymmetrically arranged monomers. The 13C CPMAS NMR monitoring of the cage dimer formation proves that the reaction takes place in two steps via a syn-dimer for which a non-symmetrical structure was derived from the spectrum. The non-symmetrical structure was confirmed by X-ray crystal structure analysis of one structurally related derivative. A centrosymmetric structure for both the finally formed cage dimer and the anti-dimer of the other monitored photoreaction was proved by their spectra with one set of signals for each half of the dimers, respectively. Thus, conformational properties of the molecules as well as the symmetry of the products can be directly derived from the 13C CPMAS NMR spectra. 相似文献
64.
Sylvia Sander 《Analytical and bioanalytical chemistry》1999,365(5):435-443
Four different complexing reagents namely chloranilic acid, oxine, tropolone, and cupferron were applied for AdSV determinations
of molybdenum. The parameters for the determination using a flow-through cell with a hanging mercury drop (HMDE) as working
electrode were examined systematically for all four systems and evaluated. Cyclic voltammograms were recorded to examine the
electrode reaction, alternating current (AC) voltammetry was used to determine adsorption processes. The comparison includes
sensitivity, detection limit, linear concentration range, the susceptibility to interference by organic compounds or foreign
ions, and the applicability to sea and tap water samples. The interpretation of the electrode reaction mechanism for the reduction
of the Mo cupferron complex published from Jiao et al. [10] was improved.
Received: 12 February 1999 / Revised: 10 May 1999 / Accepted: 14 May 1999 相似文献
65.
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67.
Giuliana Gorrasi Loredana Tammaro Mariarosaria Tortora Vittoria Vittoria Dirk Kaempfer Peter Reichert Rolf Mülhaupt 《Journal of Polymer Science.Polymer Physics》2003,41(15):1798-1805
Isotactic polypropylene nanocomposites were obtained by the melt blending of polypropylene‐graft‐maleic anhydride and organophilic layered silicate (OLS) consisting of synthetic fluorohectorite modified by cation exchange with protonated octadecylamine. The composition of the inorganic clay was varied between 2.5 and 10 wt %, and films of the composites were obtained via hot‐press molding. X‐ray analysis showed that nanocomposites in which silicate layers were either delaminated or ordered as in an intercalated structure were obtained. The elastic modulus of the samples was higher than that of the pure polymer over a wide temperature range and increased with increasing inorganic content. The transport properties, sorption and diffusion, were measured for two organic vapors, dichloromethane and n‐pentane. For both vapors, the sorption was not very different from that of the pure polymer, whereas the zero‐concentration diffusion parameter strongly decreased with increasing OLS content. Therefore, the permeability, that is, the product of sorption and diffusion, decreased for both vapors as a result of the decreased value of the diffusion parameter. The decrease was higher for the less interacting n‐pentane. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1798–1805, 2003 相似文献
68.
Hausdorff momentum problem and its relations to spectral theorem for bounded Hilbert space operators are treated. A generalization for some ordered algebras is shown, where projections are replaced by idempotents. 相似文献
69.
The chemisorption of Na on the Al(001) surface has been studied by 2D bandstructure calculations on slab models using a density functional STO-LCAO method. Two slab models of three and five layers of substrate atoms have been used. Overlayers of the structuresp(2×2),c(2×2) andp(1×1), representing coverages of a quarter, a half and a full atomic monolayer of sodium atoms, respectively, have been investigated. The electronic structure of the adatoms and the charge transfer to the substrate are discussed. Satisfactory agreement with experiment is obtained for the adsorption induced change of the work function, correctly reproducing its monotonic character. 相似文献
70.
We study the skew-product semiflow induced by a family of convex and cooperative delay differential systems. Under some monotonicity assumptions, we obtain an ergodic representation for the upper Lyapunov exponent of a minimal subset. In addition, when eventually strong convexity at one point is assumed and there exist two completely strongly ordered minimal subsets K1?CK2, we show that K1 is an attractor subset which is a copy of the base. The long-time behaviour of every trajectory strongly ordered with K2 is then deduced. Some examples of application of the theory are shown. 相似文献