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71.
Stable [C5H5Ni(NN)]BF4 complexes are formed by treatment of [C5H5Ni(SR2)2]BF4 (R = CH3) with some 1,2-diaminoalkylidenes NN; Chemical and spectroscopic properties are reported. 相似文献
72.
Dieter Klapstein Robert Kuhn John P. Maier Liubomir Misev Martin Ochsner 《Helvetica chimica acta》1984,67(5):1222-1232
Gas phase emission and laser excitation spectra of the Ã2E?X?2E (Σ = +½, ?½) transition of rotationally/vibrationally cooled 1-chloro- and 1-bromo-1,3-pentadiyne cations have been obtained. The emission was excited by electron impact on a seeded helium supersonic free jet and the fluorescence by laser excitation of cations produced by Penning ionization and collisional relaxation. From these two sets of data the origin bands of the spin-orbit systems are located and for the bromo species this leads to better values of the spin-orbit splitttings in the two electronic states and of the first adiabatic ionization energy. The vibrational frequencies of many of the fundamentals of these cations in the X?2E and Ã2E states have been obtained to within ±2 cm?1. 相似文献
73.
3,3′-Thiobispyridine is prepared by reaction of pyridine-3-thiol with 3-bromopyridine. The base peak in the mass spectrum of 3,3′-thiobispyridine is due to the molecular ion which fragments by loss of H, HCN and CS as well as by central bond rupture. The 1,1′-dimethyl diquaternary salt of 3,3′-thiobispyridine is reduced polarographically by a one electron transfer not involving hydrogen to an unstable radical cation at a potential (Eo) of −0.72 V in the pH range 7.4–11.2. 相似文献
74.
75.
R. Kuhn 《Colloid and polymer science》1978,256(3):300-301
Ohne Zusammenfassung 相似文献
76.
Sylvia Marhold Ernst Koller Isabella Meyer Otto S. Wolfbeis 《Fresenius' Journal of Analytical Chemistry》1990,336(2):111-113
Summary A new fluorimetric assay for cationic surfactants is based on their capability of quenching the fluorescence of 8-octadecyloxypyrene-1,3,6-trisulfonate (PTS-18). It is specific for cationic surfactants which can be determined in the 40–400 g concentration range. The method is considered to be advantageous over former methods in that it only requires addition of the sample solution to the fluorophore solution, followed by measurement of fluorescence intensity of the probe. This is in contrast to existing methods where the detergent/dye ion pair has to be extracted before measurement. 相似文献
77.
78.
Peter Kuhn Ulrich Hauser Wolfgang Neuwirth 《Zeitschrift für Physik A Hadrons and Nuclei》1973,264(4):287-300
The Mössbauer spectra of Fe(CO)5 dissolved in 39 organic solvents were investigated. An influence on the quadrupole split was found only for those solvents containing carbonylic CO, but not for solvents containing another polar group. The change of the quadrupole split means always a reduction and is independent of temperature. The concentration dependence of the additional split indicates that it is caused only by nearest neighbours.—These results give a hint for a specific weak interaction between the carbonylic CO group of Fe(CO)5 and the solvents. This cannot be a general dipole-dipole interaction because of the missing influence of other polar solvents, so that a weak chemical bond is suggested. 相似文献
79.
Two experimental arrangements of an optical frequency up-converter using GaSe are described. Two wavelength regions have been covered by series of monochromatique rays (one ranging from 3.25 μ to 3.85 μ, the other one from 0.954 μ to 0.968 μ). 相似文献
80.
G. Ransoné P. Sixel H.H. Kaufmann R. Klein H. Vogt H. Dreverman D. Kuhn J.P. Porte R.T. Ross F. Triantis K. Dziunikowska B. Muryn K.W.J. Barnham J. Wells P.R.S. Wright D. Dallman F. Mandl M. Szczekowski 《Nuclear Physics B》1980,167(3):285-291
The charged multiplicity distribution is presented for K?p interactions produced in the hydrogen bubble chamber, BEBC, using an r.f. separated, tagged K? beam of 110 GeV/c momentum. A comparison with K+p, πp and pp data at lower energies shows that the main features of the multiplicity distributions depend on energy and charge of the incident particles, but not on their strangeness. At high energies, only the energy is important. 相似文献